Citation: ZHANG Liu-Ming, LIN Jian-Xin, WANG Rong, WEI Ke-Mei. Effect of Preparation Methods on the Catalytic Activity of Ag-Ru/CeO₂ Catalyst for Ammonia Synthesis[J]. Acta Physico-Chimica Sinica, ;2011, 27(11): 2646-2650. doi: 10.3866/PKU.WHXB20111129 shu

Effect of Preparation Methods on the Catalytic Activity of Ag-Ru/CeO₂ Catalyst for Ammonia Synthesis

1.
National Engineering Research Center of Chemical Fertilizer Catalyst, Fuzhou University, Fuzhou 350002, P.R. China

Received Date: 11 June 2011
Available Online: 19 September 2011
Fund Project: 中国石油科技创新基金(2010D-5006-0502) (2010D-5006-0502)国家科技支撑计划(2007BAE08B02)资助项目 (2007BAE08B02)

Ag-Ru/CeO₂ catalysts were prepared by co-precipitation (CP), modified deposition precipitation (MDP), and incipient-wetness impregnation (IP). The obtained catalysts were characterized by N₂ physisorption, X-ray diffraction (XRD), H₂ temperature-programmed reduction (H₂-TPR), and temperatureprogrammed desorption of nitrogen (N₂-TPD). The results showed that the ammonia synthesis activity of the Ag-Ru/CeO₂ catalyst prepared by incipient-wetness impregnation was 9.4% at 10 MPa, 10000 h^-1 and 400°C, which was higher than that obtained by other methods. There were obvious differences in the reduction property of Ru/CeO₂ and in the nitrogen dissociation behavior among the catalysts prepared by different methods. Catalyst activity for the catalyst prepared by incipient-wetness impregnation improved greatly at a low reaction temperature. The high catalytic activity was due to the easier reduction of Ag-Ru/ CeO₂ and the higher amount of dissociation of chemisorbed nitrogen.
- Incipient-wetness impregnation,
- Ammonia synthesis,
- Silver,
- Ceria,
- Ru
1. [1]
  (1) Zheng, X. L.;Wei, K. M. Progress in Chemistry 2001, 13, 472. [郑晓玲, 魏可镁. 化学进展, 2001, 13, 472.]
2. [2]
  (2) Niwa,Y.; Aika, K. I. J. Catal. 1996, 162, 13.
3. [3]
  (3) Lin, B. Y.;Wang, R.; Lin, J. X.; Ni, J.;Wei, K. M. Catal. Commun. 2011, 12, 553.
4. [4]
  (4) You, Z. X.; Inazu, K. J.; Aika, K. I.; Baba, T. J. Catal. 2007, 251, 321.
5. [5]
  (5) Han,W. F.; Liu, H. Z.; Zhu, H. Catal. Commun. 2007, 8, 351.
6. [6]
  (6) Liang, C. H.;Wei, Z. B.; Xin, Q.; Li, C. Appl. Catal. A 2001, 208, 193.
7. [7]
  (7) Forni, L.; Molinari, D.; Rossetti, I.; Pernicone, N. Appl. Catal. A 1999, 185, 269.
8. [8]
  (8) Kowalczyk, Z.; Sentek, J.; Jodzis, S.; Mizera, E.; Góralski, J.; Paryjczak, T.; Diduszko, R. Catal. Lett. 1997, 45, 65.
9. [9]
  (9) Raróg,W.; Kowalczyk, Z.; Sentek, J.; Skladanowski, D.; Zieliński, J. Catal. Lett. 2000, 68, 163.
10. [10]
  (10) Kowalczyk, Z.; Jodzis, S.; Raróg ,W.; Zielinski, J.; Pielaszek, J. Appl. Catal. A 1998, 173, 153.
11. [11]
  (11) Larichev, Y.; Shlyapin, D.; Tsyrul’nikov, P.; Bukhtiyarov, V. Catal. Lett. 2008, 120, 204.
12. [12]
  (12) Guraya, M.; Sprenger, S.; Rarog-Pilecka,W.; Szmigiel, D.; Kowalczyk, Z.; Muhler, M. Appl. Surf. Sci. 2004, 238, 77.
13. [13]
  (13) Hansen, T.W.; Hansen, P. L.; Dahl, S.; Jacobsen, C. J. H. Catal. Lett. 2002, 84, 7.
14. [14]
  (14) Rossetti, I.; Pernicone, N.; Forni, L. Appl. Catal. A 2001, 208, 271.
15. [15]
  (15) Aika, K. I.; Kawahara, T.; Murata, S.; Onishi, T. Bull. Chem. Soc. Jpn. 1990, 63, 1221.
16. [16]
  (16) Raróg-Pilecka,W.; Miskiewicz, E.; Jodzis, S.; Petryk, J.; Lomot, D.; Kaszkur, Z.; Karpinski, Z.; Kowalczyk, Z. J. Catal. 2006, 239, 313.
17. [17]
  (17) Wang, L. X.; Zhu, H.; Xia,W. Q.; Liu, H. Z. Chinese Journal of Catalysis 2000, 21, 276. [王晓南, 朱虹, 夏伟琴, 刘化章. 催化学报, 2000, 21, 276.]
18. [18]
  (18) Fu,W. J.; Zheng, X. L.; Yu, Y. B.; Zhang, S. J. Xu, J. X.;Wei, K. M. Journal of Fuel Chemistry and Technology 2003, 31, 86. [傅武俊, 郑晓玲, 俞裕斌, 张淑娟, 许交兴, 魏可镁. 燃料化学学报, 2003, 31, 86.]
19. [19]
  (19) Izumi, Y.; Iwata, Y.; Aika, K. I.; J. Phys. Chem. 1996, 100, 9421.
20. [20]
  (20) Saito, M.; Itoh, M.; Iwamoto, J.; Li, C. Y.; Machida, K. I. Catal. Lett. 2006, 106, 107.
21. [21]
  (21) Zhang, H. Y.; Zhu, A. M.;Wang, X. K.;Wang, Y.; Shi, C. Catal. Commun. 2007, 8, 612.
22. [22]
  (22) Kayama, T.; Yamazaki, K.; Shinjoh, H. J . Am. Chem. Soc. 2010, 132, 13154.
23. [23]
  (23) Ni, J.;Wang, R.; Lin, J. X.;Wei, K. M. Chin. J. Catal. 2009, 30, 185.
24. [24]
  (24) Hosokawa, S.; Kanai, H.; Utani, K.; Taniguchi, Y.; Saito, Y.; Imamura, S. Appl. Catal. B 2003, 45, 181.
25. [25]
  (25) Wang, X. Y.; Ni, J.; Lin, B. Y.;Wang, R.; Lin, J. X.;Wei, K. M. Catal. Commun. 2010, 12, 251.
26. [26]
  (26) Niwa, Y.; Aika, K. I. Chem. Lett. 1996, 25, 3.
1. [1]
  Laiying Zhang , Yaxian Zhu . Exploring the Silver Family. University Chemistry, 2024, 39(9): 1-4. doi: 10.12461/PKU.DXHX202409015
2. [2]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
3. [3]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
4. [4]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
5. [5]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
6. [6]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
7. [7]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
8. [8]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
9. [9]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
10. [10]
  Bingliang Li , Yuying Han , Dianyang Li , Dandan Liu , Wenbin Shang . One-Step Synthesis of Benorilate Guided by Green Chemistry Principles and in vivo Dynamic Evaluation. University Chemistry, 2024, 39(6): 342-349. doi: 10.3866/PKU.DXHX202311070
11. [11]
  Hui Shi , Shuangyan Huan , Yuzhi Wang . Ideological and Political Design of Potassium Permanganate Oxidation-Reduction Titration Experiment. University Chemistry, 2024, 39(2): 175-180. doi: 10.3866/PKU.DXHX202308042
12. [12]
  Qijin Mo , Meifang Zhuo , Zhiyi Zhong , Chunfang Gan , Lixia Zhang . Research-Oriented Experimental Teaching in Chemistry Education at Normal University: Taking the Project of Recovering Silver Nitrate from Silver-Containing Waste as an Example. University Chemistry, 2024, 39(6): 201-206. doi: 10.3866/PKU.DXHX202310099
13. [13]
  Yuan Zheng , Quan Lan , Zhenggen Zha , Lingling Li , Jun Jiang , Pingping Zhu . Teaching Reform of Organic Synthesis Experiments by Introducing Reverse Thinking and Design Concepts: Taking the Synthesis of Cinnamic Acid Based on Retrosynthetic Analysis as an Example. University Chemistry, 2024, 39(6): 207-213. doi: 10.3866/PKU.DXHX202310065
14. [14]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
15. [15]
  Yuanyi Lu , Jun Zhao , Hongshuang Li . Silver-Catalyzed Ring-Opening Minisci Reaction: Developing a Teaching Experiment Suitable for Undergraduates. University Chemistry, 2024, 39(11): 225-231. doi: 10.3866/PKU.DXHX202401088
16. [16]
  Zhen Yao , Bing Lin , Youping Tian , Tao Li , Wenhui Zhang , Xiongwei Liu , Wude Yang . Visible-Light-Mediated One-Pot Synthesis of Secondary Amines and Mechanistic Exploration. University Chemistry, 2024, 39(5): 201-208. doi: 10.3866/PKU.DXHX202311033
17. [17]
  Haiyuan Wang , Yiming Tang , Haoran Guo , Guohui Chen , Yajing Sun , Chao Zhao , Zhen Zhang . Comprehensive Chemistry Experimental Teaching Design Based on the Integration of Science and Education: Preparation and Catalytic Properties of Silver Nanomaterials. University Chemistry, 2024, 39(10): 219-228. doi: 10.12461/PKU.DXHX202404067
18. [18]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
19. [19]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
20. [20]
  Yinwu Su , Xuanwen Zheng , Jianghui Du , Boda Li , Tao Wang , Zhiyan Huang . Green Synthesis of 1,3-Dibromoacetone Using Halogen Exchange Method: Recommending a Basic Organic Synthesis Teaching Experiment. University Chemistry, 2024, 39(5): 307-314. doi: 10.3866/PKU.DXHX202311092

Get Citation

PDF

XML

Metrics

PDF Downloads(971)
Abstract views(2192)
HTML views(1)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of Preparation Methods on the Catalytic Activity of Ag-Ru/CeO2 Catalyst for Ammonia Synthesis

Metrics

通讯作者: 陈斌, bchen63@163.com

Effect of Preparation Methods on the Catalytic Activity of Ag-Ru/CeO₂ Catalyst for Ammonia Synthesis