Citation: GUO Xing-Zhong, YAN Li-Qing, YANG Hui, LI Jian, LI Chao-Yu, CAI Xiao-Bo. Synthesis of Zirconia Aerogels by Ambient Pressure Drying with Propylene Oxide Addition[J]. Acta Physico-Chimica Sinica, ;2011, 27(10): 2478-2484. doi: 10.3866/PKU.WHXB20110925 shu

Synthesis of Zirconia Aerogels by Ambient Pressure Drying with Propylene Oxide Addition

1.
Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, P. R. China

Received Date: 25 May 2011
Available Online: 15 July 2011
Fund Project: 浙江省重点创新团队项目(2009R50010)资助 (2009R50010)

ZrO₂ aerogels were successfully synthesized by the sol-gel process and ambient pressure drying using ZrO(NO₃)₂·5H₂O as a precursor, 1,2-propylene oxide (PO) as a gelation agent, and formamide (FA) as a drying control chemical additive (DCCA). The prepared zirconia aerogel samples were characterized using differential thermal analysis (DTA), scanning electron microscopy (SEM), and nitrogen adsorption/desorption analysis. The results showed that the zirconia aerogels prepared by the propylene oxide addition method had a nanoscale porous network structure, as well as supercritical dried ones, with a low bulk density (202.08 kg·m^-3) and a high surface area (645.0 m²·g^-1). Propylene oxide can induce gelation through its nucleophilic property and its irreversible ring-opening reaction, and thus the sol-gel process and the state of gel can be controlled.
- Aerogel,
- Zirconia,
- Ambient pressure drying,
- Propylene oxide,
- Sol-gel
1. [1]
  (1) Hasegawa, T.; Hashimoto, O.; Nagae, T.; Sekimoto, M. Nucl. Instrum. Methods Phys. Res. Sect. A 1994, 342, 383.
2. [2]
  (2) Burchell, M.J.; Fairey, S.A.J.; Foster, N.J.; Cole, M. J. Planet. Space Sci. 2009, 57, 58.
3. [3]
  (3) Ackerman,W.C.; Vlachos, M.; Rouanet, S.; Fruendt, J. J. Non-Cryst. Solids 2001, 285, 264.
4. [4]
  (4) Hostler, S.R.; Abramson, A.R.; Gawryla, M.D.; Bandi, S.A.; Schiraldi, D.A. Int. J. Heat Mass Transfer 2009, 52, 665.
5. [5]
  (5) Maury, S.; Buisson, P.; Perrard, A.; Pierre, A.C. J. Mol. Catal. B- Enzym. 2004, 29, 133.
6. [6]
  (6) Smirnova, A.;Wender, T.; berman, D.; Hu, Y. L.; Aindow, M.; Rhine,W.; Sammes, N.M. Int. J. Hydrog. Energy 2009, I, 6.
7. [7]
  (7) Gerlach, R.; Krau?, O.; Fricke, J.; Eccardt, P. C.; Kroemer, N.; Ma ri, V. J. Non-Cryst. Solids 1992, 145, 227.
8. [8]
  (8) Krau?, O.; Gerlach, R.; Fricke, J. Ultrasonics 1994, 32, 217.
9. [9]
  (9) Li,W. C.; Probstie, H.; Fricke, J. J. Non-Cryst. Solids 2003, 325, 1.
10. [10]
  (10) Jang, K. J.; Kim K. J. J. Vac. Sci. Technol. A 1992, 10, 1152.
11. [11]
  (11) Bedilo, A. F.; Klabunde, K. J. Nanostruct. Mater. 1997, 8, 119.
12. [12]
  (12) Sun, Q.; Zhang, Y. L.; Deng, J. F.; Chen, S. Y.;Wu, D. Appl. Catal. A 1997, 152, L165.
13. [13]
  (13) Wu, Z. G.; Zhao, Y. X.; Xu, L. P.; Liu. D. S. J. Non-Cryst. Solids 2003, 330, 274.
14. [14]
  (14) Chervin, N. C.; Clapsaddle, J. B.; Chiu,W. H.; et al. Chem. Mater 2005, 17, 3345.
15. [15]
  (15) Sui, R. H.; Rizkalla, A. S.; Charpentier, P. A. Langmuir 2006, 22, 4390.
16. [16]
  (16) Stocker, C.; Baiker. A. J. Non-Cryst. Solids 1998, 223, 165.
17. [17]
  (17) Signoretto, M.; Oliva, L.; Pinna, F.; Strukul, G. J. Non-Cryst. Solids 2001, 290, 145.
18. [18]
  (18) Kalies, H.; Pinto, N.; Pajonk, G. M.; Bianchi, D. Appl. Catal. A 2000, 202, 197.
19. [19]
  (19) Xiang, H.W.; Zhong, B.; Peng, S. Y.;Wu, D.; Fan,W. H. J. Mol. Catal. (China) 1994, 8, 263.
20. [20]
  [相宏伟, 钟炳, 彭少逸, 吴东, 范文浩. 分子催化, 1994, 8, 263.]
21. [21]
  (20) Xiang, H.W.; Zhong, B.; Peng, S. Y.;Wu, D.; Fan,W. H. J. Fuel Chem. Technol. 1994, 22, 119.
22. [22]
  [相宏伟, 钟炳, 彭少逸, 吴东, 范文浩. 燃料化学学报, 1994, 22, 119.]
23. [23]
  (21) Xiang, H.W.; Zhong, B.; Peng, S. Y.;Wu, D.; Fan,W. H. J. Fuel Chem. Technol. 1994, 22, 125.
24. [24]
  [相宏伟, 钟炳, 彭少逸, 吴东, 范文浩. 燃料化学学报, 1994, 22, 125.]
25. [25]
  (22) Xiang, H.W.; Zhong, B.; Peng, S. Y.;Wu, D.; Fan,W. H. Acta Phys. -Chim. Sin. 1995, 11, 46.
26. [26]
  [相宏伟, 钟炳, 彭少逸, 吴东, 范文浩. 物理化学学报, 1995, 11, 46.]
27. [27]
  (23) Wu, Z. G.; Zhao, Y. X.; Liu, D. S. J. Funct. Mater. 2004, 35, 389.
28. [28]
  [武志刚, 赵永祥, 刘滇生. 功能材料, 2004, 35, 389.]
29. [29]
  (24) Bai, L. H.; Ma, H. X.; Gao, C. G.; Zhao, Y. X. J. Mol. Catal. (China) 2006, 20, 539.
30. [30]
  [白利红, 马宏勋, 高春光, 赵永祥. 分子催化, 2006, 20, 539.]
31. [31]
  (25) Haranath, D.; Rao V.;Wagh P. B. J J. Porous Mater. 1999, 6, 55.
32. [32]
  (26) Xu, Z. J.; Gan, L. H.; Pang, Y. C.; Chen, L.W. Acta Phys. -Chim. Sin. 2005, 21, 221.
33. [33]
  [徐子颉, 甘礼华, 庞颖聪, 陈龙武. 物理化学学报, 2005, 21, 221.]
34. [34]
  (27) Haereid, S.; Dahle, M.; Lima, S.; Einarsrud, M. A. J. Non-Cryst. Solids 1995, 186, 96.
35. [35]
  (28) Einarsrud, M. A.; Nilsen, E.; Rigacci, A.; Pajonk, G. M.; Buathier, S.; Valette, D.; Durant, M.; Chevalier, B.; Nitz, P.; Ehrburger-Dolle, F. J. Non-Cryst. Solids 2001, 285, 1.
36. [36]
  (29) Gash, A. E.; Tillotson, T. M.; Satcher Jr., J. H.; Hrubesh, L.W.; Simpson, R. L. J. Non-Cryst. Solids 2001, 285, 22.
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