Citation: ZHU Yan-Feng, ZHANG Juan, ZHANG Yi-Yong, DING Min, QI Hai-Qing, DU Rong-Gui, LIN Chang-Jian. Anticorrosion Properties of Modified Nano-TiO₂ Films Prepared by Sol-Gel Method[J]. Acta Physico-Chimica Sinica, ;2012, 28(02): 393-398. doi: 10.3866/PKU.WHXB201112163 shu

Anticorrosion Properties of Modified Nano-TiO₂ Films Prepared by Sol-Gel Method

1.
State Key Laboratory for Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China

Received Date: 22 August 2011
Available Online: 16 December 2011
Fund Project: 国家高技术研究发展计划项目(863) (2009AA03Z327) (863) (2009AA03Z327)国家自然科学基金(21073151 和21173177)资助 (21073151 和21173177)

TiO₂ and B-Fe-Ce-modified TiO₂ films were synthesized on the surfaces of 316L stainless steel (316L SS) substrates using a sol-gel and dip-coating method. The properties of the films were characterized by field emission scanning electron microscopy, atomic force microscopy, Raman spectroscopy and energy dispersive spectrometry. The corrosion resistance of the films and their ability to protect stainless steel were investigated by electrochemical impedance spectroscopy and potentiodynamic polarization curves. Both TiO₂ and B-Fe-Ce-modified TiO₂ films were composed of anatase nanoparticles about 15 and 10 nm in diameter, respectively. Impedance spectra of the stainless steel substrates coated TiO₂ films contained semicircles for capacitive reactance in 0.5 mol·L^-1 NaCl solution, but the charge transfer resistance of the B-Fe-Ce-TiO₂/316L SS electrode was higher than that of the TiO₂/316L SS electrode. The potentiodynamic anodic polarization curve of the B-Fe-Ce-TiO₂/316L SS electrode showed a larger stable passive region and a higher breakdown potential than the TiO₂/316L SS electrode, indicating that the modified film had better corrosion resistance and protective properties for 316L SS.
- Nano-TiO₂ film,
- Sol-gel method,
- 316L stainless steel,
- Electrochemical impedance spectroscopy
1. [1]
  (1) Hou, B. R. Corrosion Research and Protection; Ocean Press: Beijing, 1998; p1. [侯保荣.腐蚀研究与防护.北京: 海洋出版杜, 1998: 1].
2. [2]
  (2) Liu, R. H.; Zhang, P. F. Metal Corrosion Principle; Aviation Industry Press: Beijing, 1993; pp 249-253. [刘永辉, 张佩芬. 金属腐蚀学原理. 北京: 航空工业出版社, 1993: 249-253].
3. [3]
  (3) Kasten, L. S.; Grant, J. T.; Grebasch, N.; Voevodin, N.; Arnold, F. E.; Donley, M. S. Surf. Coat. Technol. 2001, 140. 11.
4. [4]
  (4) Hamdy, A. S.; Butt, D. P. Surf. Coat. Technol. 2006, 201, 401.
5. [5]
  (5) Jing, F. J.; Jin, F. Y.; Liu, Y.W.;Wan, G. J.; Liu, X. M.; Zhao, X. B.; Fu, R. K. Y.; Leng, Y. X.; Huang, N.; Chu, P. K. J. Vac. Sci. Technol. A 2006, 24, 1790.
6. [6]
  (6) Carbajal, G.; Martinez-Villafane, A.; nzalez-Rodriguez, J. G.; Castano, V. M. Anti.-Corros. Method. M. 2001, 48, 241.
7. [7]
  (7) Shen, G. X.; Chen, Y. C.; Lin, C. J. Acta Phys.-Chim. Sin. 2005, 21, 485. [沈广霞, 陈艺聪, 林昌键. 物理化学学报, 2005, 21, 485]
8. [8]
  (8) Akpan, U. G.; Hameed, B. H. Appl. Catal. A.-Gen. 2010, 375, 1.
9. [9]
  (9) Ye,W.; Li, J.;Wang, F. H. Elechtrochim. Acta 2006, 51, 4426.
10. [10]
  (10) Liu, L.; Li, Y.;Wang, F. H. Elechtrochim. Acta 2006, 52, 2392.
11. [11]
  (11) Zhu, Y. F.; Du, R. G.; Li, J.; Qi, H. Q.; Lin, C. J. Acta Phys.-Chim. Sin. 2010, 26, 2349. [朱燕峰, 杜荣归, 李静, 漆海清, 林昌键. 物理化学学报, 2010, 26, 2349.]
12. [12]
  (12) Chan, M. H.; Lu, F. H. The Solid Films 2009, 518, 1369.
13. [13]
  (13) Prakasam, H. E.; Shankar, K.; Paulose, M.; Varghese, O. K.; Grimes, C. A. J. Phys. Chem. C 2007, 111, 7235.
14. [14]
  (14) Chen,W.W.; Gao,W. Elechtrochim. Acta 2010, 55, 6865.
15. [15]
  (15) He, Y. D.; Fu, H. F.; Li, X. Q.; Gao,W. Scripta Mater. 2008. 58, 504.
16. [16]
  (16) Ping, Z. X.; He, Y. D.; Gu, C. D.; Zhang, T. Y. Surf. Coat. Technol. 2008, 202, 6023.
17. [17]
  (17) Barati, N.; Faghihi Sani, M. A.; Ghasemi, H.; Sadeghian, Z.; Mirhoseini, S. M. M. Appl. Surf. Sci. 2009, 255, 8328.
18. [18]
  (18) Shibli, S. M. A.; Chacko, F. Surf. Coat. Technol. 2011, 205, 2931.
19. [19]
  (19) Liu, T.; Zhang, F. F.; Xue, C. R.; Li, L.;Yin, Y. S. Surf. Coat. Technol. 2010, 205, 2335.
20. [20]
  (20) Shen, G. X.; Chen, Y. C.; Lin, C. J. Thin Solid Films 2005, 489, 130.
21. [21]
  (21) Yun, H.; Li, J.; Chen, H. B.; Lin, C. J. Elechtrochim. Acta 2007, 52, 6679.
22. [22]
  (22) Bai, L.Y.; Su, X.Y.; Lei, M. K. J. Inorg. Mater. 2006, 21, 1085. [白凌云, 苏显云, 雷明凯. 无机材料学报, 2006, 21, 1085].
23. [23]
  (23) Wang, Y.W.; Huang, Y.; Ho,W. K.; Zhang, L. Z.; Zou, Z. G.; Lee, S. C. J. Hazard. Mater. 2009, 169, 77.
24. [24]
  (24) Mechiakh, R.; Ben Sedrine, N.; Chtourou, R.; Bensaha, R. Appl. Surf. Sci. 2010, 257, 670.
25. [25]
  (25) Zhang, Z. Y.; Shao, C. L.; Zhang, L. N.; Li, X. H.; Liu, Y. C. J. Colloid. Interf. Sci. 2010, 351, 57.
26. [26]
  (26) Deng, L. X.;Wang, S. R.; Liu, D. Y.; Zhu, B. L. Huang,W. P. Wu, S. H.; Zhang, S. M. Catal. Lett. 2009, 129, 513.
27. [27]
  (27) Yu, T.; Tan, X.; Zhao, L. J. Hazard. Mater. 2010, 176, 829.
28. [28]
  (28) Chen, D. M.; Yang, D.;Wang, Q.; Jiang, Z.Y. Ind. Eng. Chem. Res. 2006, 45, 4110.
29. [29]
  (29) Bhattacharyya, K.; Varma, S.; Tripathi, A. K.; Bhattacharyya, D.; Mathon, O.; Tyagi, A. K. J. Appl. Phys. 2009, 106.
30. [30]
  (30) Choi, H. C.; Jung, Y. M.; Kim, S. B. Vib. Spectrosc. 2005, 37, 33.
31. [31]
  (31) Shen, G .X.; Chen, Y. C.; Lin, L.; Lin, C. J.; Scantlebury, D. Elechtrochim. Acta 2005, 50, 5038.
32. [32]
  (32) Hamadou, L.; Kadri, A.; Benbrahim, N. Appl. Surf. Sci. 2005, 252, 1510.
33. [33]
  (33) Rammelt, U.; Reinhard, G. Elechtrochim. Acta 1990, 35, 1045.
34. [34]
  (34) Leibig, M.; Halsey, T. C. Elechtrochim. Acta 1993, 38, 1985.
35. [35]
  (35) Benedeti, A. V.; Sumodjo, P. T. A.; Nobe, K.; Cabot, P. L.; Proud,W. G. Elechtrochim. Acta 1995, 40, 2657.
1. [1]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
2. [2]
  Zhengli Hu , Jia Wang , Yi-Lun Ying , Shaochuang Liu , Hui Ma , Wenwei Zhang , Jianrong Zhang , Yi-Tao Long . Exploration of Ideological and Political Elements in the Development History of Nanopore Electrochemistry. University Chemistry, 2024, 39(8): 344-350. doi: 10.3866/PKU.DXHX202401072
3. [3]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
4. [4]
  Fanxin Kong , Hongzhi Wang , Huimei Duan . Inhibition effect of sulfation on Pt/TiO2 catalysts in methane combustion. Chinese Journal of Structural Chemistry, 2024, 43(5): 100287-100287. doi: 10.1016/j.cjsc.2024.100287
5. [5]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
6. [6]
  Lihua HUANG , Jian HUA . Denitration performance of HoCeMn/TiO₂ catalysts prepared by co-precipitation and impregnation methods. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 629-645. doi: 10.11862/CJIC.20230315
7. [7]
  Hongye Bai , Lihao Yu , Jinfu Xu , Xuliang Pang , Yajie Bai , Jianguo Cui , Weiqiang Fan . Controllable Decoration of Ni-MOF on TiO2: Understanding the Role of Coordination State on Photoelectrochemical Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100096-100096. doi: 10.1016/j.cjsc.2023.100096
8. [8]
  Wenhao Wang , Guangpu Zhang , Qiufeng Wang , Fancang Meng , Hongbin Jia , Wei Jiang , Qingmin Ji . Hybrid nanoarchitectonics of TiO₂/aramid nanofiber membranes with softness and durability for photocatalytic dye degradation. Chinese Chemical Letters, 2024, 35(7): 109193-. doi: 10.1016/j.cclet.2023.109193
9. [9]
  Mengli Xu , Zhenmin Xu , Zhenfeng Bian . Achieving Ullmann coupling reaction via photothermal synergy with ultrafine Pd nanoclusters supported on mesoporous TiO2. Chinese Journal of Structural Chemistry, 2024, 43(7): 100305-100305. doi: 10.1016/j.cjsc.2024.100305
10. [10]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
11. [11]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
12. [12]
  Yongming Zhu , Huili Hu , Yuanchun Yu , Xudong Li , Peng Gao . Construction and Practice on New Form Stereoscopic Textbook of Electrochemistry for Energy Storage Science and Engineering: Taking Basic Course of Electrochemistry as an Example. University Chemistry, 2024, 39(8): 44-47. doi: 10.3866/PKU.DXHX202312086
13. [13]
  Yifen He , Chao Qu , Na Ren , Dawei Liang . Enhanced degradation of refractory organics in ORR-EO system with a blue TiO₂ nanotube array modified Ti-based Ni-Sb co-doped SnO₂ anode. Chinese Chemical Letters, 2024, 35(8): 109262-. doi: 10.1016/j.cclet.2023.109262
14. [14]
  Maosen Xu , Pengfei Zhu , Qinghong Cai , Meichun Bu , Chenghua Zhang , Hong Wu , Youzhou He , Min Fu , Siqi Li , Xingyan Liu . In-situ fabrication of TiO₂/NH₂−MIL-125(Ti) via MOF-driven strategy to promote efficient interfacial effects for enhancing photocatalytic NO removal activity. Chinese Chemical Letters, 2024, 35(10): 109524-. doi: 10.1016/j.cclet.2024.109524
15. [15]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
16. [16]
  Jinyao Du , Xingchao Zang , Ningning Xu , Yongjun Liu , Weisi Guo . Electrochemical Thiocyanation of 4-Bromoethylbenzene. University Chemistry, 2024, 39(6): 312-317. doi: 10.3866/PKU.DXHX202310039
17. [17]
  Yong Zhou , Jia Guo , Yun Xiong , Luying He , Hui Li . Comprehensive Teaching Experiment on Electrochemical Corrosion in Galvanic Cell for Chemical Safety and Environmental Protection Course. University Chemistry, 2024, 39(7): 330-336. doi: 10.3866/PKU.DXHX202310109
18. [18]
  Shuangxi Li , Huijun Yu , Tianwei Lan , Liyi Shi , Danhong Cheng , Lupeng Han , Dengsong Zhang . NO_x reduction against alkali poisoning over Ce(SO₄)₂-V₂O₅/TiO₂ catalysts by constructing the Ce⁴⁺–SO₄²⁻ pair sites. Chinese Chemical Letters, 2024, 35(5): 108240-. doi: 10.1016/j.cclet.2023.108240
19. [19]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
20. [20]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351

Get Citation

PDF

XML

Metrics

PDF Downloads(974)
Abstract views(2673)
HTML views(16)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Anticorrosion Properties of Modified Nano-TiO2 Films Prepared by Sol-Gel Method

Metrics

通讯作者: 陈斌, bchen63@163.com

Anticorrosion Properties of Modified Nano-TiO₂ Films Prepared by Sol-Gel Method