Citation: LI Jie-Bin, XU You-Long, XIONG Li-Long, WANG Jing-Ping. Improvement of LiNi_1/3Co_1/3Mn_1/3O₂ Cathode Materials by Nano-M Doping[J]. Acta Physico-Chimica Sinica, ;2011, 27(11): 2593-2599. doi: 10.3866/PKU.WHXB20111104 shu

Improvement of LiNi_1/3Co_1/3Mn_1/3O₂ Cathode Materials by Nano-M Doping

1.
1. International Center for Dielectric Research, Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education, Xi'an Jiaotong University, Xi'an 710049, P. R. China;
2. Shaanxi Applied Physics and Chemistry Research Institute, Xi'an 710061, P. R. China

Received Date: 7 June 2011
Available Online: 29 August 2011

Nano-sized M₃O₄ (M=Ni_1/3Co_1/3Mn_1/3) powder with a spinel structure was prepared by sintering co-precipitated M(OH)₂ at 500°C for 5 h. The so-obtained M₃O₄ was then mixed with LiOH and different amounts of nano-M . The mixture was sintered at 850°C for 24 h to synthesize Li(Ni_1/3Co_1/3Mn_1/3)_1-xMg_xO₂ (x=0, 0.01, 0.02, 0.03, 0.04,0.05) cathode materials. The lattice parameters increased while the diffusion coefficients of Li⁺ ion showed an increasing and then decreasing trend with an increase in the amount of Mg substitution. Li(Ni_1/3Co_1/3Mn_1/3)_0.98Mg_0.02O₂ had the highest Li⁺ ion diffusion coefficients, which were 29.20× 10^-11 cm²·s^-1 for Li⁺ de-intercalation and 4.760×10^-11 cm²·s^-1 for Li⁺ intercalation. Its discharge capacity at 3C rate was 139.3 mAh·g^-1, which is 9.5 mAh·g^-1 higher than that of the pristine material. Furthermore, its cycle performance was also improved significantly compared with the un-doped counterpart.
- Lithium ion battery,
- Cathode material,
- LiNi_1/3Co_1/3Mn_1/3O₂,
- Mg-doping,
- Diffusion coefficient of Li⁺ ion
1. [1]
  (1) Ohzuku, T.; Makimura, Y. Chem. Lett. 2001, 7, 642.
2. [2]
  (2) Hwang, B. J.; Tsai, Y.W.; Carlier, D.; Ceder, G. Chem. Mater. 2003, 15, 3676.
3. [3]
  (3) Shaju, K. M.; Rao, G. V. S.; Chowdari, B. V. R. Electrochim. Acta 2002, 48, 145.
4. [4]
  (4) Lee, M. H.; Kang, Y.; Myung, S. T.; Sun, Y. K. Electrochim. Acta 2004, 50, 939.
5. [5]
  (5) Wu, F.;Wang, M.; Su, Y. F.; Chen. S. Acta Phys. -Chim. Sin. 2009, 25(4), 629. [吴峰, 王萌, 苏岳峰, 陈实. 物理化学学报, 2009, 25(4), 629.]
6. [6]
  (6) Chen, J.;Wang, S.; Whittingham, M. S. J. Power Sources 2007, 174, 442.
7. [7]
  (7) Reddy, M. V.; Rao, G. V. S.; Chowdari, B. V. R. J. Power Sources 2006, 159, 263.
8. [8]
  (8) Chebiam, R. V.; Prado, F.; Manthiram, A. Chem. Mater. 2001, 13, 2951.
9. [9]
  (9) Chen, Y. H.; Chen, R. Z.; Tang, Z. Y.;Wang, L. J. Alloys Compd. 2009, 476, 539.
10. [10]
  (10) Ding, Y. H.; Zhang, P.; Jiang, Y.; Gao, D. S. Solid State Ionics 2007, 178(13-14), 967.
11. [11]
  (11) Luo,W. B.; Li, X. H.; Dahn, J. R. J. Electrochem. Soc. 2010, 157 (7), A782.
12. [12]
  (12) Luo,W. B.; Li, X. H.; Dahn, J. R. Chem. Mater. 2010, 22(17), 5065.
13. [13]
  (13) Kim, G. H.; Myung, S. T.; Kim, H. S.; Sun, Y. K. Electrochim. Acta 2006, 51 (12), 2447.
14. [14]
  (14) Oh, S.W.; Park, S. H.; Amine, K.; Sun, Y. K. J. Power Sources 2006, 160, 558.
15. [15]
  (15) Hwang, B. J.; R. Santhanam, C. H. Chen. J. Power Sources 2003, 114, 244.
16. [16]
  (16) Alcantara, R.; Lavela, P.; Tirado, J. L.; Stoyanova, R.; Zhecheva, E. J. Electrochem. Soc. 1998, 145, 730.
17. [17]
  (17) Tang, Z. Y.; Xue, J. J.; Li, J. G.;Wang Z. L. Acta Phys. -Chim. Sin. 2001, 17 (6), 526. [唐致远, 薛建军, 李建刚, 王占良. 物理化学学报, 2001, 17 (6), 526.]
18. [18]
  (18) Xia, H.; Lu, L.; Lai, M. O. Electrochim. Acta 2009, 54: 5986.
19. [19]
  (19) Ni, J. F.; Zhou, H. H.; Chen, J. T.; Zhang, X. X. Electrochim. Acta 2007, 53, 3075.
20. [20]
  (20) Li, J. G.;Wan, C. R.; Yang, D. P.; Yang, Z. P. Acta Phys. -Chim. Sin. 2003, 19 (11), 1030. [李建刚, 万春荣, 杨冬平, 杨张平. 物理化学学报, 2003, 19 (11), 1030.]
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Improvement of LiNi1/3Co1/3Mn1/3O2 Cathode Materials by Nano-M Doping

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Improvement of LiNi_1/3Co_1/3Mn_1/3O₂ Cathode Materials by Nano-M Doping