Citation: LI Shuo-Qi, LIU Lu, TIAN Hui-Feng, HU Jing-Bo. High Density Attachment of Silver Nanoparticles onto an NH₂⁺ Ion Implanted Indium Tin Oxide Glass Substrate[J]. Acta Physico-Chimica Sinica, ;2011, 27(11): 2671-2676. doi: 10.3866/PKU.WHXB20111135 shu

High Density Attachment of Silver Nanoparticles onto an NH₂⁺ Ion Implanted Indium Tin Oxide Glass Substrate

LI Shuo-Qi ² ,
LIU Lu ³ ,
TIAN Hui-Feng ² ,
HU Jing-Bo ^1,2,

1.
1. Key Laboratory of Beam Technology and Material Modification of Ministry of Education, Beijing Normal University, Beijing 100875, P. R. China;
2. College of Chemistry, Beijing Normal University, Beijing 100875, P. R. China;
3. College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Received Date: 1 August 2011
Available Online: 21 September 2011
Fund Project: 国家自然科学基金(20211130505) (20211130505)

An effective approach to attach silver nanoparticles (AgNPs) directly onto an indium tin oxide (ITO) surface with high density was reported. An NH₂⁺ ion implanted ITO (NH₂/ITO) film was prepared and the AgNPs were adsorbed onto the surface of the obtained NH₂/ITO film resulting in an AgNPs-attached NH₂/ITO (AgNPs/NH₂/ITO) substrate. Characterization of stepwise changes in the ITO, NH₂/ITO, and AgNPs/NH₂/ITO surfaces were carried out using Fourier transform infrared (FT-IR) spectrometry, X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), scanning electron microscopy (SEM), ultravioletvisible (UV-Vis) spectroscopy, and electrochemical methods. Cyclic voltammtric voltammetry results indicate that the immobilized AgNPs on the NH₂/ITO electrode gave excellent electrochemical properties, implying facile electrochemical communication between the AgNPs and the ITO substrate through theby implanted amino groups. Thus, the AgNPs/NH₂/ITO surfaces are promising as new functional interfaces because AgNPs can be attached to surfaces without the use of organic binding molecules.
- Ion implantation,
- Assembly,
- Silver nanoparticle,
- Indium tin oxide
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High Density Attachment of Silver Nanoparticles onto an NH₂⁺ Ion Implanted Indium Tin Oxide Glass Substrate