Citation: XIA Hui-Yun, ZHANG Ying, GAO Li-Ning, YAN Lu-Ke. Ag-P(AM-co-MAA) Composite Microspheres Based on Morphology Transcription Method[J]. Acta Physico-Chimica Sinica, ;2011, 27(10): 2485-2492. doi: 10.3866/PKU.WHXB20111020 shu

Ag-P(AM-co-MAA) Composite Microspheres Based on Morphology Transcription Method

1.
1. Engineering Research Center of Transportation Materials, Ministry of Education, Schol of Materials Science and Engineering, Chang'an University, Xi?an 710061, P. R. China;
2. Key Laboratory of Applied Surface and Colloid Chemistry of Ministry of Education, School of Chemistry and Materials Science, Shaanxi Normal University, Xi'an 710062, P. R. China

Received Date: 7 June 2011
Available Online: 19 August 2011
Fund Project: 国家自然科学基金(20903015) (20903015)

Ag₃PO₄-P(AM-co-MAA) composite microspheres were prepared by the combination of a polymeric microgel method and a reverse micelle technique. Novel silver-poly(acrylamide-co-methacrylic acid) [Ag-P(AM-co-MAA)] composite microspheres with sizes ranging in the tens of micrometers and containing a patterned surface as well as core/shell structures were prepared by the chemical reduction of Ag₃PO₄-P(AM-co-MAA) composite microspheres in ethanol. Energy dispersive X-ray (EDX) analysis revealed that the chemical composition of the"shell"is dominated by Ag, but the"core"is dominated by the template, P(AM-co-MAA). Scanning electron microscopy (SEM) results demonstrate that the surface morphology of the Ag-polymer composite microspheres is similar to that of their precursors and can be controlled to a certain extent by varying the composition of the template copolymer, the approaches and the amount of Ag₃PO₄ deposited. X-ray diffraction (XRD) indicated that the salt had been completely converted to Ag. Biological antimicrobial experiments showed that this kind of composites exhibit distinctive antibacterial activity toward Escherichia coli and Staphylococcus aureus.
- Silver,
- Silver phosphate,
- Composite microspheres,
- Morphology transcription,
- Core-shell structure,
- Antibacterial
1. [1]
  (1) Yang, D. P.; Chen, S. H.; Huang, P.;Wang, X. S.; Jiang,W. Q.; Pandoli, O.; Cui, D. X. Green Chem. 2010, 12, 2038.
2. [2]
  (2) Zheng, X. L.; Guo, D.W; Shao Y. L.; Jia, S.; Xu, S. P.; Zhao, B.; Xu,W. Q. Langmuir 2008, 24, 4394.
3. [3]
  (3) Kumar, R.; Münstedt, H. Biomaterials 2005, 26, 2081.
4. [4]
  (4) Xiao, H. P.; Xia,Y. Y. Polym. Eng. Sci. 2010, 9, 1767.
5. [5]
  (5) Sun, Y. G. J. Phys. Chem. C 2010, 114, 2127.
6. [6]
  (6) F?rster, S.; Plantenberg, T. Angew Chem. Int. Edit. 2002, 41, 688.
7. [7]
  (7) Zhang, J. H.; Bai, L.; Zhang, K.; Cui, Z. C.; Zhang, G.; Yang, B. J. Mater. Chem. 2003, 13, 514.
8. [8]
  (8) Pol, V. G.; Gedanken, A.; Moreno, J. C. Chem. Mater. 2003, 15, 1111.
9. [9]
  (9) Cui, H. M.; Liu, H.;Wang, J. Y.; Li, X. F. H.; Boughton, R. I. J. Cryst. Growth 2004, 271, 456.
10. [10]
  (10) Pol, V. G.; Grisaru, H.; Gedanken, A. Langmuir 2005, 21, 3635.
11. [11]
  (11) Zhu,Y. J.; Qian, Y. T.; Li, X. J.; Zhang. M.W. Chem. Commun. 1997, No. 12, 1081.
12. [12]
  (12) Wu, D. Z.; Ge, X.W.; Huang, Y. H.; Zhang, Z. C.; Ye, Q. Mater. Lett. 2003, 57, 3549.
13. [13]
  (13) Choi, S. H.; Zhang, Y. P.; palan, A.; Lee, K. P.; Kang, H. D. Colloids Surf. A 1987, 25, 155.
14. [14]
  (14) Cheng, D. M.; Zhou, X. D.; Xia, H. B.; Chan, H. S. O. Chem. Mater. 2005, 17, 3578.
15. [15]
  (15) Wang, P. H.; Pan, C. Y. Eur. Polym. J. 2000, 36, 2297.
16. [16]
  (16) Wang, P. H.; Pan, C. Y. Colloid Polym. Sci. 2002, 280, 152.
17. [17]
  (17) Tierno, P.; edel,W. A. J. Phys. Chem. B 2006, 110, 3043.
18. [18]
  (18) Xu, L. N.; Zhou, K. C.; Xu, H. F.; Zhang, H. Q.; Huang, L.; Liao, J. H.; Xun, A. Q.; Gu, N.; Shen, H. Y.; Liu, J. Z. Appl. Surf. Sci. 2001, 183, 58.
19. [19]
  (19) Dong, A. G.;Wang, Y. J.; Tang, Y.; Ren, N.; Yang,W. L.; Gao, Z. Chem. Commun. 2002, No. 4, 350.
20. [20]
  (20) Zhang, J. H.; Liu, J. B.;Wang, S. Z.; Zhan, P.;Wang, Z. L.; Ming, N. B. Adv. Funct. Mater. 2004, 14, 1089.
21. [21]
  (21) Xia, H. Y.; Zhang, Y.; Peng, J. X.; Fang, Y.; Gu, Z. Z. Colloid Polym. Sci. 2006, 284, 1221.
22. [22]
  (22) Deng, Y. H.; Qi, D.W.; Deng, C. H.; Zhang, X. M.; Zhao, D. Y. J. Am. Chem. Soc. 2008, 130, 28.
23. [23]
  (23) Zhang, J. G.; Xu, S. Q.; Kumacheva, E. Adv. Mater. 2005, 17, 2336.
24. [24]
  (24) Wang, G. Z.; Xia, H. Y.; Zhang, Y.; Peng, S. J. Acta Chim. Sin. 2007, 65, 2051.
25. [25]
  [王公正, 夏慧芸, 张颖, 彭世杰. 化学学报, 2007, 65, 2051.]
26. [26]
  (25) Suzuki, D.; Kawaguchi, H. Langmuir 2006, 22, 3818.
27. [27]
  (26) Bai, C. L.; Fang, Y.; Zhang, Y.; Chen, B. B. Langmuir 2004, 20, 263.
28. [28]
  (27) Fang, Y.; Bai, C. L.; Zhang, Y. Chem. Commun. 2004, No. 4,, 804.
29. [29]
  (28) Wu, H. T.; Zhang, Y.; Ning, X. L.; Liang, H. L.; Fang, Y. Acta Phys. Chim. Sin. 2008, 24, 646.
30. [30]
  [吴华涛, 张颖, 宁向莉, 梁红莲, 房喻, 物理化学学报, 2008, 24, 646.]
31. [31]
  (29) Zhang, Y.; Xia, H. Y.; Xie, Y. X.;Wang, R. F.; Li. X. J. J. Colloid Interface Sci. 2006, 30, 210.
32. [32]
  (30) Xia, H. Y.; Zhang, Y.; Sun, S.; Fang, Y. Colloid Polym. Sci. 2007, 285, 1655.
33. [33]
  (31) Dloczik, L.; K?nenkamp, R. Nano. Lett. 2003, 3, 651.
34. [34]
  (32) Mirkin, C. A.; Rogers, J. A. MRS Bull. 2001, 26, 506.
35. [35]
  (33) Dioczik, L.; Engelhardt, R.; Ernst, K.; Fiechter, S.; Sieber, I.; K?nenkamp, R. Appl. Phys. Lett. 2001, 78, 3687.
36. [36]
  (34) Jeong, U. Y.; Kim, J. U.; Xia, Y. N. Nano Lett. 2005, 5, 937.
37. [37]
  (35) Yin, Y. D.; Rioux, R. M.; Erdomez, C. K.; Hughes, S.; Somorjai, G. A.; Alivisatos, A. P. Science 2004, 304, 711.
38. [38]
  (36) Yang, J. H.; Qi, L. M.; Lu, C. H.; Ma, J. M.; Cheng, H. M. Angew Chem. Int. Edit. 2005, 44, 598.
39. [39]
  (37) Smigelskas, A. D.; Kirkendall, E. O. Trans. Am. Inst. Min. Metall. Pet. Eng. 1947, 171, 130.
1. [1]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
2. [2]
  Laiying Zhang , Yaxian Zhu . Exploring the Silver Family. University Chemistry, 2024, 39(9): 1-4. doi: 10.12461/PKU.DXHX202409015
3. [3]
  Shipeng WANG , Shangyu XIE , Luxian LIANG , Xuehong WANG , Jie WEI , Deqiang WANG . Piezoelectric effect of Mn, Bi co-doped sodium niobate for promoting cell proliferation and bacteriostasis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1919-1931. doi: 10.11862/CJIC.20240094
4. [4]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
5. [5]
  Qijin Mo , Meifang Zhuo , Zhiyi Zhong , Chunfang Gan , Lixia Zhang . Research-Oriented Experimental Teaching in Chemistry Education at Normal University: Taking the Project of Recovering Silver Nitrate from Silver-Containing Waste as an Example. University Chemistry, 2024, 39(6): 201-206. doi: 10.3866/PKU.DXHX202310099
6. [6]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
7. [7]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
8. [8]
  Yuanyi Lu , Jun Zhao , Hongshuang Li . Silver-Catalyzed Ring-Opening Minisci Reaction: Developing a Teaching Experiment Suitable for Undergraduates. University Chemistry, 2024, 39(11): 225-231. doi: 10.3866/PKU.DXHX202401088
9. [9]
  Haiyuan Wang , Yiming Tang , Haoran Guo , Guohui Chen , Yajing Sun , Chao Zhao , Zhen Zhang . Comprehensive Chemistry Experimental Teaching Design Based on the Integration of Science and Education: Preparation and Catalytic Properties of Silver Nanomaterials. University Chemistry, 2024, 39(10): 219-228. doi: 10.12461/PKU.DXHX202404067
10. [10]
  Dong-Bing Cheng , Junxin Duan , Haiyu Gao . Experimental Teaching Design on Chitosan Extraction and Preparation of Antibacterial Gel. University Chemistry, 2024, 39(2): 330-339. doi: 10.3866/PKU.DXHX202308053
11. [11]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
12. [12]
  Fan Wu , Wenchang Tian , Jin Liu , Qiuting Zhang , YanHui Zhong , Zian Lin . Core-Shell Structured Covalent Organic Framework-Coated Silica Microspheres as Mixed-Mode Stationary Phase for High Performance Liquid Chromatography. University Chemistry, 2024, 39(11): 319-326. doi: 10.12461/PKU.DXHX202403031
13. [13]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
14. [14]
  Jingjie Tang , Luying Xie , Jiayu Liu , Shangyu Shi , Xinyu Sun , Jiayang Lin , Qikun Yang , Chuan'ang Yu , Zecheng Wang , Yingying Wang , Zengyang Xie . Efficient Rapid Synthesis and Antibacterial Activities of Tosylhydrazones: A Recommended Innovative Chemistry Experiment for Undergraduate Medical University. University Chemistry, 2024, 39(3): 316-326. doi: 10.3866/PKU.DXHX202309091
15. [15]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
16. [16]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
17. [17]
  Juan Yuan , Bin Zhang , Jinping Wu , Mengfan Wang . Design of a Comprehensive Experiment on Preparation and Characterization of Cu₂(Salen)₂ Nanomaterials with Two Distinct Morphologies. University Chemistry, 2024, 39(10): 420-425. doi: 10.3866/PKU.DXHX202402014
18. [18]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
19. [19]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
20. [20]
  Renxiao Liang , Zhe Zhong , Zhangling Jin , Lijuan Shi , Yixia Jia . A Palladium/Chiral Phosphoric Acid Relay Catalysis for the One-Pot Three-Step Synthesis of Chiral Tetrahydroquinoline. University Chemistry, 2024, 39(5): 209-217. doi: 10.3866/PKU.DXHX202311024

Get Citation

PDF

XML

Metrics

PDF Downloads(871)
Abstract views(2330)
HTML views(7)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142