Citation: LIU Ling-Ling, DING Lei, XU Li, QIAO Jin-Li, SHENG Jia-Wei. Synthesis and Properties of Chemically Cross-Linked Poly(vinyl alcohol) Modified Quaterized Hydroxyethylcellulose Ethoxylate as Novel Alkaline Anion-Exchange Membrane[J]. Acta Physico-Chimica Sinica, ;2011, 27(11): 2665-2670. doi: 10.3866/PKU.WHXB20111106 shu

Synthesis and Properties of Chemically Cross-Linked Poly(vinyl alcohol) Modified Quaterized Hydroxyethylcellulose Ethoxylate as Novel Alkaline Anion-Exchange Membrane

1.
1. College of Environmental Science and Engineering, Donghua University, Shanghai 201620, P. R. China;
2. College of Chemical Engineering and Materials, Zhejiang Industrial University, Hangzhou 310032, P. R. China

Received Date: 13 June 2011
Available Online: 30 August 2011
Fund Project: 国家自然科学基金(21173039) (21173039) 上海市浦江人才基金(08PJ14096) (08PJ14096) 上海市自然科学基金(09ZR1433300) (09ZR1433300) 浙江省重中之重学科开放基金(20110927) (20110927) 教育部归国留学人员基金(2009(1001)) (2009(1001))上海市重点学科项目(B604)资助项目 (B604)

Much attention has been paid to alkaline ion-exchange membranes with high alkaline stability. In this work, chemically cross-linked poly(vinyl alcohol) modified quaterized hydroxyethylcellulose ethoxylate (PVA/QHECE) membranes were prepared and evaluated as OH^--conducting polymer electrolytes. The membranes were characterized using Fourier transform infrared (FTIR) spectra, thermogravimetric (TG) analysis, and the alternating current (AC) impedance technique as for their inner structure, thermal stability, alkaline resistance stability, and OH^- conductivity (σ). The OH^- conductivity of the membranes was investigated as a function of cross-linking time, the content of cross-linking agent, polymer composition, and water uptake. It was found that membrane swelling decreased with cross-linking time accompanied by an improvement in mechanical properties but no obvious decrease in OH^- conductivity resulted from the reduced water uptake. The OH^- conductivities in the range of 3.26×10^-4-4.44×10^-4 S·cm^-1 were obtained at room temperature ((19 ± 2)°C), depending on the different PVA/QHECE compositions. TG analysis showed that the PVA/QHECE membrane exhibited high thermal stability at up to 260°C when the QHECE content was 42.9%. In addition, the membranes had a high alkaline stability without a loss of integrity and OH^- conductivity after immersion in 6 mol·L^-1 KOH at 80°C for 168 h.
- Alkaline anion-exchange membrane,
- PVA,
- QHECE,
- Blending and chemical crosslinking,
- OH^- conductivity,
- Alkaline resistance stability
References
1. [1]
  (1) Kim, S.; Hong, I. J. Ind. Eng. Chem. 2010, 16, 901.
2. [2]
  (2) Varcoe, J. R.; Slade, R. C. T. Fuel cells 2005, 5, 187.
3. [3]
  (3) Savado , O. J. Power Sources 2004, 127, 135.
4. [4]
  (4) Kima, J.; Mommab, T.; Osakaa, T. J. Power Sources 2009, 189, 999.
5. [5]
  (5) Abuin, G. C.; Nonjola, P.; Franceschini, E. A.; Izraelevitch, F. H.; Mathe, M. K.; Corti, H. R. Int. J. Hydrog. Energy 2010, 35, 5850.
6. [6]
  (6) Wang, G. G.;Weng, Y. M.; Chu, D.; Chen, R. R.; Xie, D. J. Membr. Sci. 2009, 332, 63.
7. [7]
  (7) Yu, E. H.; Scott, K. J. Power Sources 2004, 137, 248.
8. [8]
  (8) Komkova, E. N.; Stamatialis, D. F.; Strathmann; H.;Wessling; M. J. Membr. Sci. 2004, 244, 25.
9. [9]
  (9) Lebrun, L.; Follain, N.; Metayer, M. Electrochim. Acta 2004, 50, 985.
10. [10]
  (10) Choi, Y. J.; Park, J. M.; Yeon, K. H.; Moon, S. H. J. Membr. Sci. 2005, 250, 295.
11. [11]
  (11) Carvalho, L. B., Jr.; Araujo, A. M.; Almeda, A. M. P.; Azevedo, W. M. Sensors and Actuators B. 1996, 35 -36, 427.
12. [12]
  (12) Park, J. S.; Park, J.W.; Ruckenstein, E. J. Appl. Polym. Sci. 2001, 80, 1825.
13. [13]
  (13) Mohamad, A. A.; Arof, A. K. Mater. Lett. 2007, 61, 3096.
14. [14]
  (14) Zhang, S.; Li, F. X.; Yu, G. Y. Hsieh, Y. L. Carbohydrate Polymers 2010, 81, 668.
15. [15]
  (15) Zhbankov, R. G.; Firsov, S. P.; Buslov, D. K.; Nikonenko, N. A.; Marchewka, M. K.; Ratajczak, H. J. Mol. Struct. 2002, 614, 117.
16. [16]
  (16) Chen, N.; Li, L.;Wang, Q. Plastic, Rubber and Composites: Macromolecular Engineering 2007, 36, 283.
17. [17]
  (17) Gindl,W.; Martinschitz, K. J.; Boesecke, P.; Keckes, J. Compos. Sci. Technol. 2006, 66, 2639.
18. [18]
  (18) Sakellariou, P.; Hassan, A.; Rowe, R. C. Polymer 1993, 34, 1240.
19. [19]
  (19) Chen, Y.; Cao, X. D.; Chang, P. R.; Huneault, M. A. Carbohydrate Polymers 2008, 73, 8.
20. [20]
  (20) Zhang,W.; Yang, X. L.; Li, C. Y.; Liang, M.; Lu, C. H.; Deng, Y. L. Carbohydrate Polymers 2011, 83, 258.
21. [21]
  (21) Sun, T.; Du,W.; Liu, D. H.; Dai, L. M. Process Biochemistry. 2010, 45, 1192.
22. [22]
  (22) Yeom, C. K.; Lee, K. H. J. Membr. Sci. 1996, 109, 257.
23. [23]
  (23) Qiao, J. L.; Hamaya, T.; Okada, T. Chem. Mater. 2005, 17, 2415.
24. [24]
  (24) Qiao, J. L.; Hamaya, T.; Okada, T. Polymer 2005, 46, 10810.
25. [25]
  (25) Qiao, J. L.; Okada, T. Electrochem. Solid State Lett. 2006, 9, A379.
26. [26]
  (26) Fu, J.; Qiao, J. L.; Ma, J. X. Chem. J. Chin. Univ. 2011, 32, 1. [傅婧, 乔锦丽, 马建新. 高等学校化学学报, 2011, 32, 1.]
27. [27]
  (27) Qiao, J. L.; Fu, J.; Lv, H.; Ma, J. X. Polymer 2010, 51, 4850.
28. [28]
  (28) Li, L.;Wang, Y. X. J. Membr. Sci. 2005, 262, 1.
1. [1]
  (1) Kim, S.; Hong, I. J. Ind. Eng. Chem. 2010, 16, 901.
2. [2]
  (2) Varcoe, J. R.; Slade, R. C. T. Fuel cells 2005, 5, 187.
3. [3]
  (3) Savado , O. J. Power Sources 2004, 127, 135.
4. [4]
  (4) Kima, J.; Mommab, T.; Osakaa, T. J. Power Sources 2009, 189, 999.
5. [5]
  (5) Abuin, G. C.; Nonjola, P.; Franceschini, E. A.; Izraelevitch, F. H.; Mathe, M. K.; Corti, H. R. Int. J. Hydrog. Energy 2010, 35, 5850.
6. [6]
  (6) Wang, G. G.;Weng, Y. M.; Chu, D.; Chen, R. R.; Xie, D. J. Membr. Sci. 2009, 332, 63.
7. [7]
  (7) Yu, E. H.; Scott, K. J. Power Sources 2004, 137, 248.
8. [8]
  (8) Komkova, E. N.; Stamatialis, D. F.; Strathmann; H.;Wessling; M. J. Membr. Sci. 2004, 244, 25.
9. [9]
  (9) Lebrun, L.; Follain, N.; Metayer, M. Electrochim. Acta 2004, 50, 985.
10. [10]
  (10) Choi, Y. J.; Park, J. M.; Yeon, K. H.; Moon, S. H. J. Membr. Sci. 2005, 250, 295.
11. [11]
  (11) Carvalho, L. B., Jr.; Araujo, A. M.; Almeda, A. M. P.; Azevedo, W. M. Sensors and Actuators B. 1996, 35 -36, 427.
12. [12]
  (12) Park, J. S.; Park, J.W.; Ruckenstein, E. J. Appl. Polym. Sci. 2001, 80, 1825.
13. [13]
  (13) Mohamad, A. A.; Arof, A. K. Mater. Lett. 2007, 61, 3096.
14. [14]
  (14) Zhang, S.; Li, F. X.; Yu, G. Y. Hsieh, Y. L. Carbohydrate Polymers 2010, 81, 668.
15. [15]
  (15) Zhbankov, R. G.; Firsov, S. P.; Buslov, D. K.; Nikonenko, N. A.; Marchewka, M. K.; Ratajczak, H. J. Mol. Struct. 2002, 614, 117.
16. [16]
  (16) Chen, N.; Li, L.;Wang, Q. Plastic, Rubber and Composites: Macromolecular Engineering 2007, 36, 283.
17. [17]
  (17) Gindl,W.; Martinschitz, K. J.; Boesecke, P.; Keckes, J. Compos. Sci. Technol. 2006, 66, 2639.
18. [18]
  (18) Sakellariou, P.; Hassan, A.; Rowe, R. C. Polymer 1993, 34, 1240.
19. [19]
  (19) Chen, Y.; Cao, X. D.; Chang, P. R.; Huneault, M. A. Carbohydrate Polymers 2008, 73, 8.
20. [20]
  (20) Zhang,W.; Yang, X. L.; Li, C. Y.; Liang, M.; Lu, C. H.; Deng, Y. L. Carbohydrate Polymers 2011, 83, 258.
21. [21]
  (21) Sun, T.; Du,W.; Liu, D. H.; Dai, L. M. Process Biochemistry. 2010, 45, 1192.
22. [22]
  (22) Yeom, C. K.; Lee, K. H. J. Membr. Sci. 1996, 109, 257.
23. [23]
  (23) Qiao, J. L.; Hamaya, T.; Okada, T. Chem. Mater. 2005, 17, 2415.
24. [24]
  (24) Qiao, J. L.; Hamaya, T.; Okada, T. Polymer 2005, 46, 10810.
25. [25]
  (25) Qiao, J. L.; Okada, T. Electrochem. Solid State Lett. 2006, 9, A379.
26. [26]
  (26) Fu, J.; Qiao, J. L.; Ma, J. X. Chem. J. Chin. Univ. 2011, 32, 1. [傅婧, 乔锦丽, 马建新. 高等学校化学学报, 2011, 32, 1.]
27. [27]
  (27) Qiao, J. L.; Fu, J.; Lv, H.; Ma, J. X. Polymer 2010, 51, 4850.
28. [28]
  (28) Li, L.;Wang, Y. X. J. Membr. Sci. 2005, 262, 1.
1. [1]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
2. [2]
  Renqing Lü , Shutao Wang , Fang Wang , Guoping Shen . Computational Chemistry Aided Organic Chemistry Teaching: A Case of Comparison of Basicity and Stability of Diazine Isomers. University Chemistry, 2025, 40(3): 76-82. doi: 10.12461/PKU.DXHX202404119
3. [3]
  Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
4. [4]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
5. [5]
  Shitao Fu , Jianming Zhang , Cancan Cao , Zhihui Wang , Chaoran Qin , Jian Zhang , Hui Xiong . Study on the Stability of Purple Cabbage Pigment. University Chemistry, 2024, 39(4): 367-372. doi: 10.3866/PKU.DXHX202401059
6. [6]
  Jiaxi Xu , Yuan Ma . Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide. University Chemistry, 2024, 39(11): 374-377. doi: 10.3866/PKU.DXHX202402049
7. [7]
  Xuewei BA , Cheng CHENG , Huaikang ZHANG , Deqing ZHANG , Shuhua LI . Preparation and luminescent performance of Sr_1-xZrSi₂O₇∶xDy³⁺ phosphor with high thermal stability. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 357-364. doi: 10.11862/CJIC.20240096
8. [8]
  Baitong Wei , Jinxin Guo , Xigong Liu , Rongxiu Zhu , Lei Liu . Theoretical Study on the Structure, Stability of Hydrocarbon Free Radicals and Selectivity of Alkane Chlorination Reaction. University Chemistry, 2025, 40(3): 402-407. doi: 10.12461/PKU.DXHX202406003
9. [9]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
10. [10]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
11. [11]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
12. [12]
  Jihua Deng , Xinshi Wu , Dichang Zhong . Exploration of Green Teaching and Ideological and Political Education in Chemical Experiment of “Preparation of Ammonium Ferrous Sulfate”. University Chemistry, 2024, 39(10): 325-329. doi: 10.12461/PKU.DXHX202405046
13. [13]
  Yifeng TAN , Ping CAO , Kai MA , Jingtong LI , Yuheng WANG . Synthesis of pentaerythritol tetra(2-ethylthylhexoate) catalyzed by h-MoO₃/SiO₂. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2155-2162. doi: 10.11862/CJIC.20240147
14. [14]
  Xinhao Yan , Guoliang Hu , Ruixi Chen , Hongyu Liu , Qizhi Yao , Jiao Li , Lingling Li . Polyethylene Glycol-Ammonium Sulfate-Nitroso R Salt System for the Separation of Cobalt (II). University Chemistry, 2024, 39(6): 287-294. doi: 10.3866/PKU.DXHX202310073
15. [15]
  Hong Wu , Yuxi Wang , Hongyan Feng , Xiaokui Wang , Bangkun Jin , Xuan Lei , Qianghua Wu , Hongchun Li . Application of Computational Chemistry in the Determination of Magnetic Susceptibility of Metal Complexes. University Chemistry, 2025, 40(3): 116-123. doi: 10.12461/PKU.DXHX202405141
16. [16]
  Aili Feng , Xin Lu , Peng Liu , Dongju Zhang . Computational Chemistry Study of Acid-Catalyzed Esterification Reactions between Carboxylic Acids and Alcohols. University Chemistry, 2025, 40(3): 92-99. doi: 10.12461/PKU.DXHX202405072
17. [17]
  Yiping HUANG , Liqin TANG , Yufan JI , Cheng CHEN , Shuangtao LI , Jingjing HUANG , Xuechao GAO , Xuehong GU . Hollow fiber NaA zeolite membrane for deep dehydration of ethanol solvent by vapor permeation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 225-234. doi: 10.11862/CJIC.20240224
18. [18]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
19. [19]
  Yanan Jiang , Yuchen Ma . Brief Discussion on the Electronic Exchange Interaction in Quantum Chemistry Computations. University Chemistry, 2025, 40(3): 10-15. doi: 10.12461/PKU.DXHX202402058
20. [20]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149

Get Citation

PDF

XML

Metrics

PDF Downloads(1024)
Abstract views(2717)
HTML views(14)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Properties of Chemically Cross-Linked Poly(vinyl alcohol) Modified Quaterized Hydroxyethylcellulose Ethoxylate as Novel Alkaline Anion-Exchange Membrane

References

Metrics

通讯作者: 陈斌, bchen63@163.com