Citation: LIU Ling-Ling, DING Lei, XU Li, QIAO Jin-Li, SHENG Jia-Wei. Synthesis and Properties of Chemically Cross-Linked Poly(vinyl alcohol) Modified Quaterized Hydroxyethylcellulose Ethoxylate as Novel Alkaline Anion-Exchange Membrane[J]. Acta Physico-Chimica Sinica, ;2011, 27(11): 2665-2670. doi: 10.3866/PKU.WHXB20111106 shu

Synthesis and Properties of Chemically Cross-Linked Poly(vinyl alcohol) Modified Quaterized Hydroxyethylcellulose Ethoxylate as Novel Alkaline Anion-Exchange Membrane

1.
1. College of Environmental Science and Engineering, Donghua University, Shanghai 201620, P. R. China;
2. College of Chemical Engineering and Materials, Zhejiang Industrial University, Hangzhou 310032, P. R. China

Received Date: 13 June 2011
Available Online: 30 August 2011
Fund Project: 国家自然科学基金(21173039) (21173039) 上海市浦江人才基金(08PJ14096) (08PJ14096) 上海市自然科学基金(09ZR1433300) (09ZR1433300) 浙江省重中之重学科开放基金(20110927) (20110927) 教育部归国留学人员基金(2009(1001)) (2009(1001))上海市重点学科项目(B604)资助项目 (B604)

Much attention has been paid to alkaline ion-exchange membranes with high alkaline stability. In this work, chemically cross-linked poly(vinyl alcohol) modified quaterized hydroxyethylcellulose ethoxylate (PVA/QHECE) membranes were prepared and evaluated as OH^--conducting polymer electrolytes. The membranes were characterized using Fourier transform infrared (FTIR) spectra, thermogravimetric (TG) analysis, and the alternating current (AC) impedance technique as for their inner structure, thermal stability, alkaline resistance stability, and OH^- conductivity (σ). The OH^- conductivity of the membranes was investigated as a function of cross-linking time, the content of cross-linking agent, polymer composition, and water uptake. It was found that membrane swelling decreased with cross-linking time accompanied by an improvement in mechanical properties but no obvious decrease in OH^- conductivity resulted from the reduced water uptake. The OH^- conductivities in the range of 3.26×10^-4-4.44×10^-4 S·cm^-1 were obtained at room temperature ((19 ± 2)°C), depending on the different PVA/QHECE compositions. TG analysis showed that the PVA/QHECE membrane exhibited high thermal stability at up to 260°C when the QHECE content was 42.9%. In addition, the membranes had a high alkaline stability without a loss of integrity and OH^- conductivity after immersion in 6 mol·L^-1 KOH at 80°C for 168 h.
- Alkaline anion-exchange membrane,
- PVA,
- QHECE,
- Blending and chemical crosslinking,
- OH^- conductivity,
- Alkaline resistance stability
1. [1]
  (1) Kim, S.; Hong, I. J. Ind. Eng. Chem. 2010, 16, 901.
2. [2]
  (2) Varcoe, J. R.; Slade, R. C. T. Fuel cells 2005, 5, 187.
3. [3]
  (3) Savado , O. J. Power Sources 2004, 127, 135.
4. [4]
  (4) Kima, J.; Mommab, T.; Osakaa, T. J. Power Sources 2009, 189, 999.
5. [5]
  (5) Abuin, G. C.; Nonjola, P.; Franceschini, E. A.; Izraelevitch, F. H.; Mathe, M. K.; Corti, H. R. Int. J. Hydrog. Energy 2010, 35, 5850.
6. [6]
  (6) Wang, G. G.;Weng, Y. M.; Chu, D.; Chen, R. R.; Xie, D. J. Membr. Sci. 2009, 332, 63.
7. [7]
  (7) Yu, E. H.; Scott, K. J. Power Sources 2004, 137, 248.
8. [8]
  (8) Komkova, E. N.; Stamatialis, D. F.; Strathmann; H.;Wessling; M. J. Membr. Sci. 2004, 244, 25.
9. [9]
  (9) Lebrun, L.; Follain, N.; Metayer, M. Electrochim. Acta 2004, 50, 985.
10. [10]
  (10) Choi, Y. J.; Park, J. M.; Yeon, K. H.; Moon, S. H. J. Membr. Sci. 2005, 250, 295.
11. [11]
  (11) Carvalho, L. B., Jr.; Araujo, A. M.; Almeda, A. M. P.; Azevedo, W. M. Sensors and Actuators B. 1996, 35 -36, 427.
12. [12]
  (12) Park, J. S.; Park, J.W.; Ruckenstein, E. J. Appl. Polym. Sci. 2001, 80, 1825.
13. [13]
  (13) Mohamad, A. A.; Arof, A. K. Mater. Lett. 2007, 61, 3096.
14. [14]
  (14) Zhang, S.; Li, F. X.; Yu, G. Y. Hsieh, Y. L. Carbohydrate Polymers 2010, 81, 668.
15. [15]
  (15) Zhbankov, R. G.; Firsov, S. P.; Buslov, D. K.; Nikonenko, N. A.; Marchewka, M. K.; Ratajczak, H. J. Mol. Struct. 2002, 614, 117.
16. [16]
  (16) Chen, N.; Li, L.;Wang, Q. Plastic, Rubber and Composites: Macromolecular Engineering 2007, 36, 283.
17. [17]
  (17) Gindl,W.; Martinschitz, K. J.; Boesecke, P.; Keckes, J. Compos. Sci. Technol. 2006, 66, 2639.
18. [18]
  (18) Sakellariou, P.; Hassan, A.; Rowe, R. C. Polymer 1993, 34, 1240.
19. [19]
  (19) Chen, Y.; Cao, X. D.; Chang, P. R.; Huneault, M. A. Carbohydrate Polymers 2008, 73, 8.
20. [20]
  (20) Zhang,W.; Yang, X. L.; Li, C. Y.; Liang, M.; Lu, C. H.; Deng, Y. L. Carbohydrate Polymers 2011, 83, 258.
21. [21]
  (21) Sun, T.; Du,W.; Liu, D. H.; Dai, L. M. Process Biochemistry. 2010, 45, 1192.
22. [22]
  (22) Yeom, C. K.; Lee, K. H. J. Membr. Sci. 1996, 109, 257.
23. [23]
  (23) Qiao, J. L.; Hamaya, T.; Okada, T. Chem. Mater. 2005, 17, 2415.
24. [24]
  (24) Qiao, J. L.; Hamaya, T.; Okada, T. Polymer 2005, 46, 10810.
25. [25]
  (25) Qiao, J. L.; Okada, T. Electrochem. Solid State Lett. 2006, 9, A379.
26. [26]
  (26) Fu, J.; Qiao, J. L.; Ma, J. X. Chem. J. Chin. Univ. 2011, 32, 1. [傅婧, 乔锦丽, 马建新. 高等学校化学学报, 2011, 32, 1.]
27. [27]
  (27) Qiao, J. L.; Fu, J.; Lv, H.; Ma, J. X. Polymer 2010, 51, 4850.
28. [28]
  (28) Li, L.;Wang, Y. X. J. Membr. Sci. 2005, 262, 1.
1. [1]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
2. [2]
  Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
3. [3]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
4. [4]
  Shitao Fu , Jianming Zhang , Cancan Cao , Zhihui Wang , Chaoran Qin , Jian Zhang , Hui Xiong . Study on the Stability of Purple Cabbage Pigment. University Chemistry, 2024, 39(4): 367-372. doi: 10.3866/PKU.DXHX202401059
5. [5]
  Jiaxi Xu , Yuan Ma . Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide. University Chemistry, 2024, 39(11): 374-377. doi: 10.3866/PKU.DXHX202402049
6. [6]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
7. [7]
  Jihua Deng , Xinshi Wu , Dichang Zhong . Exploration of Green Teaching and Ideological and Political Education in Chemical Experiment of “Preparation of Ammonium Ferrous Sulfate”. University Chemistry, 2024, 39(10): 325-329. doi: 10.12461/PKU.DXHX202405046
8. [8]
  Xinhao Yan , Guoliang Hu , Ruixi Chen , Hongyu Liu , Qizhi Yao , Jiao Li , Lingling Li . Polyethylene Glycol-Ammonium Sulfate-Nitroso R Salt System for the Separation of Cobalt (II). University Chemistry, 2024, 39(6): 287-294. doi: 10.3866/PKU.DXHX202310073
9. [9]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
10. [10]
  Meiyu Lin , Yuxin Fang , Songzhang Shen , Yaqian Duan , Wenyi Liang , Chi Zhang , Juan Su . Exploration and Implementation of a Dual-Pathway Blended Teaching Model in General Chemistry Experiment Course: A Case Study of Copper Glycine Synthesis and Its Thermal Analysis. University Chemistry, 2024, 39(8): 48-53. doi: 10.3866/PKU.DXHX202312042
11. [11]
  Ronghao Zhao , Yifan Liang , Mengyao Shi , Rongxiu Zhu , Dongju Zhang . Investigation into the Mechanism and Migratory Aptitude of Typical Pinacol Rearrangement Reactions: A Research-Oriented Computational Chemistry Experiment. University Chemistry, 2024, 39(4): 305-313. doi: 10.3866/PKU.DXHX202309101
12. [12]
  Lan Ma , Cailu He , Ziqi Liu , Yaohan Yang , Qingxia Ming , Xue Luo , Tianfeng He , Liyun Zhang . Magical Surface Chemistry: Fabrication and Application of Oil-Water Separation Membranes. University Chemistry, 2024, 39(5): 218-227. doi: 10.3866/PKU.DXHX202311046
13. [13]
  Yiling Wu , Peiyao Jin , Shenyue Tian , Ji Zhang . The Star of Sugar Substitutes: An Interview of Erythritol. University Chemistry, 2024, 39(9): 22-27. doi: 10.12461/PKU.DXHX202404034
14. [14]
  Chengqian Mao , Yanghan Chen , Haotong Bai , Junru Huang , Junpeng Zhuang . Photodimerization of Styrylpyridinium Salt and Its Application in Silk Screen Printing. University Chemistry, 2024, 39(5): 354-362. doi: 10.3866/PKU.DXHX202312014
15. [15]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
16. [16]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
17. [17]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
18. [18]
  Shipeng WANG , Shangyu XIE , Luxian LIANG , Xuehong WANG , Jie WEI , Deqiang WANG . Piezoelectric effect of Mn, Bi co-doped sodium niobate for promoting cell proliferation and bacteriostasis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1919-1931. doi: 10.11862/CJIC.20240094
19. [19]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
20. [20]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006

Get Citation

PDF

XML

Metrics

PDF Downloads(1024)
Abstract views(2662)
HTML views(12)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142