Citation: LIU Jian, ZHAO Zhen, WANG Hong-Xuan, DUAN Ai-Jun, JIANG Gui-Yuan. Selective Oxidation Performance of Propane over Supported Vanadium Oxide Catalysts[J]. Acta Physico-Chimica Sinica, ;2011, 27(11): 2659-2664. doi: 10.3866/PKU.WHXB20111108 shu

Selective Oxidation Performance of Propane over Supported Vanadium Oxide Catalysts

1.
State Key Laboratory of Heavy Oil, China University of Petroleum, Beijing 102249, P. R. China

Received Date: 7 June 2011
Available Online: 31 August 2011
Fund Project: 新世纪优秀人才支持计划(NCET-10-0811) (NCET-10-0811) 高等学校博士点基金(200804251016) (200804251016) 国家自然科学基金(20803093, 20833011) (20803093, 20833011) 国家高技术研究发展计划(863) (2006AA06Z313) (863) (2006AA06Z313)中石油项目及创新基金(2010D-4604-0402)资助项目 (2010D-4604-0402)

A series of SBA-15 supported vanadium oxide catalysts with different active components were prepared by the method of incipient-wet impregnation. The structures of the catalysts were characterized by N₂ adsorption, X-ray diffraction (XRD), ultraviolet (UV)-Raman, Fourier transform infrared (FTIR), and ultraviolet-visble diffuse reflectance spectroscopy (UV-Vis DRS) techniques, and their catalytic performances for the selective oxidation of propane were investigated. The results showed that SBA-15 was a better support in the catalyst system than SiO₂ for the selective oxidation of propane to aldehydes. The SBA-15 supported low loading catalyst is a highly dispersed catalyst system and the SBA-15 supported vanadium oxide samples with low loading (n(V)/n(Si)<2.5%) have ordered hexa nal mesostructures. For the VO_x/SBA-15 catalysts, isolated vanadyl species with tetrahedral coordination are the active sites for aldehyde formation at very low loadings of vanadium (n(V)/n(Si)<0.1%). The polymeric vanadyl species with octahedral coordination and microcrystalline vanadium oxide are active sites for the oxidative dehydrogenation or deep oxidation of propane when the loading of vanadium (n(V)/n(Si)) is higher than 2.5%.
- Selective oxidation of propane,
- Catalyst,
- SBA-15 mesoporous molecular sieve,
- Supported vanadium oxide,
- Characterization
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沈阳化工大学材料科学与工程学院沈阳 110142