Citation: GUO Zhi-Jun, CHEN Zong-Yuan, WU Wang-Suo, LIU Chun-Li, CHEN Tao, TIAN Wen-Yu, LI Chun. Adsorption of Se(IV) onto Beishan Granite[J]. Acta Physico-Chimica Sinica, ;2011, 27(09): 2222-2226. doi: 10.3866/PKU.WHXB20110918 shu

Adsorption of Se(IV) onto Beishan Granite

1.
1. Beijing National Laboratory for Molecular Sciences, Radiochemistry & Radiation Chemistry Key Laboratory for Fundamental Science, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China;
2. School of Nuclear Science and Technology, Lanzhou University, Lanzhou 730000, P. R. China

Received Date: 12 April 2011
Available Online: 12 July 2011
Fund Project: 国家自然科学基金(10775008, 11075006，91026010，20971061) (10775008, 11075006，91026010，20971061) 教育部博士点基金(20060001032) (20060001032) 国防科工委军工遗留专项基金(科工计[2007]840) (科工计[2007]840) 中央高校基本科研业务费专项资金和北京大学测试基金(第16-18 期)资助项目 (第16-18 期)

The adsorption of Se(IV) onto crushed Beishan granite (BS03, 600 m) was studied by a batch experimental method. The results showed that the distribution coefficient (K_d) remained almost constant in the pH range of 3-7 and decreased at pH>7. The adsorption of Se(IV) did not vary with ionic strength. The presence of Ca²⁺ (4.10×10^-3 mol·L^-1) and SO₄^2- (3.17×10^-3 mol·L^-1) had no effect on Se(IV) adsorption. Moreover, we found that the adsorption of Se(IV) (1.46×10^-5 mol·L^-1) and Eu(III) (3.33×10^-6 mol·L^-1) on Beishan granite had no effect on each other in the ternary adsorption system consisting of Se(IV)/Eu(III)/ granite. The adsorption of Se(IV) onto Beishan granite was quantitatively interpreted by considering the two surface complexation reactions of HseO₃^- to form ≡SHSeO₃ and ≡SSeO₃^- on the ≡SOH general adsorption sites.
- Beishan granite,
- Adsorption,
- Selenium(IV),
- Surface complexation model
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