Citation:
XU Shou-Dong, ZHUANG Quan-Chao, SHI Yue-Li, ZHU Ya-Bo, QIU Xiang-Yun, SUN Zhi. Electrochemical Impedance Spectra of Intercalation Compound Electrodes: Models and Theoretical Simulations[J]. Acta Physico-Chimica Sinica,
;2011, 27(10): 2353-2359.
doi:
10.3866/PKU.WHXB20111004
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Single intercalation particles, mixed particles, homogeneous porous electrodes and nonhomogeneous, multilayered porous electrode models are proposed in this paper. Some peculiar features of impedance spectra were simulated using the above-mentioned models. The results reveal that the features of impedance spectra of the single intercalation particle and the mixed particles are the same and the features consist of lithium ion migration through the solid electrolyte interphase (SEI) film (RSEI‖CSEI semicircle), an electron and ion transfer process (Rct‖Cdl semicircle), and a finite-diffusion Warburg element. For the nonhomogeneous, multilayered porous electrodes model, a peculiar feature of impedance spectra is that a new arc appears in the Nyquist plot. A detailed analysis revealed that a different particle size distribution could lead to the appearance of a new arc and a different layer distribution (a thicker layer and a thinner layer), which could lead to a well-developed semicircle.
-
-
-
[1]
(1) Zhuang, Q. C.;Wei, T.; Du, L. L.; Cui, Y. L.; Fang, L.; Sun, S. G. J. Phys. Chem. C 2010, 114, 8614.
-
[2]
(2) Zhuang, Q. C.; Xu, S. D.; Qiu, X. Y.; Cui, Y. L.; Fang, L.; Sun, S. G. Progress in Chemistry 2010, 22 (6), 1044.
-
[3]
[庄全超, 徐守冬, 邱祥云, 崔永丽, 方亮, 孙世刚. 化学进展, 2010, 22 (6), 1044.]
-
[4]
(3) Wei, T.; Zhuang, Q. C.;Wu, C.; Cui, Y. L.; Fang, L.; Sun, S. G. Acta Chim. Sin. 2010, 68 (15), 1481.
-
[5]
[魏涛, 庄全超, 崔永丽, 方亮, 孙世刚. 化学学报, 2010, 68 (15), 1481.]
-
[6]
(4) Qiu, X. Y.; Zhuang, Q. C.;Wang, H. M.; Cui, Y. L.; Fang, L.; Sun, S. G. Acta Phys. -Chim. Sin. 2010, 26 (6), 1499.
-
[7]
[邱祥云, 庄全超, 王红明, 崔永丽, 方亮, 孙世刚. 物理化学学报, 2010, 26 (6), 1499.]
-
[8]
(5) Song, J. Y.; Lee, H. H.;Wang, Y. Y.;Wan, C. C. J. Power Sources 2002, 111, 255.
-
[9]
(6) Xu, M. M.; Dewald, H. D. Electrochim. Acta 2005, 50, 5473.
-
[10]
(7) Levi, M. D.; Aurbach, D. J. Phys. Chem. B 2005, 109, 2763.
-
[11]
(8) Meyers, J. P.; Doyle, M.; Darling, R. M.; Newman, J. J. Electrochem. Soc. 2000, 147 (8), 2930.
-
[12]
(9) Doyle, M.; Meyers, J. P.; Newman, J. J. Electrochem. Soc. 2000, 147 (1), 99.
-
[13]
(10) Devan, S.; Subramanianb, V. R.; White, R. E. J. Electrochem. Soc. 2004, 151 (6), A905.
-
[14]
(11) Sikha, G.; White, R. E. J. Electrochem. Soc. 2007, 154 (1), A43.
-
[15]
(12) Sikha, G.; White, R. E. J. Electrochem. Soc. 2008, 155 (12), A893.
-
[16]
(13) Dees, D.; Gunen, E.; Abraham, D.; Jansen, A.; Prakash, J. J. Electrochem. Soc. 2005, 152 (7), A1409.
-
[17]
(14) Huang, R.W. J. M.; Chung, F.; Kelder, E. M. J. Electrochem. Soc. 2006, 153 (8), A1459.
-
[18]
(15) Mantia, F. L.; Vetter, J.; Novák, P. Electrochim. Acta 2008, 53, 4109.
-
[19]
(16) Andre, D.; Meiler, M.; Steiner, K.;Walz, H.; Soczka-Guth, T.; Sauer, D. U. J. Power Sources 2011, 196, 5349.
- [20]
-
[21]
(18) Schmidt, A. P.; Bitzer, M.; Imre, á.W.; Guzzella, L. J. Power Sources 2010, 195, 5071.
-
[22]
(19) Bard, A. J.; Faulkner, L. R. Electrochemical Methods: Fundamentals and Applications, 2nd ed.; JohnWiley & Sons Inc.: New York, 2001; pp 92-116.
-
[23]
(20) Levi, M. D.; Aurbach, D. J. Phys. Chem. B 2004, 108, 11693.
-
[24]
(21) Levi, M. D.; Aurbach, D. J. Power Sources 2005, 146, 727.
-
[25]
(22) Levi, M. D.; Aurbach, D. J. Phys. Chem. B 1997, 101, 4630.
-
[26]
(23) Levi, M. D.;Wang, C.; Aurbach, D. J. Electroanal. Chem. 2004, 561, 1.
-
[27]
(24) Itagaki, M.; Kobari, N.; Yotsuda, S.;Watanabe, K.; Kinoshita, S.; Ue, M. J. Power Sources 2004, 135, 255.
- [28]
-
[29]
(26) Diard, J. P.; Le rrec, B.; Montella, C. J. Electroanal. Chem. 2001, 499, 67.
-
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