Citation: YU Yan-Jie, ZHANG Shuan-Qin, KONG Ling-Dong, LIN Li, CHENG Tian-Tao, CHEN Jian-Min. Effects of Nitrates on the Heterogeneous Reaction of Carbonyl Sulfide on Model Aerosols[J]. Acta Physico-Chimica Sinica, ;2011, 27(10): 2275-2281. doi: 10.3866/PKU.WHXB20110912 shu

Effects of Nitrates on the Heterogeneous Reaction of Carbonyl Sulfide on Model Aerosols

1.
Department of Environmental Science & Engineering, Fudan University, Shanghai 200433, P. R. China

Received Date: 15 May 2011
Available Online: 7 July 2011
Fund Project: 国家自然科学基金(40775079, 40875073, 40728006, 40533017) (40775079, 40875073, 40728006, 40533017)

The heterogeneous reaction of carbonyl sulfide (COS) on hematite particles in the presence of nitrate was investigated by in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS). For sodium nitrate-containing samples, the hematite sample containing NaNO₃ with mass fraction of 4% gave the highest reaction rate, which was about 5 times higher than that of hematite. For the particles containing nitrate at the same mass fraction (24%) the reactivity in descending order was α-Fe₂O₃/KNO₃, α-Fe₂O₃/NaNO₃, α-Fe₂O₃/NH₄NO₃ and α-Fe₂O₃. No uptake of COS was observed for the pure NaNO₃, KNO₃ and NH₄NO₃ samples. These results indicate that the added nitrate increased the COS conversion ability of α-Fe₂O₃ particles.
- Carbonyl sulfide,
- Aerosol,
- Nitrate,
- Heterogeneous reaction
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