Citation: LIU Li, TIAN Fang-Hua, WANG Xian-You, ZHOU Meng. Electrochemical Behavior of LiV₃O₈ in Aqueous Li₂SO₄ Solution[J]. Acta Physico-Chimica Sinica, ;2011, 27(11): 2600-2604. doi: 10.3866/PKU.WHXB20111126 shu

Electrochemical Behavior of LiV₃O₈ in Aqueous Li₂SO₄ Solution

LIU Li ^1,2, ,
TIAN Fang-Hua ¹ ,
WANG Xian-You ^1,2 ,
ZHOU Meng ¹

1.
1. Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, School of Chemistry, Xiangtan 411105, Hunan Province, P. R. China;
2. Key Laboratory of Materials Design and Preparation Technology of Hunan Province, Xiangtan University, Xiangtan 411105, Hunan Province, P. R. China

Received Date: 13 July 2011
Available Online: 15 September 2011
Fund Project: 国家自然科学基金(20871101) (20871101) 湖南省教育厅项目(10C1250) (10C1250) 湖南省自然科学基金(11JJ4038) (11JJ4038)湖南省科技厅项目(2010RS4027)资助 (2010RS4027)

Nanostructured LiV₃O₈ powder was synthesized by a low-temperature solid-state method. Scanning election microscopy (SEM) and transmission electron microscopy (TEM) show that the as-prepared material is composed of nanostructured particles. X-ray diffraction (XRD) measurements indicate that the as-prepared material has a monoclinic structure with a space group of P2₁/m. The electrochemical properties of the LiV₃O₈ electrodes in 1 mol·L^-1 Li₂SO₄, 2 mol·L^-1 Li₂SO₄, and saturated Li₂SO₄ aqueous electrolytes were studied using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) in this work. The results show that the LiV₃O₈ electrode in the saturated Li₂SO₄ electrolyte has the best electrochemical properties. An aqueous rechargeable lithium battery (ARLB) containing a LiV₃O₈ anode, a LiNi_1/3Co_1/3Mn_1/3O₂ cathode, and a saturated Li₂SO₄ electrolyte was fabricated. The battery delivered an initial capacity of 95.2 mAh·g^-1 and retained a capacity of 37.0 mAh·g^-1 after 100 cycles at a charge-discharge rate of 0.5C (1C=300 mA·g^-1).
- Aqueous rechargeable lithium battery,
- LiV₃O₈,
- Li₂SO₄ aqueous solution,
- Aqueous electrolyte,
- Electrochemical property
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Electrochemical Behavior of LiV₃O₈ in Aqueous Li₂SO₄ Solution