Citation: JIANG Jin-Qiang, JIANG Tao, ZHANG Cheng-Bang, CHENG Hao, LIU Xiao-Ya, ZHANG Sheng-Wen, CHEN Ming-Qing. Inclusion Behavior of β-Cyclodextrin and Amphiphilic Telechelic Polymer C-PDMAEMA[J]. Acta Physico-Chimica Sinica, ;2011, 27(11): 2691-2696. doi: 10.3866/PKU.WHXB20111019 shu

Inclusion Behavior of β-Cyclodextrin and Amphiphilic Telechelic Polymer C-PDMAEMA

1.
School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, Jiangsu Province, P. R. China

Received Date: 31 May 2011
Available Online: 19 August 2011
Fund Project: 国家自然科学基金(20704017, 50973044) (20704017, 50973044)及中央高校基本科研业务费专项资金(JUSRP31003)资助项目 (JUSRP31003)

A novel photosensitive telechelic polymer C-PDMAEMA was prepared using 2-(dimethylamino) ethyl methacrylate (DAMEMA) as a monomer, azobisisobutyronitrile (AIBN) as inititon, coumarincontaining disulfides (C-S-S-C) as a chain transfer agent in the presence of tributyl phosphine (Bu₃P) and water. Characterization was carried out using ¹H-nuclear magnetic responance (¹H-NMR), gel permeation chromatography (GPC) and Fourier transform infrared (FTIR) spectroscopy. It was found that the coumarin can form a host-guest inclusion complex with β-CD in aqueous solution. The UV-Vis and fluorescence spectra showed that only a 1:1 complex was formed with an inclusion complex K=(1.270±0.062)×10⁴ L· mol^-1. The irradiation experiment showed that this host-guest inclusion might have a very small effect on the photodimerization of coumarin end groups.
- Coumarin,
- Cyclodextrin,
- Inclusion complex,
- Telechelic,
- Photo-dimerization
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