Citation: SHI Ji-Fu, WAN Qing-Cui, XU Gang, XU Xue-Qing, FAN Ye. Influence of Temperature on the Properties of Polysulfide Electrolyte and Quantum Dot Sensitized Solar Cells[J]. Acta Physico-Chimica Sinica, ;2011, 27(10): 2360-2366. doi: 10.3866/PKU.WHXB20111023 shu

Influence of Temperature on the Properties of Polysulfide Electrolyte and Quantum Dot Sensitized Solar Cells

1.
Guangzhou Institute of Energy Conversion, Key Laboratory of Renewable Energy and Gas Hydrate, Chinese Academy of Sciences, Guangzhou 510640, P. R. China

Received Date: 9 June 2011
Available Online: 24 August 2011
Fund Project: 国家自然科学基金(21073193, 21103194) (21073193, 21103194) 广东省科技计划(2009B011100005) (2009B011100005)中国科学院广州能源研究所所长创新基金(y007r71001)资助项目 (y007r71001)

We studied the influence of temperature on the conductivity of a polysulfide electrolyte and the photovoltaic performance of quantum dot sensitized solar cells by electrochemical methods. The results indicate that the conductivity of the electrolyte increases and the diffusion impedance of the polysulfide ions in the electrolyte decreases with an increase in the temperature. Moreover, the photoelectric conversion efficiency of the quantum dot sensitized solar cells decreases when the temperature increases. This phenomenon is mainly caused by a more serious back reaction and the desorption of quantum dots at higher temperatures.
- Quantum dot sensitized solar cell,
- Temperature,
- Electrolyte,
- Conductivity,
- Impedance
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