Citation: YE Bin, GAO Cai, ZHAO Han, CHEN Kai-Song, YANG Suo, LIU Xiang-Nong. ¹H NMR Investigation on Effect of Solute Concentration on the Hydrogen Bonding and Glass Transition of Three-Carbon Polyalcohol Aqueous Solutions[J]. Acta Physico-Chimica Sinica, ;2011, 27(11): 2505-2511. doi: 10.3866/PKU.WHXB20111103 shu

¹H NMR Investigation on Effect of Solute Concentration on the Hydrogen Bonding and Glass Transition of Three-Carbon Polyalcohol Aqueous Solutions

1.
School of Mechanical and Automotive Engineering, Hefei University of Technology, Hefei 230009, P. R. China

Received Date: 2 June 2011
Available Online: 29 August 2011
Fund Project: 国家自然科学基金(20803016) (20803016)安徽省自然科学基金(070414163)资助项目 (070414163)

We investigated the effects of solute concentration on the hydrogen bonding interactions of three-carbon polyalcohol aqueous solutions. In order to inspect the capacity of the solutions to form glass, proton nuclear magnetic resonance (¹H NMR) chemical shifts were determined in binary mixtures of water and 1-propanol (NPA), 2-propanol (IPA), 1,2-propanediol (PG), 1,3-propanediol (PD), and glycerol at room temperature and at atmospheric pressure using the external reference method. We found that the alkyl proton chemical shifts of PG with the CH₃CH(OH)― group showed biphasic behavior, which was different from other molecules. Water molecules formed relatively strong O ― H···O hydrogen bonds with the alcohol hydroxyls. The proton chemical shifts of H₂O and the hydroxyl protons decrease with an increase in the number of alcohol hydroxyls at the same mole fraction. Moreover, the proton chemical shifts of H₂O and hydroxyl protons with the same number of alcohol hydroxyls are different because of their different locations. The order of increased basicity agrees with the order of increased ice homogeneous nucleation suppression, that is, glycerol>PG>PD>IPA>NPA. This explains why glycerol and PG are more suitable as cryoprotective agents (CPAs) among the five polyalcohols.
- ¹H nuclear magnetic resonance,
- Three-carbon polyalcohol,
- Aqueous solution,
- Cryoprotective agent,
- Proton chemical shift,
- Hydrogen bonding
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

1H NMR Investigation on Effect of Solute Concentration on the Hydrogen Bonding and Glass Transition of Three-Carbon Polyalcohol Aqueous Solutions

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通讯作者: 陈斌, bchen63@163.com

¹H NMR Investigation on Effect of Solute Concentration on the Hydrogen Bonding and Glass Transition of Three-Carbon Polyalcohol Aqueous Solutions