Citation: LIU Lei, SONG Shi-Yong, ZHANG Ping-Yu. Preparation and Micro-Tribological Study on Dually Mixed Self-Assembled Monolayers[J]. Acta Physico-Chimica Sinica, ;2012, 28(02): 427-432. doi: 10.3866/PKU.WHXB201111213 shu

Preparation and Micro-Tribological Study on Dually Mixed Self-Assembled Monolayers

1.
1. Institute of Pharmaceutics, Pharmaceutical College, Henan University, Kaifeng 475004, Henan Province, P. R. China;
2. Key Laboratory for Special Functional Materials, Ministry of Education, Kaifeng 475004, Henan Province, P. R. China

Received Date: 29 August 2011
Available Online: 21 November 2011
Fund Project: 国家自然科学基金(51005057)资助项目 (51005057)

A series of dually mixed self-assembled monolayers were prepared by a simple step-by-step method. Four carbonyl chlorides with different chain lengths were selected and assembled onto a N-[3- (trimethoxylsilyl)propyl] ethylene diamine self-assembled monolayer. Different mixed films were obtained by controlling the ratio of co-deposited carbonyl chlorides. The structures of the films were characterized by measuring their contact angles, ellipsometric thickness, and atomic force microscopy. No phase separation was observed in the mixed films. Micro-tribological studies were also carried out on the films. It was found that frictional coefficients decreased as the ratio of the longer component was increased.
- Self-assembled monolayer,
- Micro-tribology,
- Mixed film,
- Contact angle,
- Ellipsometirc thickness,
- Atomic force microscopy
1. [1]
  (1) Ulman, A. Chem. Rev. 1996, 96 ,1533.
2. [2]
  (2) (a) Gu, G. T.; Zhang, Z. J.; Dang, H. X. Acta Phys. -Chim. Sin. 2002, 18, 669. [谷国团, 张治军, 党鸿辛. 物理化学学报, 2002, 18, 669.]
3. [3]
  (b) Qian, L. P.; Deng,W. L. Acta Phys. -Chim. Sin. 2008, 24, 433. [钱丽萍, 邓文礼. 物理化学学报, 2008, 24, 433.]
4. [4]
  (3) Ostuni, E.; Yan, L.; Whitesides, G.. M. Colloid Surf. B Biointerfaces 1999, 15, 3.
5. [5]
  (4) Gulino, A.; Mineo, P.; Scamporrino, E.; Vitalini, D.; Fragala, I. Chem. Mater. 2004, 16, 1838.
6. [6]
  (5) Wang, Z.; Luo, H.; Gao, L.;Wang, K. Acta Phys. -Chim. Sin. 2011, 27, 754. [王志平, 罗虹, 高丽华, 王科志. 物理化学学报, 2011, 27, 754.]
7. [7]
  (6) Wang, M.; Liechti, K. M.;Wang, Q.; White, J. M. Langmuir 2005, 21, 1848.
8. [8]
  (7) Song, S.; Chu, R.; Zhou, J.;Yang, S.; Zhang, J. J. Phys. Chem. C 2008, 112, 3805.
9. [9]
  (8) Song, S.; J.; Zhou, Q. M.; Yang, S.; Zhang, J. Langmuir 2008, 24, 105.
10. [10]
  (9) Gershwitz, O.; Grinstein, M.; Sukenik, C. N. J. Phys. Chem. B 2004, 108, 664.
11. [11]
  (10) Monsathaporn, S.; Effenberger, F. Langmuir 2004, 20, 10375.
12. [12]
  (11) Mowery, M. D.; Kopta, S.; Ogletree, D. F.; Salmeron, M.; Evans C. E. Langmuir 1999, 15, 5118.
13. [13]
  (12) Ren, S.; Yang, S.; Zhao, Y. Langmuir 2003, 19, 2763.
14. [14]
  (13) Choi, J.; Morishita, H.; Kato, T. Appl. Surf. Sci. 2004, 228, 191.
15. [15]
  (14) Lee, B. S.; Chi, Y. S.; Lee, J. K.; Choi, I. S.; Song, C. E.; Nam ong, S. K.; Lee S. J. Am. Chem. Soc 2003, 126, 480.
16. [16]
  (15) Chi, Y. S.; Lee, J. K.; Lee, S.; Choi, I. S. Langmuir 2004, 20, 3024.
17. [17]
  (16) Xiao, X.; Hu, J.; Charych, D. H.; Salmeron, M. Langmuir 1996, 12, 235.
18. [18]
  (17) Lio, A.; Carych, D. H.; Salmeron, M. J. Phys. Chem. B 1997, 101, 3800.
19. [19]
  (18) Nakano, M.; Ishida, T.; Numata, T.; Ando, Y.; Sasaki, S. Jpn. J. Appl. Phys. Part 1. 2003, 42, 4734.
20. [20]
  (19) (a) Kim, H. I.; Graupe, M.; Oloba, O.; Koini, T.; Imaduddin, S.; Lee, T. R.; Perry, S. S. Langmuir 1999, 15, 3179.
21. [21]
  (b) Houston, J. E.; Doelling, C. M.; Vanderlick, T. K.; Hu, Y.; Scoles, G..;Wenzl, I.; Lee, T. R. Langmuir 2005, 21, 3926.
22. [22]
  (20) Brewer, N. J.; Beake, B. D.; Leggett, G.. J. Langmuir 2001, 17, 1970.
23. [23]
  (21) Brewer, N. J.; Foster, T. T.; Leggett, G. J.; Alexander, M. R.; McAlpine, E. J. Phys. Chem. B 2004, 108, 4723.
24. [24]
  (22) Noy, A.; Frisbie. C. D.; Rozsnyai, L. F.;Wrighton, M. S.; Lieber, S. M. J. Am. Chem. Soc. 1995, 117, 7943.
25. [25]
  (23) Kim, H. I.; Houston, J. E. J. Am. Chem. Soc. 2000, 122, 12045.
26. [26]
  (24) Leng, Y.; Jiang, S. J. Am. Chem. Soc. 2002, 124, 11764.
27. [27]
  (25) Brewer, N. J.; Leggett, G.. J. Langmuir 2004, 20, 4109.
28. [28]
  (26) Li, L.; Chen, S.; Jiang, S. Langmuir 2003, 19, 666.
29. [29]
  (27) Beake, B.D.; Leggett, G. J. Langmuir 2000, 16, 735.
30. [30]
  (28) Beake, B. D.; Leggett, G. J. Phys. Chem. Chem. Phys. 1999, 1, 3345.
31. [31]
  (29) Laibinis, P. E.; Nuzzo, R. G.; Whitesides, G. M. J. Phys. Chem. 1992, 96, 5097.
32. [32]
  (30) Zhang, Q.; Archer, L. A. J. Phys. Chem. B 2003, 107, 13123.
33. [33]
  (31) Zhang, Q.; Archer, L. A. Langmuir 2005, 21, 5405.
34. [34]
  (32) Bain, C. D.; Whitesides, G. M. J. Am. Chem. Soc. 1989, 111, 7164.
35. [35]
  (33) Wasserman, S. R.; Tao, Y. T.; Whitesides, G. M. S. Langmuir 1989, 5, 1074.
36. [36]
  (34) Maoz, R.; Sagiv, J. Langmuir 1987, 3, 1034.
37. [37]
  (35) Choi, I.; Kim,Y.; Kang, S. K.; Lee, J.; Yi, J. Langmuir 2006, 22, 4885.
38. [38]
  (36) McDermott, M. T.; Green, J.B. D.; Porter, M. D. Langmuir 1997, 13, 2504.
39. [39]
  (37) Foster, T. T.; Alexander, M. R.; Leggett, G. J.; McAlpine, E. Langmuir 2006, 22, 9254.
40. [40]
  (38) Lio, A.; Charych, D. H.; Salmeron, M. J. Phys. Chem. B 1997, 101, 3800.
41. [41]
  (39) Sambasivan, S.; Hsieh, S.; Fischer, D. A.; Hsu, S. M. J. Vac. Sci. Technol. A 2006, 24, 1484.
42. [42]
  (40) Lee, S.; Seok, Y. S.; Colorado, R. Jr.; Guenard, R. L.; Lee, T. R.; Perry, S. S. Langmuir 2000, 16, 2220.
1. [1]
  Qin Li , Ziyao Jia , Ye Chen , Mingze Ma , Lin Li , Tao Huang . A Journey into the Enigmatic World of Pickering Emulsion: A Chemical Science Popularization Experiment. University Chemistry, 2024, 39(9): 311-318. doi: 10.3866/PKU.DXHX202306035
2. [2]
  Chunai Dai , Yongsheng Han , Luting Yan , Zhen Li , Yingze Cao . Ideological and Political Design of Solid-liquid Contact Angle Measurement Experiment. University Chemistry, 2024, 39(2): 28-33. doi: 10.3866/PKU.DXHX202306065
3. [3]
  Peiyu Zhang , Aixin Song , Jingcheng Hao , Jiwei Cui . 高频超声法制备聚多巴胺薄膜综合实验. University Chemistry, 2025, 40(6): 210-214. doi: 10.12461/PKU.DXHX202407081
4. [4]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
5. [5]
  Wenjian Zhang , Mengxin Fan , Wenwen Fei , Wei Bai . Cultivation of Critical Thinking Ability: Based on RAFT Polymerization-Induced Self-Assembly. University Chemistry, 2025, 40(4): 108-112. doi: 10.12461/PKU.DXHX202406099
6. [6]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
7. [7]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
8. [8]
  Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
9. [9]
  Ronghui LI . Photocatalysis performance of nitrogen-doped CeO₂ thin films via ion beam-assisted deposition. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1123-1130. doi: 10.11862/CJIC.20240440
10. [10]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-. doi: 10.3866/PKU.WHXB202408012
11. [11]
  Hongyun Liu , Jiarun Li , Xinyi Li , Zhe Liu , Jiaxuan Li , Cong Xiao . Course Ideological and Political Design of a Comprehensive Chemistry Experiment: Constructing a Visual Molecular Logic System Based on Intelligent Hydrogel Film Electrodes. University Chemistry, 2024, 39(2): 227-233. doi: 10.3866/PKU.DXHX202309070
12. [12]
  Lisha LEI , Wei YONG , Yiting CHENG , Yibo WANG , Wenchao HUANG , Junhuan ZHAO , Zhongjie ZHAI , Yangbin DING . Application of regenerated cellulose and reduced graphene oxide film in synergistic power generation from moisture electricity generation and Mg-air batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1151-1161. doi: 10.11862/CJIC.20240202
13. [13]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
14. [14]
  Mengfei He , Chao Chen , Yue Tang , Si Meng , Zunfa Wang , Liyu Wang , Jiabao Xing , Xinyu Zhang , Jiahui Huang , Jiangbo Lu , Hongmei Jing , Xiangyu Liu , Hua Xu . Epitaxial Growth of Nonlayered 2D MnTe Nanosheets with Thickness-Tunable Conduction for p-Type Field Effect Transistor and Superior Contact Electrode. Acta Physico-Chimica Sinica, 2025, 41(2): 100016-. doi: 10.3866/PKU.WHXB202310029
15. [15]
  Lijuan Wang , Yuping Ning , Jian Li , Sha Luo , Xiongfei Luo , Ruiwen Wang . Enhancing the Advanced Nature of Natural Product Chemistry Laboratory Courses with New Research Findings: A Case Study of the Application of Berberine Hydrochloride in Photodynamic Antimicrobial Films. University Chemistry, 2024, 39(11): 241-250. doi: 10.12461/PKU.DXHX202403017
16. [16]
  Zhening Lou , Quanxing Mao , Xiaogeng Feng , Lei Zhang , Xu Xu , Yuyang Zhang , Xueyan Liu , Hongling Kang , Dongyang Feng , Yongku Li . Practice of Implementing Blended Teaching in Shared Analytical Chemistry Course. University Chemistry, 2024, 39(2): 263-269. doi: 10.3866/PKU.DXHX202308089
17. [17]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
18. [18]
  Huan Zhang , Linyu Pu , Wei Wang , Yatang Dai , Xu Huang . Curriculum Development and Blended Teaching Practice in the Graduate Course on Elemental Inorganic Chemistry. University Chemistry, 2024, 39(6): 166-173. doi: 10.3866/PKU.DXHX202402010
19. [19]
  Zhiguang Xu , Xuan Xu , Qiong Luo , Ganquan Wang , Bin Peng . Reform and Practice of Online and Offline Blended Teaching in Structural Chemistry Course. University Chemistry, 2024, 39(6): 195-200. doi: 10.3866/PKU.DXHX202310112
20. [20]
  Zhongxin YU , Wei SONG , Yang LIU , Yuxue DING , Fanhao MENG , Shuju WANG , Lixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304

Get Citation

PDF

XML

Metrics

PDF Downloads(729)
Abstract views(2142)
HTML views(1)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142