Citation: MAO Jing, DAI Ke-Hua, ZHAI Yu-Chun. High Rate Capability and Cycling Stability of Li_1.07Mn_1.93O₄ Nanoflakes Synthesized via Gel-Combustion Method[J]. Acta Physico-Chimica Sinica, ;2012, 28(02): 349-354. doi: 10.3866/PKU.WHXB201112052 shu

High Rate Capability and Cycling Stability of Li_1.07Mn_1.93O₄ Nanoflakes Synthesized via Gel-Combustion Method

1.
School of Materials and Metallurgy, Northeastern University, Shenyang 110004, P. R. China

Received Date: 18 July 2011
Available Online: 5 December 2011

Li_1.07Mn_1.93O₄ nanoflakes were synthesized by a gel-combustion method using polyvinylpyrrolidone (PVP) as the polymer chelating agent and fuel. Thermogravimetric and differential thermal analyses (TG/DTA) were used to investigate the combustion process of the gel precursor. X-ray diffraction (XRD) analysis indicated that the as-prepared Li_1.07Mn_1.93O₄ was a pure, highly crystalline phase. Scanning electron microscopy (SEM) results showed that most of the secondary particles were nanoflakes, about 100 nm in thickness, and the primary particle of the nanoflakes was about 100 nm in size. Charge and discharge tests suggested that the Li_1.07Mn_1.93O₄ nanoflakes had excellent rate capability and od cycling stability. The initial discharge capacity was 115.4 mAh·g^-1 at a rate of 0.5C (1C=120 mAh·g^-1) and the capacity was maintained at 105.3 mAh·g^-1 at the high discharge rate of 40C. When cycling at 10C, the material retained 81% of its initial capacity after 850 cycles. Electrochemical impedance spectroscopy (EIS) tests indicated that the charge-transfer resistance (R_ct) of the Li_1.07Mn_1.93O₄ nanoflakes was much less than that of commercial Li_1.07Mn_1.93O₄.
- Lithium ion battery,
- Lithium manganese oxide,
- Combustion synthesis,
- Rate capability,
- Cycling stability
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

High Rate Capability and Cycling Stability of Li1.07Mn1.93O4 Nanoflakes Synthesized via Gel-Combustion Method

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通讯作者: 陈斌, bchen63@163.com

High Rate Capability and Cycling Stability of Li_1.07Mn_1.93O₄ Nanoflakes Synthesized via Gel-Combustion Method