Citation: WANG Song, MAO Dong-Sen, GUO Xiao-Ming, LU Guan-Zhong. Dimethyl Ether Synthesis from CO₂ Hydrogenation over CuO-TiO₂-ZrO₂/HZSM-5 Catalysts[J]. Acta Physico-Chimica Sinica, ;2011, 27(11): 2651-2658. doi: 10.3866/PKU.WHXB20111018 shu

Dimethyl Ether Synthesis from CO₂ Hydrogenation over CuO-TiO₂-ZrO₂/HZSM-5 Catalysts

1.
Research Institute of Applied Catalysis, School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 200235, P. R. China

Received Date: 9 May 2011
Available Online: 19 August 2011
Fund Project: 上海市科委(08520513600) (08520513600) 上海市教委重点学科(J51503) (J51503)上海市优秀青年教师专项基金(yyy10078)资助项目 (yyy10078)

A series of CuO-TiO₂-ZrO₂ mixed oxides with different CuO mass fractions (50%-80%) were prepared by co-precipitation and characterized by X-ray diffraction (XRD), N₂ physisorption, temperatureprogrammed reduction of hydrogen (H₂-TPR), temperature-programmed desorption of carbon dioxide (CO₂-TPD) and hydrogen (H₂-TPD), and reactive N₂O adsorption techniques. The prepared CuO-TiO₂-ZrO₂ samples were mixed physically with HZSM-5 zeolite to synthesize dimethyl ether (DME) from CO₂ hydrogenation in a fixed bed reactor at 250°C, 3.0 MPa, gas hourly space velocity (GHSV) of 1500 mL·g^-1· h^-1, and volume ratio of 2.8 for H₂ to CO₂. We found that the conversion of CO₂ increased with an increase in CuO content, reached a maximum at a CuO content of 70% and then decreased. The selectivity of DME increased with an increase in CuO content initially and remained essentially constant when the CuO content was ≥70%. Thus, the yield of DME reached a maximum of 13.2% at 70% CuO content. The productivity of the oxygenated compounds (including methanol and DME) on the CuO-TiO₂-ZrO₂/HZSM-5 catalysts is closely related to the metallic copper surface area.
- Hydrogenation of CO₂,
- Dimethyl ether,
- CuO-TiO₂-ZrO₂ mixed oxide,
- Zeolite HZSM-5,
- Bifunctional catalyst
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Dimethyl Ether Synthesis from CO2 Hydrogenation over CuO-TiO2-ZrO2/HZSM-5 Catalysts

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通讯作者: 陈斌, bchen63@163.com

Dimethyl Ether Synthesis from CO₂ Hydrogenation over CuO-TiO₂-ZrO₂/HZSM-5 Catalysts