Citation: XIONG Peng-Fei, ZHONG Bei-Jing, YANG Fan. Heterogeneous Mechanism of C₁-C₄ on a Platinum Catalyst[J]. Acta Physico-Chimica Sinica, ;2011, 27(09): 2200-2208. doi: 10.3866/PKU.WHXB20110927 shu

Heterogeneous Mechanism of C₁-C₄ on a Platinum Catalyst

1.
Scool of Aerospace, Tsinghua University, Beijing 100084, P. R. China

Received Date: 16 May 2011
Available Online: 19 July 2011
Fund Project: 国家自然科学基金(50976056, 50721140648)资助项目 (50976056, 50721140648)

We developed a H₂ and C₁-C₄ heterogeneous mechanism to describe their catalytic reaction on a platinum catalyst. To verify the mechanism we carried out simulations with methane, ethane, propane, and n-butane and compared the results to the reported experimental data. The ignition and combustion (ignition or combustion of CH₄, C₂H₆ with or without adding H₂, C₃H₈ with or without adding H₂, C₄H₁₀ with adding H₂) was of interest. od agreement was obtained and we found that H₂ improved the ignition of propane and n-butane, and the combustion of ethane. However, their kinetic processes are different. Therefore, the H₂ and C₁-C₄ heterogeneous mechanism determined in this work is reasonable with some certainty and could be used to describe the characteristics of ignition and combustion, which can be used to analyze the kinetic process.
- Catalytic combustion,
- H₂ and C₁-C₄ heterogeneous mechanism,
- Validation with experimental data,
- Hydrogen-assisted catalytic ignition,
- Pt catalyst
1. [1]
  (1) Epstein, A. H.; Senturia, S. D. Science 1997, 276, 1211.
2. [2]
  (2) Fernandez-Pello, A. C. Proc. Combust. Inst. 2002, 29, 883.
3. [3]
  (3) Chigier, N.; Gemci, T. Electrohydrodynamic Atomization for MEMS Combustion Engines. In American Institute of Aeronautics and Astronautics. 41st Aerospace Sciences Meeting and Exhibit, Jan 6-9, 2003, Reno, Nevada. AIAA-2003-675, 2003.
4. [4]
  (4) Dunn-Rankin, D.; Leal, E. M.;Walther, D. C. Progress in Energy and Combustion Science 2005, 31, 422.
5. [5]
  (5) Maruta, K. Proc. Combust. Inst. 2011, 33, 125.
6. [6]
  (6) Chao, Y. C.; Chen, G. B.; Hsu, C. J.; Leu, T. S.;Wu, C. Y.; Cheng, T. S. Combust. Sci. Tech. 2004, 176, 1755.
7. [7]
  (7) Veser, G. Chem. Eng. Sci. 2001, 56, 1265.
8. [8]
  (8) Norton, D. G.;Wetzel, E. D.; Vlachos, D. G. Ind. Eng. Chem. Res. 2004, 43, 4833.
9. [9]
  (9) Boyarko, G. A.; Sung, C. J.; Schneider, S. J. Proc. Combust. Inst. 2005, 30, 2481.
10. [10]
  (10) Volchko, S. J.; Sung, C. J.; Huang, Y.; Schneider, S. J. J. Propul Power 2006, 22, 684.
11. [11]
  (11) Deutschmann, O.; Schmidt, R.; Behrendt, F.;Warnatz, J. Proc. Combust. Inst. 1996, 26, 1747.
12. [12]
  (12) Deutschmann, O.; Maier, L. I.; Riedel, U.; Stroemman, A. H.; Dibble, R.W. Catal. Today 2000, 59, 141.
13. [13]
  (13) Zerkle, D. K.; Allendorf, M. D.;Wolf, M.; Deutschmann, O. J. Catal. 2000, 196, 18.
14. [14]
  (14) Chatterjee, D.; Deutschmann, O.;Warnatz, J. Faraday Discuss. 2001, 119, 371.
15. [15]
  (15) Xu, C.; Koel, B. E.; Paffett, M. T. Langmuir 1994, 10, 166.
16. [16]
  (16) Roke, S.; Coquel, J. M.; Kleyn, A.W. Chem. Phys. Lett. 2000, 323, 201.
17. [17]
  (17) Weaver, J. F.; Krzyzowski, M. A.; Robert, J. M. J. Chem. Phys. 2000, 112, 396.
18. [18]
  (18) Pirngruber, G. D.; Seshan, K.; Lercher, J. A. J. Catal. 2000, 190, 338.
19. [19]
  (19) Jackson, S. D.; Kelly, G. J.;Webb, G. J. Catal. 1998, 176, 225.
20. [20]
  (20) Lee, I.; Zaera, F. J. Phys. Chem. B 2005, 109, 2745.
21. [21]
  (21) Duane, A. G.; Schmidt, L. D. Science 1996, 271, 1560.
22. [22]
  (22) Katano, S.; Kato, H. S.; Kawai, M.; Domen, K. J. Phys. Chem. C 2008, 112, 17219.
23. [23]
  (23) Marinov, N. M.; Pitz,W. J.;Westbrook, C. K.; Vincitore, A. M.; Castaldi, M. J.; Senkan, S. M.; Melius, C. F. Combust. Flame 1998, 114, 192.
24. [24]
  (24) Zhong, B. J.; Hong, Z. K. Heat and Power Engineering 2003, 18, 584. [钟北京, 洪泽恺. 热能动力工程, 2003, 18, 584.]
25. [25]
  (25) Schwiedernoch, R.; Tischer, S.; Deutschmann, O.;Warnatz, J. Proc. Combust. Inst. 2002, 29, 1005.
26. [26]
  (26) Bodke, A. S.; Bharadwaj, S. S.; Schmidt, L. D. J. Catal. 1998, 179, 138.
27. [27]
  (27) Bodke, A. S.; Henning, D.; Schmidt, L. D.; Bharadwaj, S. S.; Maj, J. J.; Siddall, J. J. Catal. 2000, 191, 62.
28. [28]
  (28) Beretta, A.; Piovesan, L.; Forzatti, P. J. Catal. 1999, 184, 455.
29. [29]
  (29) Norton, D. G.; Vlachos, D. G. Proc. Combust. Inst. 2005, 30, 2473.
30. [30]
  (30) Zhong, B. J.; Yang, Q. T.; Yang, F. Combust. Flame 2010, 157, 2005.
1. [1]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
2. [2]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
3. [3]
  Xue Liu , Lipeng Wang , Luling Li , Kai Wang , Wenju Liu , Biao Hu , Daofan Cao , Fenghao Jiang , Junguo Li , Ke Liu . Cu基和Pt基甲醇水蒸气重整制氢催化剂研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100049-. doi: 10.1016/j.actphy.2025.100049
4. [4]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
5. [5]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
6. [6]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
7. [7]
  Yulian Hu , Xin Zhou , Xiaojun Han . A Virtual Simulation Experiment on the Design and Property Analysis of CO₂ Reduction Photocatalyst. University Chemistry, 2025, 40(3): 30-35. doi: 10.12461/PKU.DXHX202403088
8. [8]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
9. [9]
  Shuang Yang , Qun Wang , Caiqin Miao , Ziqi Geng , Xinran Li , Yang Li , Xiaohong Wu . Ideological and Political Education Design for Research-Oriented Experimental Course of Highly Efficient Hydrogen Production from Water Electrolysis in Aerospace Perspective. University Chemistry, 2024, 39(11): 269-277. doi: 10.12461/PKU.DXHX202403044
10. [10]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . 碳基催化剂催化有机液体氢载体脱氢研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-. doi: 10.1016/j.actphy.2024.100044
11. [11]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
12. [12]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
13. [13]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
14. [14]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . 4-氨基-1H-咪唑-5-甲腈修饰供体-受体型氮化碳光催化剂的构建及其高效光催化产氢研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-. doi: 10.3866/PKU.WHXB202406026
15. [15]
  Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . 碳修饰的铜催化剂实现安培级电流电化学还原CO₂制C₂₊产物. Acta Physico-Chimica Sinica, 2025, 41(3): 2404012-. doi: 10.3866/PKU.WHXB202404012
16. [16]
  Yi Yang , Xin Zhou , Miaoli Gu , Bei Cheng , Zhen Wu , Jianjun Zhang . S型ZnO/CdIn₂S₄光催化剂制备H₂O₂偶联苄胺氧化的超快电子转移飞秒吸收光谱研究. Acta Physico-Chimica Sinica, 2025, 41(6): 100064-. doi: 10.1016/j.actphy.2025.100064
17. [17]
  Yang WANG , Xiaoqin ZHENG , Yang LIU , Kai ZHANG , Jiahui KOU , Linbing SUN . Mn single-atom catalysts based on confined space: Fabrication and the electrocatalytic oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2175-2185. doi: 10.11862/CJIC.20240165
18. [18]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
19. [19]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
20. [20]
  Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081

Get Citation

PDF

XML

Metrics

PDF Downloads(1127)
Abstract views(2679)
HTML views(36)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Heterogeneous Mechanism of C1-C4 on a Platinum Catalyst

Metrics

通讯作者: 陈斌, bchen63@163.com

Heterogeneous Mechanism of C₁-C₄ on a Platinum Catalyst