Citation: GAO Yun-Yan, LI Hai-Xia, OU Zhi-Ze, HAO Ping, LI Yi, YANG Guo-Qiang. Enhancing the Catalytic Activity of Peroxidase by Adsorption onto Fe₃O₄ Magnetic Nanoparticle/Multiwalled Carbon Nanotube Composite Surfaces[J]. Acta Physico-Chimica Sinica, ;2011, 27(10): 2469-2477. doi: 10.3866/PKU.WHXB20110939 shu

Enhancing the Catalytic Activity of Peroxidase by Adsorption onto Fe₃O₄ Magnetic Nanoparticle/Multiwalled Carbon Nanotube Composite Surfaces

GAO Yun-Yan ^1, ,
LI Hai-Xia ¹ ,
OU Zhi-Ze ^1, ,
HAO Ping ¹ ,
LI Yi ² ,
YANG Guo-Qiang ³

1.
1. Ministry of Education Key Laboratory of Space, Applied Physics and Chemistry, School of Science, Northwestern Polytechnical University, Xi'an 710072, P. R. China;
2. Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China;
3. Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

Received Date: 10 April 2011
Available Online: 11 August 2011
Fund Project: 国家自然科学基金(21073143) (21073143) 教育部春晖计划基金(Z2009-1-71002, Z2009-1-71006) (Z2009-1-71002, Z2009-1-71006)西北工业大学基础研究基金(JC200822, JC20100239)资助项目 (JC200822, JC20100239)

Fe₃O₄ magnetic nanoparticles were prepared by co-precipitation and supported on the surface of aminopyridine-grafted multiwalled carbon nanotubes (MWCNT-AP), affording a superparamagnetic Fe₃O₄/MWCNT-AP composite with od dispersity. The Fe₃O₄/MWCNT-AP composites were characterized by Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), and hysteresis curve measurements. Transmission electron microscopy (TEM) experimental results suggest that the Fe₃O₄ nanoparticles are mainly adsorbed on the tips of the MWCNT-AP. UV-Vis absorption and fluorescence results demonstrate that horseradish peroxidase (HRP) can be physically adsorbed onto the surfaces of the Fe₃O₄/MWCNT-AP composite. Under acidic conditions (pH 4.0), the maximum reaction rate (v_max) value of the HRP increases 3-fold after interaction with Fe₃O₄/MWCNT-AP.
- Carbon nanotube,
- Magnetic nanoparticle,
- Peroxidase,
- Nanocomposite,
- Superparamagnetic property
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Enhancing the Catalytic Activity of Peroxidase by Adsorption onto Fe₃O₄ Magnetic Nanoparticle/Multiwalled Carbon Nanotube Composite Surfaces