Citation: XUE Rong, YAN Jing-Wang, TIAN Ying, YI Bao-Lian. Lanthanum Doped Manganese Dioxide/Carbon Nanotube Composite Electrodes for Electrochemical Supercapacitors[J]. Acta Physico-Chimica Sinica, ;2011, 27(10): 2340-2346. doi: 10.3866/PKU.WHXB20111002 shu

Lanthanum Doped Manganese Dioxide/Carbon Nanotube Composite Electrodes for Electrochemical Supercapacitors

1.
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning Province, P. R. China

Received Date: 24 February 2011
Available Online: 15 August 2011
Fund Project:

Although higher specific capacitances have been achieved for manganese dioxide/multi-walled carbon nanotubes (MnO₂/MWCNTs), the low conductivity of MnO₂ is still the main obstacle in increasing its loading or film thickness. Another problem is that the cycling stability of MnO₂/MWCNTs is much lower than that of activated carbon electrodes. Therefore, this new type of electrode material is still limited in application until now. In this paper, lanthanum doped MnO₂/MWCNTs composites were prepared by an in situ redox method. The surface morphology and phase structure of the as-prepared samples were investigated by transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier transform infrared (FTIR) spectrometry. The electrochemical properties were investigated by cyclic voltammetry (CV), galvanostatic charge/discharge, and electrochemical impedance spectroscopy (EIS). The La-doped MnO₂ could be formed on the MWCNTs by the reduction of MnO₄^-. The resistance of the composite electrodes decreased because La doping increases the number of imperfections in the MnO₂ lattice, which improves the electrical conductivity and the electrochemical activity of the electrode. La doping is, therefore, an effective way to overcome the intrinsic low electric conductivity of MnO₂, which facilitates an increase in the loading or the film thickness of MnO₂ without increasing electrode resistance. The major effect of La doping is a significant improvement in the charge/discharge cycling performance of a symmetric electrochemical supercapacitor with electrodes composed of MnO₂/ MWCNTs. The specific capacitance of the composite electrodes was improved by La doping.
- Supercapacitor,
- Multi-walled carbon nanotube,
- Lanthanum,
- Manganese dioxide,
- Pseudocapacitance
1. [1]
  (1) Conway, B. E. Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications; Kluwer Academic/Plenum Publishers: New York, 1999.
2. [2]
  (2) Burke, A. Electrochim. Acta 2007, 53, 1083.
3. [3]
  (3) Conway, B. E.; Pell,W. G. J. Solid State Electrochem. 2003, 7, 637.
4. [4]
  (4) Qu, D. Y.; Shi, H. J. Power Sources 1998, 74, 99.
5. [5]
  (5) Arabale, G.;Wagh, D.; Kulkarni, M.; Mulla, I. S.; Vernekar, S. P.; Vijayamohanan, K.; Rao, A. M. Chem. Phys. Lett. 2003, 376, 207.
6. [6]
  (6) Sharma, R. K.; Karakoti, A.; Seal, S.; Zhai, L. J. Power Sources 2010, 195, 1256.
7. [7]
  (7) Zein, S. H. S.; Yeoh, L. C.; Chai, S. P.; Mohamed, A. R.; Mahayuddin, M. E. M. J Mater. Process Technol. 2007, 190, 402.
8. [8]
  (8) Toupin, M.; Brousse, T.; Bélanger, D. Chem. Mater. 2004, 16, 3184.
9. [9]
  (9) Subramanian, V.; Zhu, H.W.;Wei, B. Q. Electrochem. Commun. 2006, 8, 827.
10. [10]
  (10) Shao, G. J.; Yao, Y.; Zhang, S. P.; He, P. Rare Metals 2009, 28, 132.
11. [11]
  (11) Man?i?, D.; Paunovi?, V.; Vijatovi?, M.; Stojanovi?, B.; ?ivkovi?, L. Science of Sintering 2008, 40, 283.
12. [12]
  (12) Ma, S. B.; Ahn, K. Y.; Lee, E. S.; Oh, K. H.; Kim, K. B. Carbon 2007, 45, 375.
13. [13]
  (13) Athou?l, L.; Moser, F.; Dugas, R.; Crosnier, O.; Bélanger, D.; Brousse, T. J. Phys. Chem. C 2008, 112, 7270.
14. [14]
  (14) Jin, X.; Zhou,W.; Zhang, S.; Chen, G. Z. Small 2007, 3, 1513.
15. [15]
  (15) Kovtyukhova, N. I.; Mallouk, T. E.; Pan, L.; Dickey, E. C. J. Am. Chem. Soc. 2003, 125, 9761.
16. [16]
  (16) Holzinger, M.; Vostrowsky, O.; Hirsch, A.; Hennrich, F.; Kappes, M.;Weiss, R.; Jellen, F. Angew Chem. Int. Edit. 2001, 40, 4002.
17. [17]
  (17) Kim, U. J.; Furtado, C. A.; Liu, X. M.; Chen, G. G.; Eklund, P. C. J. Am. Chem. Soc. 2005, 127, 15437.
18. [18]
  (18) Kuznetsova, A.; Mawhinney, D. B.; Naumenko, V.; Yates, J. T.; Liu, J.; Smalley, R. E. Chem. Phys. Lett. 2000, 321, 292.
19. [19]
  (19) Lu, K. L.; La , R. M.; Chen, Y. K.; Green, M. L. H.; Harris, P. J. F.; Tsang, S. C. Carbon 1996, 34, 814.
20. [20]
  (20) Xie, X. F.; Gao, L. Carbon 2007, 45, 2365.
21. [21]
  (21) White, A. M.; Slade, R. C. T. Electrochim. Acta 2004, 49, 861.
22. [22]
  (22) Masarapu, C.; Zeng, H. F.; Hung, K. H.;Wei, B. Q. ACS Nano 2009, 3, 2199.
23. [23]
  (23) Hu, C. C.;Wang, C. C. J. Electrochem. Soc. 2003, 150, A1079.
24. [24]
  (24) Wu, M. S.; Chiang, P. C. J. Electrochemical and Solid State Letters 2004, 7, A123.
25. [25]
  (25) Yan, J.; Fan, Z. J.;Wei, T.; Cheng, J.; Shao, B.;Wang, K.; Song, L. P.; Zhang, M. L. J. Power Sources 2009, 194, 1202.
26. [26]
  (26) Li, Y.; Xie, H. Q.;Wang, J. F.; Chen, L. F. Mater. Lett 2011, 65, 403.
27. [27]
  (27) Raymundo-Piñero, E.; Khomenko, V.; Frackowiak, E.; Béguin, F. J. Electrochem. Soc. 2005, 152, A229.
28. [28]
  (28) Fang, D. L.;Wu, B. C.; Mao, A. Q.; Yan, Y.; Zheng, C. H. J. Alloy. Compd. 2010, 507, 526.
29. [29]
  (29) Wu, M.; Snook, G. A.; Chen, G. Z.; Fray, D. J. Electrochem. Commun. 2004, 6, 499.
30. [30]
  (30) Pourbaix, M. Atlas of electrochemical equilibria in aqueous solutions; National Association of Corrosion Engineers, 1974.
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沈阳化工大学材料科学与工程学院沈阳 110142