Citation: TONG Hai-Jie, QIAN Zheng-Gang, REID Jonathan P., ZHANG Yun-Hong. High Temporal and Spatial Resolution Measurements of the Rapid Efflorescence of Sea Salt Droplets[J]. Acta Physico-Chimica Sinica, ;2011, 27(11): 2521-2527. doi: 10.3866/PKU.WHXB20111121 shu

High Temporal and Spatial Resolution Measurements of the Rapid Efflorescence of Sea Salt Droplets

1.
1. Institute of Chemical Physics, Key Laboratory of Cluster Science, Beijing Institute of Technology, Beijing 100081, P. R. China;
2. School of Chemistry, University of Bristol, Bristol, BS8 1TS, UK

Received Date: 2 June 2011
Available Online: 13 September 2011
Fund Project: 国家自然科学基金(20933001, 20873006)资助项目 (20933001, 20873006)

The rapid efflorescence of individual seawater droplets on polytetrafluoroethylene (PTFE, hydrophobic) and quartz (hydrophilic) substrates was investigated using a high-speed camera for imaging and micro-Raman spectroscopy to spatially resolve the particle composition. The morphology of the evaporating sea salt particles was captured using millisecond time resolution and micrometer spatial resolution. Upon rapid desiccation with dry N₂ on a quartz substrate, Na₂Ca₅(SO₄)₆·3H₂O and Na_2xCa_6-x(SO₄)₆· 3H₂O (0<x<1) crystallized first followed by NaCl and finally KMgCl₃·6H₂O. We determined the formation behavior of the mixed sodium-calcium salts as crystallization products during the quick desiccation process and CaSO₄·2H₂O during the slow desiccation process. In addition, the crystallization location of different crystal products were identified and the growth speed of Na₂Ca₅(SO₄)₆·3H₂O crystal was compared with that of CaSO₄·2H₂O crystal. Moreover, sea salt particles with a hollow structure were observed on the PTFE substrate at the end of the quick efflorescence process.
- Sea salt,
- High-speed photography,
- Raman spectroscopy,
- Efflorescence,
- Relative humidity
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