Citation: ZHANG Jie, WANG Juan-Fen, ZHANG Jian-Jun. Synthesis, Characterization and Thermal Decomposition Mechanism of Rare Earth Complexes with 5-Chloro-2-methoxybenzoic Acid and 1,10-Phenanthroline[J]. Acta Physico-Chimica Sinica, ;2012, 28(02): 290-296. doi: 10.3866/PKU.WHXB201112121 shu

Synthesis, Characterization and Thermal Decomposition Mechanism of Rare Earth Complexes with 5-Chloro-2-methoxybenzoic Acid and 1,10-Phenanthroline

1.
1. Shijiazhuang Pharmaceutical Group, Hebei Zhongrun Pharmaceutical Co., Ltd., Shijiazhuang 050041, P. R. China;
2. Experimental Center, Hebei Normal University, Shijiazhuang 050016, P. R. China

Received Date: 2 September 2011
Available Online: 12 December 2011
Fund Project: 国家自然科学基金(20773034, 21073053)资助项目 (20773034, 21073053)

Three rare earth complexes of [Ln(5-Cl-2MOBA)₃phen]₂ (Ln=Nd(1), Eu(2), Ho(3); 5-Cl- 2MOBA: 5-chloro-2-methoxybenzoate; phen: 1,10-phenanthroline) were synthesized and characterized by elemental analysis, thermogravimetry-differential thermogravimetry-differential scanning calorimetry (TG-DTG-DSC), infrared (IR) spectra, ultraviolet (UV) spectra, and molar conductance techniques. The fluorescence spectra showed that complex (2) emitted a characteristic fluorescence of the Eu³⁺ ions. The thermal properties are discussed by thermogravimetry - differential scanning calorimetry / Fourier transform infrared (TG-DSC/FTIR) techniques. And the three-dimensional IR accumulation spectra for the three complexes were also analyzed.
1. [1]
  (1) Bian, Z. Q.; Gao, D. Q.; Guan, M.; Xin, H.; Li, F. Y.;Wang, K. Z.; Jin, L. P.; Huang, C. H. Sci.China Ser. B- Chem. 2004, 34 (2) , 113 [卞祖强, 高德青, 关敏, 辛颢, 李富友, 王科志, 金林培, 黄春辉. 中国科学B辑-化学, 2004, 34 (2), 113.]
2. [2]
  (2) Ma, R. X.; Chen, Z. M.; Gao, Z. H.;Wang, S. P.;Wang, R. F.; Zhang, J. J. Synthetic Met. 2009, 159 (13), 1272.
3. [3]
  (3) Zhao, N.;Wang, S. P.; Ma, R. X.; Gao, Z. H.;Wang, R. F.; Zhang, J. J. J. Alloy. Compd. 2008, 463, 338.
4. [4]
  (4) Li, Y.; Zheng, F. K.; Liu, X.; Zou,W. Q.; Guo, G. C.; Lu, C. Z.; Huang, J. S. Inorg Chem. 2006, 45, 6308.
5. [5]
  (5) Ferenc,W.; Bocian B. J. Therm. Anal. Calorim. 2001, 63, 309.
6. [6]
  (6) Wieslawa, F.; Agnieszka,W. D. J. Therm. Anal. Calorim. 2003, 74, 511.
7. [7]
  (7) Yszczek, R. J . Therm. Anal. Calorim. 2007, 90, 533.
8. [8]
  (8) Ye, H. M.; Ren, N.; Zhang, J. J.; Sun, S. J.;Wang, J. F. New . J . Chem. 2010, 34, 533.
9. [9]
  (9) Tian, L.; Ren, N.; Zhang, J. J.; Liu, H. M.; Bai, J. H.; Ye, H. M.; Sun, S. J. Inorg . Chim . Acta 2009, 362, 3388.
10. [10]
  (10) Zhang, H.Y.; Ren, N.; Tian, L.; Zhang, J. J. J. Therm. Anal. Calorim. 2009, 98, 401.
11. [11]
  (11) Ye, H. M.; Ren, N.; Zhang, J. J.; Sun, S. J.;Wang, J. F. Struct Chem. 2010, 21, 165
12. [12]
  (12) Wang, J. F.; Ren, N.; Meng, F.T.; Zhang, J. J. Thermochimica Acta 2011, 512, 118.
13. [13]
  (13) Wang, J. F.; Meng, F.T.; Xu, S. L.; Liu, X.; Zhang, J. J. Thermochimica Acta 2011, 521, 2
14. [14]
  (14) Geary,W. J. Coord. Chem. Rev. 1971, 7, 81
15. [15]
  (15) Shi, Y. Z.; Sun, X. Z.; Jiang, Y H. Spectrum and Chemical Identification of Organic Compounds; Science and Technology Press: Nanjing, 1988; p 98. [施耀曾, 孙祥祯, 蒋燕灏. 有机化合物光谱和化学鉴定. 南京: 江苏科学技术出版社, 1988: 98.]
16. [16]
  (16) Wang, R. F.; Jin, L. P.;Wang, M. Z.; Huang, S. H.; Chen, X. T. Acta Chim. Sin. 1995, 53, 39. [王瑞芬, 金林培, 王明昭, 黄世华, 陈学太. 化学学报, 1995, 53, 39.]
17. [17]
  (17) Bai, G. B.; Chen, G. D.;Wang, Z. M.; Yuan, L.; Kang, Z.W.; Gao, J. Z. Chin . J . Inorg . Chem. 1988, 4 (2), 32. [白光弼, 陈广德, 王喆明, 袁莉, 康致万, 高锦章. 无机化学学报, 1988, 4 (2),32.]
18. [18]
  (18) An, B. L.; ng, M. L.; Li, M. X.; Zhang, J. M. J . Mol . Struct. 2004, 687, 1.
19. [19]
  (19) Wang, L. F.;Wu, J. G.; Peng, Z. R.; Ran,W.; Yan, G. H. Chin . J . Inorg . Chem. 1990, 6 (2), 141. [王流芳, 吴集贵, 彭周人, 冉卫, 晏国洪. 无机化学学报, 1990, 6 (2), 141.]
20. [20]
  (20) Zhang, Y.; Jin, L. P.; Lü, S. Z. Chin . J . Inorg . Chem. 1997, 9 (3), 44. [张颖, 金林培, 吕少哲. 无机化学学报, 1997, 9 (3), 44.]
21. [21]
  (21) Zhao, Y. L.; An, X. P.;Wang, L. M.; Bao, J. R. J. Chin. Soc. Rare Earth. 2004, 22 (2), 26. [赵永亮, 安晓萍, 王连蒙, 宝金荣. 中国稀土学报, 2004, 22 (2), 26.]
22. [22]
  (22) Zhang, R. H.; Shen, B.W. Rare Earth Elements Chemistry; Tianjin Science and Technology Press: Tianjin, 1987; p44, 71. [张若桦, 申泮文. 稀土元素化学. 天津: 天津科学技术出版社, 1987: 44, 71.]
23. [23]
  (23) Ren, N.; Zhang, J.J.; Xu, S. L.;Wang, R. F.;Wang, S. P. Thermochimica Acta 2005, 438, 172.
24. [24]
  (24) Wang, J. F.; Zhang, D. H.; Liu, X.;Wu, K. Z.; Zhang, J. J. J. Chem. Eng. Data 2010, 55, 5608.
25. [25]
  (25) Xie, J. X.; Chang, J. B.;Wang, X. M. Infrared Spectroscopy in Organic Chemistry and Medicinal Chemistry Application; Science Press: Beijing, 2001; p163, 286. [谢晶曦, 常俊标, 王绪明. 红外光谱在有机化学和药物化学中的应用. 北京: 科学出版社, 2001; 163, 286.]
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