Citation: LIU Jia, GUO Li-Qin, ZHANG Xiao-Hong, RUAN Wen-Juan, ZHU Zhi-Ang. Synthesis, Characterization and Properties of Salen-Type Complexes[J]. Acta Physico-Chimica Sinica, ;2012, 28(02): 265-272. doi: 10.3866/PKU.WHXB201111251 shu

Synthesis, Characterization and Properties of Salen-Type Complexes

1.
College of Chemistry, Nankai University, Tianjin 300071, P. R. China

Received Date: 8 September 2011
Available Online: 25 November 2011
Fund Project: 国家自然科学基金(20671053)资助项目 (20671053)

Two new Salen ligands H₂L¹ (N,N'-bis(3-dimethoxy-salicylidene)-4,5-dimethoxy-1,2- phenylenediamine) and H₂L² (N,N'-bis(3-dimethoxy-salicylidene)-4,5-dinitryl-1,2-phenylenediamine), and their nickel, copper, and zinc complexes ML¹, and ML² (M=Ni, Cu, Zn) were synthesized. The compounds synthesized were characterized by 1H-nuclear magnetic resonance (¹H NMR), ultraviolet-visible absorption spectrometry (UV-Vis), infrared (IR) spectrometry, mass spectroscopy (MS), and elemental analysis. The fluorescence properties of the complexes were also studied. The fluorescence intensity of ligand H₂L² was lower than that of ligand H₂L¹, because of the introduction of the strong electron-withdrawing group, ―NO₂. Moreover, the fluorescence intensities of the zinc complexes are greater than those of the ligands; however the fluorescence is quenched upon complexing of nickel or copper ions. In addition, the cyclic voltammetry shows that the redox process in CuL1 was a one-electron quasi-reversible charge-transfer. Because of the introduction of the electron-donating group ―OCH₃, the solution conductivity of ligand H₂L¹ was lower than that of H₂L².
- Salen-type complex,
- Synthesis and characterization,
- Spectrum property,
- Electrochemical property,
- Fluorescence property
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