Citation: SHI Ji-Fu, WAN Qing-Cui, XU Gang, XU Xue-Qing, FAN Ye. Influence of Temperature on the Properties of Polysulfide Electrolyte and Quantum Dot Sensitized Solar Cells[J]. Acta Physico-Chimica Sinica, ;2011, 27(10): 2360-2366. doi: 10.3866/PKU.WHXB20111023 shu

Influence of Temperature on the Properties of Polysulfide Electrolyte and Quantum Dot Sensitized Solar Cells

1.
Guangzhou Institute of Energy Conversion, Key Laboratory of Renewable Energy and Gas Hydrate, Chinese Academy of Sciences, Guangzhou 510640, P. R. China

Received Date: 9 June 2011
Available Online: 24 August 2011
Fund Project: 国家自然科学基金(21073193, 21103194) (21073193, 21103194) 广东省科技计划(2009B011100005) (2009B011100005)中国科学院广州能源研究所所长创新基金(y007r71001)资助项目 (y007r71001)

We studied the influence of temperature on the conductivity of a polysulfide electrolyte and the photovoltaic performance of quantum dot sensitized solar cells by electrochemical methods. The results indicate that the conductivity of the electrolyte increases and the diffusion impedance of the polysulfide ions in the electrolyte decreases with an increase in the temperature. Moreover, the photoelectric conversion efficiency of the quantum dot sensitized solar cells decreases when the temperature increases. This phenomenon is mainly caused by a more serious back reaction and the desorption of quantum dots at higher temperatures.
- Quantum dot sensitized solar cell,
- Temperature,
- Electrolyte,
- Conductivity,
- Impedance
1. [1]
  (1) O'Regan, B.; Grätzel, M. Nature 1991, 353, 737.
2. [2]
  (2) Liao, J. Y.; Lei, B. X.;Wang, Y. F.; Liu, J. M.; Su, C. Y.; Kuang, D. B. Chem. Eur. J. 2011, 17, 1352.
3. [3]
  (3) Pei, J.; Liang, M.; Chen, J.; Tao, Z. L.; Xu,W. Acta Phys. -Chim. Sin. 2008, 24, 1950. [裴娟, 梁茂, 陈军, 陶占良, 许炜. 物理化学学报, 2008, 24, 1950.]
4. [4]
  (4) Shi, J. F.; Peng, S. J.; Pei, J.; Liang, Y. L.; Cheng, F. Y.; Chen, J. ACS Appl. Mater. Interfaces 2009, 1, 944.
5. [5]
  (5) Tao, L.; Yang, Y. Z.; Shi, C.W.;Wu, Y. C.;Wu, X. Y. Acta Phys. -Chim. Sin. 2010, 26, 578. [桃李, 杨燕珍, 史成武, 吴玉程, 吴小燕. 物理化学学报, 2010, 26, 578.]
6. [6]
  (6) Shi, J. F.; Xu, G.; Miao, L.; Xu, X. Q. Acta Phys. -Chim. Sin. 2011, 27, 1287. [史继富, 徐刚, 苗蕾, 徐雪青. 物理化学学报, 2011, 27, 1287.]
7. [7]
  (7) Yu, Q.;Wang, Y.; Yi, Z.; Zu, N.; Zhang, J.; Zhang, M.;Wang, P. ACS Nano 2010, 4, 6032.
8. [8]
  (8) Wang, P.; Zakeeruddin, S. M.; Moser, J. E.; Nazeeruddin, M. K.; Sekiguchi, T.; Grätzel, M. Nat. Mater. 2003, 2, 402.
9. [9]
  (9) Ruhle, S.; Shalom, M.; Zaban, A. ChemPhysChem 2010, 11, 2290.
10. [10]
  (10) Zhang, Q.; Zhang, Y.; Huang, S.; Huang, X.; Luo, Y.; Meng, Q.; Li, D. Electrochem. Commun. 2010, 12, 327.
11. [11]
  (11) Lee, H.; Yum, J. H.; Leventis, H. C.; Zakeeruddin, S. M.; Haque, S; A.; Chen, P.; Seok, S.; Grätzel, M. Nazeeruddin, M. K. J. Phys. Chem. C 2008, 112, 11600.
12. [12]
  (12) nzalez-Pedro, V.; Xu, X.; Mora-Sero, I.; Bisquert, J. ACS Nano 2010, 4, 5783.
13. [13]
  (13) Lee, H. J.;Wang, M.; Chen, P.; Gamelin, D. R.; Zakeeruddin, S. M.; Grätzel, M.; Nazeeruddin, M. K. Nano Lett. 2009, 9, 4221.
14. [14]
  (14) Shi, J. F.; Peng, B.; Pei, J.; Peng, S. J.; Chen, J. J. Power Sources 2009, 193, 878.
15. [15]
  (15) Yu, Z.; Zhang, Q.; Qin, D.; Luo, Y.; Li, D.; Shen, Q.; Toyoda, T.; Meng, Q. Electrochem. Commun. 2010, 12, 1776.
16. [16]
  (16) Wu, J.; Hao, S.; Lan, Z.; Lin, J.; Huang, M.; Huang, Y.; Fang, L.; Yin, S.; Sato, T. Adv. Funct. Mater. 2007, 17, 2645.
17. [17]
  (17) Fan, S. Q.; Fang, B.; Kim, J. H.; Jeong, B.; Kim, C.; Yu, J. S.; Ko, J. Langmuir 2010, 26, 13644.
18. [18]
  (18) Deng, M.; Huang, S.; Zhang, Q.; Li, D.; Luo, Y.; Shen, Q.; Toyoda, T.; Meng, Q. Chem. Lett. 2010, 39, 1168.
19. [19]
  (19) Berginc, M.; Krasovec, U. O.; Jankovec, M. Topic, M. Sol. Energy Mater. Sol. Cells 2007, 91, 821.
20. [20]
  (20) Huang, S. Y.; Schlichthorl, G.; Nozik, A. J.; Grätzel, M.; Frank, A. J. J. Phys. Chem. B 1997, 101, 2576.
21. [21]
  (21) Zhang, Q. B.; Feng, Z. F.; Han, N. N.; Lin, L. L.; Zhou, J. Z.; Lin, Z. H. Acta Phys. -Chim. Sin. 2010, 26, 2927. [张桥保, 冯增芳, 韩楠楠, 林玲玲, 周剑章, 林仲华. 物理化学学报, 2010, 26, 2927.]
22. [22]
  (22) Hore, S.; Kern, R. Appl. Phys. Lett. 2005, 87, 263504.
23. [23]
  (23) Shi, J.; Liang, J.; Peng, S.; Xu,W.; Pei, J.; Chen, J. Solid State Sci. 2009, 11, 433.
24. [24]
  (24) Zhang, Z.; Zakeeruddin, S. M.; O'Regan, B. C.; Humphry- Baker, R.; Grätzel, M. J. Phys. Chem. B 2005, 109, 21818.
25. [25]
  (25) Wang, Q.; Ito, S.; Grätzel, M.; Fabregat-Santia , F.; Mora- Sero, I.; Bisquert, J.; Bessho, T. B.; Imai, H. J. Phys. Chem. B 2006, 110, 25210.
26. [26]
  (26) Shalom, M.; Dor, S.; Ruhle, S.; Grinis, L.; Zaban, A. J. Phys. Chem. C 2009, 113, 3895.
27. [27]
  (27) Samadpour1, M.; Irajizad, A.; Taghavinia, N.; Molaei, M. J. Phys. D-Appl. Phys. 2011, 44, 045103.
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