Citation: SHI Ji-Fu, WAN Qing-Cui, XU Gang, XU Xue-Qing, FAN Ye. Influence of Temperature on the Properties of Polysulfide Electrolyte and Quantum Dot Sensitized Solar Cells[J]. Acta Physico-Chimica Sinica, ;2011, 27(10): 2360-2366. doi: 10.3866/PKU.WHXB20111023 shu

Influence of Temperature on the Properties of Polysulfide Electrolyte and Quantum Dot Sensitized Solar Cells

1.
Guangzhou Institute of Energy Conversion, Key Laboratory of Renewable Energy and Gas Hydrate, Chinese Academy of Sciences, Guangzhou 510640, P. R. China

Received Date: 9 June 2011
Available Online: 24 August 2011
Fund Project: 国家自然科学基金(21073193, 21103194) (21073193, 21103194) 广东省科技计划(2009B011100005) (2009B011100005)中国科学院广州能源研究所所长创新基金(y007r71001)资助项目 (y007r71001)

We studied the influence of temperature on the conductivity of a polysulfide electrolyte and the photovoltaic performance of quantum dot sensitized solar cells by electrochemical methods. The results indicate that the conductivity of the electrolyte increases and the diffusion impedance of the polysulfide ions in the electrolyte decreases with an increase in the temperature. Moreover, the photoelectric conversion efficiency of the quantum dot sensitized solar cells decreases when the temperature increases. This phenomenon is mainly caused by a more serious back reaction and the desorption of quantum dots at higher temperatures.
- Quantum dot sensitized solar cell,
- Temperature,
- Electrolyte,
- Conductivity,
- Impedance
1. [1]
  (1) O'Regan, B.; Grätzel, M. Nature 1991, 353, 737.
2. [2]
  (2) Liao, J. Y.; Lei, B. X.;Wang, Y. F.; Liu, J. M.; Su, C. Y.; Kuang, D. B. Chem. Eur. J. 2011, 17, 1352.
3. [3]
  (3) Pei, J.; Liang, M.; Chen, J.; Tao, Z. L.; Xu,W. Acta Phys. -Chim. Sin. 2008, 24, 1950. [裴娟, 梁茂, 陈军, 陶占良, 许炜. 物理化学学报, 2008, 24, 1950.]
4. [4]
  (4) Shi, J. F.; Peng, S. J.; Pei, J.; Liang, Y. L.; Cheng, F. Y.; Chen, J. ACS Appl. Mater. Interfaces 2009, 1, 944.
5. [5]
  (5) Tao, L.; Yang, Y. Z.; Shi, C.W.;Wu, Y. C.;Wu, X. Y. Acta Phys. -Chim. Sin. 2010, 26, 578. [桃李, 杨燕珍, 史成武, 吴玉程, 吴小燕. 物理化学学报, 2010, 26, 578.]
6. [6]
  (6) Shi, J. F.; Xu, G.; Miao, L.; Xu, X. Q. Acta Phys. -Chim. Sin. 2011, 27, 1287. [史继富, 徐刚, 苗蕾, 徐雪青. 物理化学学报, 2011, 27, 1287.]
7. [7]
  (7) Yu, Q.;Wang, Y.; Yi, Z.; Zu, N.; Zhang, J.; Zhang, M.;Wang, P. ACS Nano 2010, 4, 6032.
8. [8]
  (8) Wang, P.; Zakeeruddin, S. M.; Moser, J. E.; Nazeeruddin, M. K.; Sekiguchi, T.; Grätzel, M. Nat. Mater. 2003, 2, 402.
9. [9]
  (9) Ruhle, S.; Shalom, M.; Zaban, A. ChemPhysChem 2010, 11, 2290.
10. [10]
  (10) Zhang, Q.; Zhang, Y.; Huang, S.; Huang, X.; Luo, Y.; Meng, Q.; Li, D. Electrochem. Commun. 2010, 12, 327.
11. [11]
  (11) Lee, H.; Yum, J. H.; Leventis, H. C.; Zakeeruddin, S. M.; Haque, S; A.; Chen, P.; Seok, S.; Grätzel, M. Nazeeruddin, M. K. J. Phys. Chem. C 2008, 112, 11600.
12. [12]
  (12) nzalez-Pedro, V.; Xu, X.; Mora-Sero, I.; Bisquert, J. ACS Nano 2010, 4, 5783.
13. [13]
  (13) Lee, H. J.;Wang, M.; Chen, P.; Gamelin, D. R.; Zakeeruddin, S. M.; Grätzel, M.; Nazeeruddin, M. K. Nano Lett. 2009, 9, 4221.
14. [14]
  (14) Shi, J. F.; Peng, B.; Pei, J.; Peng, S. J.; Chen, J. J. Power Sources 2009, 193, 878.
15. [15]
  (15) Yu, Z.; Zhang, Q.; Qin, D.; Luo, Y.; Li, D.; Shen, Q.; Toyoda, T.; Meng, Q. Electrochem. Commun. 2010, 12, 1776.
16. [16]
  (16) Wu, J.; Hao, S.; Lan, Z.; Lin, J.; Huang, M.; Huang, Y.; Fang, L.; Yin, S.; Sato, T. Adv. Funct. Mater. 2007, 17, 2645.
17. [17]
  (17) Fan, S. Q.; Fang, B.; Kim, J. H.; Jeong, B.; Kim, C.; Yu, J. S.; Ko, J. Langmuir 2010, 26, 13644.
18. [18]
  (18) Deng, M.; Huang, S.; Zhang, Q.; Li, D.; Luo, Y.; Shen, Q.; Toyoda, T.; Meng, Q. Chem. Lett. 2010, 39, 1168.
19. [19]
  (19) Berginc, M.; Krasovec, U. O.; Jankovec, M. Topic, M. Sol. Energy Mater. Sol. Cells 2007, 91, 821.
20. [20]
  (20) Huang, S. Y.; Schlichthorl, G.; Nozik, A. J.; Grätzel, M.; Frank, A. J. J. Phys. Chem. B 1997, 101, 2576.
21. [21]
  (21) Zhang, Q. B.; Feng, Z. F.; Han, N. N.; Lin, L. L.; Zhou, J. Z.; Lin, Z. H. Acta Phys. -Chim. Sin. 2010, 26, 2927. [张桥保, 冯增芳, 韩楠楠, 林玲玲, 周剑章, 林仲华. 物理化学学报, 2010, 26, 2927.]
22. [22]
  (22) Hore, S.; Kern, R. Appl. Phys. Lett. 2005, 87, 263504.
23. [23]
  (23) Shi, J.; Liang, J.; Peng, S.; Xu,W.; Pei, J.; Chen, J. Solid State Sci. 2009, 11, 433.
24. [24]
  (24) Zhang, Z.; Zakeeruddin, S. M.; O'Regan, B. C.; Humphry- Baker, R.; Grätzel, M. J. Phys. Chem. B 2005, 109, 21818.
25. [25]
  (25) Wang, Q.; Ito, S.; Grätzel, M.; Fabregat-Santia , F.; Mora- Sero, I.; Bisquert, J.; Bessho, T. B.; Imai, H. J. Phys. Chem. B 2006, 110, 25210.
26. [26]
  (26) Shalom, M.; Dor, S.; Ruhle, S.; Grinis, L.; Zaban, A. J. Phys. Chem. C 2009, 113, 3895.
27. [27]
  (27) Samadpour1, M.; Irajizad, A.; Taghavinia, N.; Molaei, M. J. Phys. D-Appl. Phys. 2011, 44, 045103.
1. [1]
  Jiayu Tang , Jichuan Pang , Shaohua Xiao , Xinhua Xu , Meifen Wu . Improvement for Measuring Transference Numbers of Ions by Moving-Boundary Method. University Chemistry, 2024, 39(5): 193-200. doi: 10.3866/PKU.DXHX202311021
2. [2]
  Ran HUO , Zhaohui ZHANG , Xi SU , Long CHEN . Research progress on multivariate two dimensional conjugated metal organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2063-2074. doi: 10.11862/CJIC.20240195
3. [3]
  Ru SONG , Biao WANG , Chunling LU , Bingbing NIU , Dongchao QIU . Electrochemical properties of stable and highly active PrBa_0.5Sr_0.5Fe_1.6Ni_0.4O_5+δ cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 639-649. doi: 10.11862/CJIC.20240397
4. [4]
  Jiandong Liu , Zhijia Zhang , Mikhail Kamenskii , Filipp Volkov , Svetlana Eliseeva , Jianmin Ma . Research Progress on Cathode Electrolyte Interphase in High-Voltage Lithium Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100011-. doi: 10.3866/PKU.WHXB202308048
5. [5]
  Tao Jiang , Yuting Wang , Lüjin Gao , Yi Zou , Bowen Zhu , Li Chen , Xianzeng Li . Experimental Design for the Preparation of Composite Solid Electrolytes for Application in All-Solid-State Batteries: Exploration of Comprehensive Chemistry Laboratory Teaching. University Chemistry, 2024, 39(2): 371-378. doi: 10.3866/PKU.DXHX202308057
6. [6]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2309019-. doi: 10.3866/PKU.WHXB202309019
7. [7]
  Yipeng Zhou , Chenxin Ran , Zhongbin Wu . Metacognitive Enhancement in Diversifying Ideological and Political Education within Graduate Course: A Case Study on “Solar Cell Performance Enhancement Technology”. University Chemistry, 2024, 39(6): 151-159. doi: 10.3866/PKU.DXHX202312096
8. [8]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
9. [9]
  Pengyu Dong , Yue Jiang , Zhengchi Yang , Licheng Liu , Gu Li , Xinyang Wen , Zhen Wang , Xinbo Shi , Guofu Zhou , Jun-Ming Liu , Jinwei Gao . NbSe₂纳米片优化钙钛矿太阳能电池的埋底界面. Acta Physico-Chimica Sinica, 2025, 41(3): 2407025-. doi: 10.3866/PKU.WHXB202407025
10. [10]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
11. [11]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
12. [12]
  Xiaoyao YIN , Wenhao ZHU , Puyao SHI , Zongsheng LI , Yichao WANG , Nengmin ZHU , Yang WANG , Weihai SUN . Fabrication of all-inorganic CsPbBr₃ perovskite solar cells with SnCl₂ interface modification. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 469-479. doi: 10.11862/CJIC.20240309
13. [13]
  Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . 氰基修饰的苝二酰亚胺衍生物作为膜厚不敏感型阴极界面材料用于高效有机太阳能电池. Acta Physico-Chimica Sinica, 2025, 41(3): 2406007-. doi: 10.3866/PKU.WHXB202406007
14. [14]
  Qiaoqiao BAI , Anqi ZHOU , Xiaowei LI , Tang LIU , Song LIU . Construction of pressure-temperature dual-functional flexible sensors and applications in biomedicine. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2259-2274. doi: 10.11862/CJIC.20240128
15. [15]
  Mingxin LU , Liyang ZHOU , Xiaoyu XU , Xiaoying FENG , Hui WANG , Bin YAN , Jie XU , Chao CHEN , Hui MEI , Feng GAO . Preparation of La-doped lead-based piezoelectric ceramics with both high electrical strain and Curie temperature. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 329-338. doi: 10.11862/CJIC.20240206
16. [16]
  Wei HE , Jing XI , Tianpei HE , Na CHEN , Quan YUAN . Application of solar-driven inorganic semiconductor-microbe hybrids in carbon dioxide fixation and biomanufacturing. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 35-44. doi: 10.11862/CJIC.20240364
17. [17]
  Xinxin JING , Weiduo WANG , Hesu MO , Peng TAN , Zhigang CHEN , Zhengying WU , Linbing SUN . Research progress on photothermal materials and their application in solar desalination. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1033-1064. doi: 10.11862/CJIC.20230371
18. [18]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
19. [19]
  Jiahe LIU , Gan TANG , Kai CHEN , Mingda ZHANG . Effect of low-temperature electrolyte additives on low-temperature performance of lithium cobaltate batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 719-728. doi: 10.11862/CJIC.20250023
20. [20]
  Miaomiao He , Zhiqing Ge , Qiang Zhou , Jiaqing He , Hong Gong , Lingling Li , Pingping Zhu , Wei Shao . Exploring the Fascinating Realm of Quantum Dots. University Chemistry, 2024, 39(6): 231-237. doi: 10.3866/PKU.DXHX202310040

Get Citation

PDF

XML

Metrics

PDF Downloads(1519)
Abstract views(3449)
HTML views(39)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142