Citation: ZHAO Yong, XUE Wen-Bin, LIU Hong-Fang. Effect of Rare Earth Ce³⁺ on the Microbial Induced Corrosion Behavior of Aluminum Alloy LY12CZ[J]. Acta Physico-Chimica Sinica, ;2011, 27(11): 2618-2624. doi: 10.3866/PKU.WHXB20111109 shu

Effect of Rare Earth Ce³⁺ on the Microbial Induced Corrosion Behavior of Aluminum Alloy LY12CZ

1.
1. School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, P. R. China;
2. Institute of Low Energy Nuclear Physics, Beijing Normal University, Beijing 100875, P. R. China

Received Date: 5 July 2011
Available Online: 1 September 2011
Fund Project: 北京师范大学射线束技术与材料改性教育部重点实验室开放课题(201022)资助项目 (201022)

The effect of rare earth Ce³⁺ on the growth of sulfate reducing bacterial (SRB) and the microbial induced corrosion (MIC) of aluminum alloy LY12CZ was studied by ultraviolet spectrophotometry (UVS), maximum probable number (MPN), cyclic anodic polarization, electrochemical impedance spectroscopy (EIS), and epi-fluorescence microscopy (EFM). The results showed that the low concentrations of Ce³⁺ could promote the growth of SRB while high concentrations had an inhibiting effect. Cyclic anodic polarization curves indicated that the pitting sensitivity of LY12CZ became lower in solutions containing rare earth Ce³⁺. EIS confirmed that corrosion resistance increased with an increase in the concentration of Ce³⁺. However, when inoculated with 1% SRB, the corrosion resistance was optimal at a Ce³⁺ concentration of 0.376 mg·L^-1 because of a synergistic effect between the biofilm and the rare earth conversion film. The growth of SRB was inhibited with an increase in the Ce³⁺ concentration which prevented the biofilm forming completely on the surface of the matrix. At the moment, the effect of MIC was more notable than the protection of rare earth conversion film that formed on the surface of aluminum alloy.
- Sulfate reducing bacterial,
- Aluminum alloy LY12CZ,
- Rare earth conversion film,
- Electrochemical method,
- Hormesis effect
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of Rare Earth Ce3+ on the Microbial Induced Corrosion Behavior of Aluminum Alloy LY12CZ

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通讯作者: 陈斌, bchen63@163.com

Effect of Rare Earth Ce³⁺ on the Microbial Induced Corrosion Behavior of Aluminum Alloy LY12CZ