Citation: XIONG Peng-Fei, ZHONG Bei-Jing, YANG Fan. Heterogeneous Mechanism of C₁-C₄ on a Platinum Catalyst[J]. Acta Physico-Chimica Sinica, ;2011, 27(09): 2200-2208. doi: 10.3866/PKU.WHXB20110927 shu

Heterogeneous Mechanism of C₁-C₄ on a Platinum Catalyst

1.
Scool of Aerospace, Tsinghua University, Beijing 100084, P. R. China

Received Date: 16 May 2011
Available Online: 19 July 2011
Fund Project: 国家自然科学基金(50976056, 50721140648)资助项目 (50976056, 50721140648)

We developed a H₂ and C₁-C₄ heterogeneous mechanism to describe their catalytic reaction on a platinum catalyst. To verify the mechanism we carried out simulations with methane, ethane, propane, and n-butane and compared the results to the reported experimental data. The ignition and combustion (ignition or combustion of CH₄, C₂H₆ with or without adding H₂, C₃H₈ with or without adding H₂, C₄H₁₀ with adding H₂) was of interest. od agreement was obtained and we found that H₂ improved the ignition of propane and n-butane, and the combustion of ethane. However, their kinetic processes are different. Therefore, the H₂ and C₁-C₄ heterogeneous mechanism determined in this work is reasonable with some certainty and could be used to describe the characteristics of ignition and combustion, which can be used to analyze the kinetic process.
- Catalytic combustion,
- H₂ and C₁-C₄ heterogeneous mechanism,
- Validation with experimental data,
- Hydrogen-assisted catalytic ignition,
- Pt catalyst
1. [1]
  (1) Epstein, A. H.; Senturia, S. D. Science 1997, 276, 1211.
2. [2]
  (2) Fernandez-Pello, A. C. Proc. Combust. Inst. 2002, 29, 883.
3. [3]
  (3) Chigier, N.; Gemci, T. Electrohydrodynamic Atomization for MEMS Combustion Engines. In American Institute of Aeronautics and Astronautics. 41st Aerospace Sciences Meeting and Exhibit, Jan 6-9, 2003, Reno, Nevada. AIAA-2003-675, 2003.
4. [4]
  (4) Dunn-Rankin, D.; Leal, E. M.;Walther, D. C. Progress in Energy and Combustion Science 2005, 31, 422.
5. [5]
  (5) Maruta, K. Proc. Combust. Inst. 2011, 33, 125.
6. [6]
  (6) Chao, Y. C.; Chen, G. B.; Hsu, C. J.; Leu, T. S.;Wu, C. Y.; Cheng, T. S. Combust. Sci. Tech. 2004, 176, 1755.
7. [7]
  (7) Veser, G. Chem. Eng. Sci. 2001, 56, 1265.
8. [8]
  (8) Norton, D. G.;Wetzel, E. D.; Vlachos, D. G. Ind. Eng. Chem. Res. 2004, 43, 4833.
9. [9]
  (9) Boyarko, G. A.; Sung, C. J.; Schneider, S. J. Proc. Combust. Inst. 2005, 30, 2481.
10. [10]
  (10) Volchko, S. J.; Sung, C. J.; Huang, Y.; Schneider, S. J. J. Propul Power 2006, 22, 684.
11. [11]
  (11) Deutschmann, O.; Schmidt, R.; Behrendt, F.;Warnatz, J. Proc. Combust. Inst. 1996, 26, 1747.
12. [12]
  (12) Deutschmann, O.; Maier, L. I.; Riedel, U.; Stroemman, A. H.; Dibble, R.W. Catal. Today 2000, 59, 141.
13. [13]
  (13) Zerkle, D. K.; Allendorf, M. D.;Wolf, M.; Deutschmann, O. J. Catal. 2000, 196, 18.
14. [14]
  (14) Chatterjee, D.; Deutschmann, O.;Warnatz, J. Faraday Discuss. 2001, 119, 371.
15. [15]
  (15) Xu, C.; Koel, B. E.; Paffett, M. T. Langmuir 1994, 10, 166.
16. [16]
  (16) Roke, S.; Coquel, J. M.; Kleyn, A.W. Chem. Phys. Lett. 2000, 323, 201.
17. [17]
  (17) Weaver, J. F.; Krzyzowski, M. A.; Robert, J. M. J. Chem. Phys. 2000, 112, 396.
18. [18]
  (18) Pirngruber, G. D.; Seshan, K.; Lercher, J. A. J. Catal. 2000, 190, 338.
19. [19]
  (19) Jackson, S. D.; Kelly, G. J.;Webb, G. J. Catal. 1998, 176, 225.
20. [20]
  (20) Lee, I.; Zaera, F. J. Phys. Chem. B 2005, 109, 2745.
21. [21]
  (21) Duane, A. G.; Schmidt, L. D. Science 1996, 271, 1560.
22. [22]
  (22) Katano, S.; Kato, H. S.; Kawai, M.; Domen, K. J. Phys. Chem. C 2008, 112, 17219.
23. [23]
  (23) Marinov, N. M.; Pitz,W. J.;Westbrook, C. K.; Vincitore, A. M.; Castaldi, M. J.; Senkan, S. M.; Melius, C. F. Combust. Flame 1998, 114, 192.
24. [24]
  (24) Zhong, B. J.; Hong, Z. K. Heat and Power Engineering 2003, 18, 584. [钟北京, 洪泽恺. 热能动力工程, 2003, 18, 584.]
25. [25]
  (25) Schwiedernoch, R.; Tischer, S.; Deutschmann, O.;Warnatz, J. Proc. Combust. Inst. 2002, 29, 1005.
26. [26]
  (26) Bodke, A. S.; Bharadwaj, S. S.; Schmidt, L. D. J. Catal. 1998, 179, 138.
27. [27]
  (27) Bodke, A. S.; Henning, D.; Schmidt, L. D.; Bharadwaj, S. S.; Maj, J. J.; Siddall, J. J. Catal. 2000, 191, 62.
28. [28]
  (28) Beretta, A.; Piovesan, L.; Forzatti, P. J. Catal. 1999, 184, 455.
29. [29]
  (29) Norton, D. G.; Vlachos, D. G. Proc. Combust. Inst. 2005, 30, 2473.
30. [30]
  (30) Zhong, B. J.; Yang, Q. T.; Yang, F. Combust. Flame 2010, 157, 2005.
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Heterogeneous Mechanism of C₁-C₄ on a Platinum Catalyst