Citation: CHEN Ke, BAO Zhi-Hao, LIU Dong, ZHU Xiu-Rong, ZHANG Zhi-Hua, ZHOU Bin. Confined Synthesis and Properties of Porous Silicon from Silica Aerogel Templates by Magnesiothermic Reduction[J]. Acta Physico-Chimica Sinica, ;2011, 27(11): 2719-2725. doi: 10.3866/PKU.WHXB20111110 shu

Confined Synthesis and Properties of Porous Silicon from Silica Aerogel Templates by Magnesiothermic Reduction

1.
Shanghai Key Laboratory of Special Microstructure Materials and Technology, Tongji University, Shanghai 200092, P. R. China

Received Date: 18 July 2011
Available Online: 1 September 2011
Fund Project: 国家自然科学基金(51072137, 50802064) (51072137, 50802064) 国家科技支撑计划(2009BAC62B02) (2009BAC62B02) 教育部新世纪优秀人才支持计划(NCET-08-0405) (NCET-08-0405)教育部博士点基金(20090072110047, 20100072110054)资助项目 (20090072110047, 20100072110054)

Novel nanoporous silicon was successfully converted from SiO₂ aerogels by a template-confined magnesiothermic reduction at low temperature (650°C) based on a gas-solid reaction. The composition, crystal structure, morphology, and pore structure of the samples were analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), and Brunauer-Emmett- Teller (BET) surface area analysis. Their optical and electrochemical properties were also investigated. The results indicated that the products consisted of nanocrystalline silicon, retained a morphology similar to that of the original templates, and possessed a specific surface area as high as 602 m²·g^-1. They also showed red photoluminescence at room temperature and had a high capacity and od Li-ion insertion/extraction properties for use in lithium ion batteries.
- Porous silicon,
- Template-confined,
- Magnesiothermic reduction,
- Aerogel,
- High specific surface area
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