Citation: GAO Wen-Chao, HUANG Tao, SHEN Yu-Dong, YU Ai-Shui. Phenolic Resin Coated Natural Graphite Oxide as an Anode Material for Lithium Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2011, 27(09): 2129-2134. doi: 10.3866/PKU.WHXB20110933 shu

Phenolic Resin Coated Natural Graphite Oxide as an Anode Material for Lithium Ion Batteries

1.
1. Department of Chemistry, Institute of New Energy, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200438, P. R. China;
2. Wuxi Dongheng New Energy Material Co., Ltd, Wuxi 214037, Jiangsu Province, P. R. China

Received Date: 13 May 2011
Available Online: 29 July 2011
Fund Project: 上海市基础研究重点项目(10JC1401500) (10JC1401500)上海市分子催化和功能材料重点实验室(08DZ2270500)资助 (08DZ2270500)

A core-shell structure of the carbon-coated natural graphite oxide composite was successfully prepared. Natural graphite was initially oxidized using concentrated sulfuric acid and then carbon coated by the carbonization of phenolic resin at high temperature. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and Raman techniques were used to characterize the morphology and structure of the natural graphite materials before and after oxidation and carbon coating by the pyrolysis of the phenolic resin. The results showed that the surface of the natural graphite particles became smoother and the surface defects were effectively modified after oxidation and carbon coating. The electrochemical test results showed that the electrochemical performance of the natural graphite improved significantly by oxidation with sulfuric acid and by carbon coating. When the covering amount of phenolic resin was 9% the modified natural graphite material gave the best electrochemical performance. Its initial discharge capacity was 434.0 mAh·g^-1 and it remained 361.6 mAh· g^-1 after 40 charge-discharge cycles. The discharge capacity of the untreated natural graphite was only 332.3 mAh·g^-1. The modification approach that improved the capacity of the natural graphite effectively is of great significance for the application of natural graphite in lithium ion batteries.
- Anode material,
- Natural graphite,
- Phenolic resin,
- Oxidation,
- Coating
1. [1]
  (1) Doyle, M.; Fuller, T. F.; Newman, J. J. Electrochem. Soc. 1993, 140, 1526.
2. [2]
  (2) Whittingham, M. S. Chem. Rev. 2004, 104 (10), 4271.
3. [3]
  (3) Li, F. Q.; Lai, Y. Q.; Zhang, Z. A.; Gao, H. Q.; Yang, J. Acta Phys. -Chim. Sin. 2008, 24, 1302. [李凡群, 赖延清, 张治安, 高宏权, 杨娟. 物理化学学报, 2008, 24, 1302.]
4. [4]
  (4) Zhao, H. P.; Ren, J. G.; He, X. M.; Li, J. J.; Jiang, C. Y.;Wan, C. R. Electrochim. Acta 2007, 52, 6006.
5. [5]
  (5) Yoshio, M.;Wang, H.; Fukuda, K.; Hara, Y.; Adachi, Y. J. Electrochem. Soc. 2000, 147, 1245.
6. [6]
  (6) Mao,W. Q.;Wang, J. M.; Xu, Z. H.; Niu, Z. X.; Zhang, J. Q. Electrochem. Commun. 2006, 8, 1326.
7. [7]
  (7) Menachem, C.;Wang, Y.; Floners, J.; Peled, E.; Greenbaum, S. G. J. Power Sources 1998, 76, 180.
8. [8]
  (8) Chen, J. T.; Zhou, H. H.; Chang,W. B.; Ci, Y. X. Acta Phys. -Chim. Sin. 2002, 18, 180. [陈继涛, 周恒辉, 常文保, 慈云祥. 物理化学学报, 2002, 18, 180.]
9. [9]
  (9) Zhang, H. L.; Li, F.; Liu, C. J. Phys. Chem. C 2008, 112, 7767.
10. [10]
  (10) Choi,W. C.; Byun, D. J.; Lee, J. K.; Cho, B.W. Electrochim. Acta 2004, 50, 523.
11. [11]
  (11) Takamura, T. Bull. Chem. Soc. Jpn. 2002, 75, 21.
12. [12]
  (12) Tossici, R.; Berrettoni, M.; Rosolen, M. J. Eletrochem. Soc. 1997, 144, 186.
13. [13]
  (13) Tanaka, U.; Sogabe, T.; Saka shi, H.; Tojo, T. Carbon 2001, 39, 931.
14. [14]
  (14) Guo, K. K.; Pan, Q. M.; Fan, S. B. J. Power Sources 2002, 111, 350.
15. [15]
  (15) Yu, Z. H.;Wu, F. Battery Bimonthly 2003, 33, 131. [俞政洪, 吴锋. 电池, 2003, 33, 131.]
16. [16]
  (16) Tuistra, F.; Koeing, J. L. J. Compos. Mater. 1970, 4, 492.
17. [17]
  (17) Tsumura, T.; Katanosaka, A.; Souma, I. Solid State Ionics 2000, 135, 209.
1. [1]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
2. [2]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . 高性能双金属氧化物负极的理性设计及储锂特性. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-. doi: 10.3866/PKU.WHXB202311005
3. [3]
  Peiyu Zhang , Aixin Song , Jingcheng Hao , Jiwei Cui . 高频超声法制备聚多巴胺薄膜综合实验. University Chemistry, 2025, 40(6): 210-214. doi: 10.12461/PKU.DXHX202407081
4. [4]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
5. [5]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
6. [6]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
7. [7]
  Zhuo WANG , Xiaotong LI , Zhipeng HU , Junqiao PAN . Three-dimensional porous carbon decorated with nano bismuth particles: Preparation and sodium storage properties. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 267-274. doi: 10.11862/CJIC.20240223
8. [8]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
9. [9]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
10. [10]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Corrosion inhibition of nickel-cobalt-phosphide in water by coating TiO₂ layer. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 365-384. doi: 10.11862/CJIC.20240063
11. [11]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
12. [12]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
13. [13]
  Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363
14. [14]
  Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . 钠离子电池中铁基异质结构负极材料的最新研究进展. Acta Physico-Chimica Sinica, 2025, 41(3): 2311015-. doi: 10.3866/PKU.WHXB202311015
15. [15]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
16. [16]
  Lisha LEI , Wei YONG , Yiting CHENG , Yibo WANG , Wenchao HUANG , Junhuan ZHAO , Zhongjie ZHAI , Yangbin DING . Application of regenerated cellulose and reduced graphene oxide film in synergistic power generation from moisture electricity generation and Mg-air batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1151-1161. doi: 10.11862/CJIC.20240202
17. [17]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
18. [18]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
19. [19]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
20. [20]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204

Get Citation

PDF

XML

Metrics

PDF Downloads(1662)
Abstract views(4810)
HTML views(113)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142