Citation: ZHU Ying-Hong, ZENG Hong-Yan, LI Shan-Shan, LU Zai-Xiang, MA Chun-An. Electrochemical Oxidation of p-Methoxy Toluene in BMIMBF4 Ionic Liquid[J]. Acta Physico-Chimica Sinica, ;2012, 28(02): 421-426. doi: 10.3866/PKU.WHXB201112122 shu

Electrochemical Oxidation of p-Methoxy Toluene in BMIMBF4 Ionic Liquid

1.
State Key Laboratory of Green Chemistry Synthesis Technology, College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310032, P. R. China

Received Date: 8 October 2011
Available Online: 12 December 2011
Fund Project: 国家自然科学基金(21076192) (21076192)浙江省重点科技创新团队项目(2009R50002)资助 (2009R50002)

The electrochemical oxidation behavior of p-methoxy toluene was studied in an ionic liquid of 1-butyl-3-methylimidazolium tetrafluoroborate (BMIMBF₄) on platinum electrode by cyclic voltammetry (CV), chronoamperometry (CP), and in situ Fourier transform infrared spectroscopy (in-situ FTIRS). The results showed that the electrochemical oxidation of p-methoxy toluene in BMIMBF₄ was irreversible. The four-electron process was controlled by diffusion, and the diffusion coefficient D was 3.4×10^-7 cm²·s^-1. The main oxidation product was anisaldehyde. A proper amount of water and a suitable temperature were favorable for the anisaldehyde.
- Electrooxidation,
- p-Methoxy toluene,
- Anisaldehyde,
- Ionic liquid,
- In situ Fourier transform infrared spectroscopy
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