Citation: QIAO Yin-Po, ZHU Zhen-Feng, ZHANG Yan-Bin, LIU Dian-Guang, WANG Bing-Qing, ZHANG Zhi-Chun. Tunable White Emitting in Ternary Ce/Tb/Sm Codoped CaO-B₂O₃-SiO₂ Glasses[J]. Acta Physico-Chimica Sinica, ;2012, 28(03): 706-710. doi: 10.3866/PKU.WHXB201112162 shu

Tunable White Emitting in Ternary Ce/Tb/Sm Codoped CaO-B₂O₃-SiO₂ Glasses

1.
School of Materials Science and Engineering, Shaanxi University of Science & Technology, Xi'an 710021, P. R. China

Received Date: 4 August 2011
Available Online: 16 December 2011
Fund Project: 中国博士后科学基金面上项目(20110491640) (20110491640) 陕西省教育厅科研计划项目(11JK0839) (11JK0839)陕西科技大学科研启动基金项目(BJ10-11)资助 (BJ10-11)

A series of luminescent glasses composed of CaO-B₂O₃-SiO₂ codoped with samarium oxide (Sm₂O₃), cerium oxide (CeO₂), and terbium oxide (Tb₄O₇) were prepared by melting at high temperature. The spectroscopic properties of the samples were investigated by photoluminescence (PL) measurements and CIE color coordinate. Blue, green, and reddish orange emission bands were observed in the PL spectra of Ce/Tb/Sm codoped glasses. The combination of these emission bands gave white light when the glasses were excited by near ultraviolet light. As the proportion of Tb₄O₇ was decreased, a gradual shift from green to white emission was observed in the PL spectra of the glasses. These rare earth ions-doped glasses are potential candidates for white light-emitting diodes.
- High temperature melting method,
- Luminescent glass,
- Photoluminescence,
- Luminescence adjustment,
- White light emitting diode
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Tunable White Emitting in Ternary Ce/Tb/Sm Codoped CaO-B2O3-SiO2 Glasses

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Tunable White Emitting in Ternary Ce/Tb/Sm Codoped CaO-B₂O₃-SiO₂ Glasses