Citation:
YE Bin, GAO Cai, ZHAO Han, CHEN Kai-Song, YANG Suo, LIU Xiang-Nong. 1H NMR Investigation on Effect of Solute Concentration on the Hydrogen Bonding and Glass Transition of Three-Carbon Polyalcohol Aqueous Solutions[J]. Acta Physico-Chimica Sinica,
;2011, 27(11): 2505-2511.
doi:
10.3866/PKU.WHXB20111103
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We investigated the effects of solute concentration on the hydrogen bonding interactions of three-carbon polyalcohol aqueous solutions. In order to inspect the capacity of the solutions to form glass, proton nuclear magnetic resonance (1H NMR) chemical shifts were determined in binary mixtures of water and 1-propanol (NPA), 2-propanol (IPA), 1,2-propanediol (PG), 1,3-propanediol (PD), and glycerol at room temperature and at atmospheric pressure using the external reference method. We found that the alkyl proton chemical shifts of PG with the CH3CH(OH)― group showed biphasic behavior, which was different from other molecules. Water molecules formed relatively strong O ― H···O hydrogen bonds with the alcohol hydroxyls. The proton chemical shifts of H2O and the hydroxyl protons decrease with an increase in the number of alcohol hydroxyls at the same mole fraction. Moreover, the proton chemical shifts of H2O and hydroxyl protons with the same number of alcohol hydroxyls are different because of their different locations. The order of increased basicity agrees with the order of increased ice homogeneous nucleation suppression, that is, glycerol>PG>PD>IPA>NPA. This explains why glycerol and PG are more suitable as cryoprotective agents (CPAs) among the five polyalcohols.
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-
-
[1]
(1) Hua, Z. C.; Ren, H. S. Cryobiomedical Techniques; Science Press: Beijing, 1994; p 12. [华泽钊, 任禾盛. 北京: 低温生物医学技术. 科学出版社, 1994, p 12]
-
[2]
(2) Hua, Z. C.; Liu B. L.; Zuo J. G. Freeze-Drying of Pharmaceutical and Food Products; Science Press: Beijing, 2006; p 123. [华泽钊, 刘宝林, 左建国. 药品和食品的冷冻干燥. 北京: 科学出版社, 2006; p 123.]
-
[3]
(3) Gao, C.;Wang, T. J.; Liu, X. N.; Zhou, G. Y.; Hua, T. C. Chin. J. Chem. Phys. 2007, 20, 258.
-
[4]
(4) Gao, C.; Zhou, G. Y.; Xu, Y.; Hua, T. C. Thermochim. Acta 2005, 435, 38.
-
[5]
(5) Gao, C.;Wang, T. J.; Liu, X. N.; Zhou, G. Y.; Hua, T. C. Thermochim. Acta 2007, 456, 19.
-
[6]
(6) Gao, C.;Wang, T. J.; Zhou, G. Y.; Hua. Z. Z. Chem. J. Chin. Univ. 2007, 28, 1139. [高才, 王铁军, 周国燕, 华泽钊. 高等学校化学学报, 2007, 28, 1139.]
-
[7]
(7) Hisashi, H.; Keiko, N.; Takao, I. J. Phys. Chem. 1990, 94, 8334.
-
[8]
(8) Zelent, B.; Nucci, N. V.; Vanderkooi, J. M. J. Phys. Chem. A 2004, 108, 11141.
-
[9]
(9) Oakes, J. J. Chem. Soc., Faraday Trans. 2. 1972, 68, 1464.
- [10]
-
[11]
(11) Sare, E. J.; Moynihan, C. T.; Angell, C. A. J. Phys. Chem. 1973, 77, 1869.
-
[12]
(12) Hinton, J. F.; Ladner, K. H. Spectrochimica Acta Part A-Molecular Spectroscopy 1972, 28, 1731.
-
[13]
(13) Holmes, J. R.; Kivelson, D.; Drinkard,W. C. J. Am. Chem. Soc. 1962, 84, 4677.
-
[14]
(14) Bhanumathi, R.; Vijayalakshamme, S. K. J. Phys. Chem. 1986, 90, 4666.
-
[15]
(15) Fratiello, A.; Luon , J. P. J. Am. Chem. Soc. 1963, 85, 3072.
-
[16]
(16) Barone, G.; Castronuovo, G.; Della, V. C.; Elia, V. J. Solution Chem. 1977, 6, 117.
-
[17]
(17) Anderson, R. G.; Symons, M. C. Trans. Faraday Soc. 1969, 65, 2550.
-
[18]
(18) Fratiello, A.; Douglass, D. C. J. Mol. Spectrosc. 1963, 11, 465.
-
[19]
(19) Klein, R.A.; Pacheco, V. J. Phys. Chem. A 2001, 105, 9298.
-
[20]
(20) Forsyth, M.; MacFarlane, D.R. J. Phys. Chem. 1990, 94, 6889.
-
[21]
(21) Zhou, Y.; Hu, K.; Shen, J. F.;Wu, X. J.; Cheng, G. Z. J. Mol. Struct. 2009, 921, 150.
-
[22]
(22) Hills, B.P.; Pardoe, K. J. Mol. Liq. 1995, 63, 229.
-
[23]
(23) Bhanumathi, R.; Vijayalakshamma, S. K. J. Phys. Chem. 1986, 90, 4666.
-
[24]
(24) Mizuno, K.; Miyashita, Y.; Shindo, Y.; Ogawa, H. J. Phys. Chem. 1995, 99, 3225.
-
[25]
(25) Xiang, S.J.; Yu, G.Q.; Liang, Y. M.;Wu, L. M. J. Mol. Struct. 2006, 789, 43.
-
[26]
(26) Yadav, M. K.; Kumar, A. J. Molecular Liquids 2005, 121, 94.
-
[27]
(27) Mizuno, K.; Kimura, Y.; Morichika, H.; Nishimura, Y.; Shimada, S.; Maeda, S.; Imafuji, S.; Ochi, T. J. Mol. Liq. 2000, 85, 139.
-
[28]
(28) Selwood, P.W. Magnetochemistry; Interscience: New York, 1943.
-
[29]
(29) The Handbook of Chemistry and Physics; CRC: Cleveland, OH, 1974.
-
[30]
(30) Pople, J. A.; Schneider,W. G.; Barnstein, H. J. High Resolution NMR, McGraw-Hill: New York, 1967.
-
[31]
(31) Becker, E. D. High Resolution NMR ; Theory and Chemical Applications, 2nd ed.; Academic Press: New York, 1980.
-
[32]
(32) Larman, M. G.; Katz-Jaffe, M. G.; Sheehan, C. B.; Gardner, D. K. Hum. Reprod. 2007, 22, 250.
-
[33]
(33) Wowk, B.; Darwin, M.; Harris, S. B.; Russell, S. R.; Rasch, C. M. J. Cryobiology 1999, 39, 215.
-
[34]
(34) Deshmukh, M. M.; Sastry, N. V.; Gadre, S. R. J. Chem. Phys. 2004, 121, 12402.
-
[35]
(35) Ziedler, M.D. In Water: A Comprehensive Treatise; Franks, F. Ed.; Plenum: New York, 1973, Vol. 2. (36) Streitweiser, A.; Heathcock, C.H. Introduction to Organic Chemistry, 2nd ed.; MacMillan: New York, 1981.
-
[36]
(37) MarFarlane, D. R.; Forsyth, M. J. Cryobiology 1990, 27, 345.
-
[37]
(38) Emiliani, S.; Bergh, M. V.; den Vannin, A. S.; Biramane, J.; Englert, Y. Hum. Reprod. 2000, 15, 905.
-
[38]
(39) Gao, C. Thermal Phenomena Study of Linear Polyalcohols aqueous solutions at low Temperature. Ph. D. Dissertation, University of ShangHai for Science and Technology, Shanghai, 2004. [高才. 线性多元醇水溶液低温下的热现象研究[D]. 上海:上海理工大学, 2004.]
-
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