Citation: TU Xiao-Hua, CHU You-Qun, MA Chun-An. Electrochemical Behavior of Nitroaromatics on Pt Microelectrode in an Aprotic Medium[J]. Acta Physico-Chimica Sinica, ;2011, 27(09): 2148-2152. doi: 10.3866/PKU.WHXB20110909 shu

Electrochemical Behavior of Nitroaromatics on Pt Microelectrode in an Aprotic Medium

TU Xiao-Hua ^1,2,3 ,
CHU You-Qun ² ,
MA Chun-An ^2,

1.
1. College of Biological and Chemical Engineering, Jiaxing University, Jiaxing 314001, Zhejiang Province, P. R. China;
2. State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Department of Applied Chemistry, Zhejiang University of Technology, Hangzhou, 310032, P. R. China;
3. Key Laboratory of Clean Chemical Process of Jiaxing, Jiaxing 314001, Zhejiang Province, P. R. China

Received Date: 22 March 2011
Available Online: 7 July 2011
Fund Project: 国家基础研究重大项目前期研究专项(2003CCA01300) (2003CCA01300)国家自然科学基金(20376074)资助项目 (20376074)

N,N-dimethylformamide (DMF) and tetrabutyl ammonium perchlorate (TBAP) were used as a solvent and a supporting electrolyte, respectively. The working electrode was a platinum microelectrode, the auxiliary electrode was a large area platinum wire and the reference electrode was a saturated calomel electrode. The electrochemical behavior of nitroaromatics (NA) was studied by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The effects of scan rate, numbers of benzene rings and nitro groups on the electrochemical reduction of NA were investigated systematically. The results showed that the reaction of NA on the Pt microelectrode was a quasi-reversible process controlled by the diffusion of NA. We found that NA was more electrochemically reducible when it contained more nitro groups and the reduction peak current of the nitro group decreased in the presence of more benzene rings.
- Nitroaromatics,
- Microelectrode,
- Aprotic medium,
- Cyclic voltammetry,
- Electrochemical impedance spectroscopy
1. [1]
  (1) Jiang, J. H.; Chen, L.;Wu, B. L.; Zhai, R. S. Acta Phys. -Chim. Sin. 1998, 14 (8), 704. [江军华, 陈岚, 吴秉亮, 翟润生. 物理化学学报, 1998, 14 (8), 704.]
2. [2]
  (2) Ma, C. A.; Ge, X. F.; Zhu, Y. H.;Wang, L. B. J. Chem. Eng. Chin. Univ. 2006, 20, 728. [马淳安, 葛小芳, 朱英红, 王连邦. 高校化学工程学报, 2006, 20, 728.]
3. [3]
  (3) Ma, C. A.; Tang, J. Y.; Li, G. H.; Sheng, J. F. Acta Chin. Sin. 2006, 64 (20), 2123. [马淳安, 汤俊艳, 李国华, 盛江峰. 化学学报, 2006, 64 (20), 2123.]
4. [4]
  (4) Ma, C. A.; Huang, Y.; Tong, S. P.; Zhang,W. M. Acta Phys. -Chim. Sin. 2005, 21 (7), 721. [马淳安, 黄烨, 童少平, 张维民. 物理化学学报, 2005, 21 (7), 721.]
5. [5]
  (5) Ma, C. A.; Huang, X. Y.; Chu, Y. Q.; Tu, X. H.;Wang, S. Q. J. Zhejiang Univ. Tech. 2007, 35, 591. [马淳安, 黄祥岳, 褚有群, 屠晓华, 王素琴. 浙江工业大学学报, 2007, 35, 591.]
6. [6]
  (6) Ma, C. A.; Chu, Y. Q.; Zhu, Y. H.; Xu, Z. H. Electrochemistry 2004, 10 (3), 298. [马淳安, 褚有群, 朱英红, 徐志花. 电化学, 2004, 10 (3), 298.]
7. [7]
  (7) Teng,W. J.; Mao, X. B.; Ma, C. A. J. Chem. Ind. Eng. 2010, 61 (5), 1313. [滕文娟, 毛信表, 马淳安. 化工学报,2010, 61 (5), 1313.]
8. [8]
  (8) Ma, C. A.; Chu, Y. Q.; Tong, S. P.; Mao, X. B.; Li, M. C.; Zhu, Y. H. J. J. Chem. Ind. Eng. 2004, 55 (12), 1971. [马淳安, 褚有群, 童少平, 毛信表, 李美超, 朱英红. 化工学报, 2004, 55 (12), 1971.]
9. [9]
  (9) Li, M. C.;Wu, H. F.; Hu, J. Q.; Ma, C. A. Acta Phys. -Chim. Sin. 2008, 24 (10), 1937. [李美超, 吴海峰, 胡佳琦, 马淳安. 物理化学学报, 2008, 24 (10), 1937.]
10. [10]
  (10) Zhang, X.; Liu, Z.; Dong, Y. M.; Zhou, C. L. J. Univ. Jinan (Sci & Tec.), 2009, 23 (4), 398. [张鑫, 刘震, 董艳敏, 周长利. 济南大学学报(自然科学版), 2009, 23 (4), 398.]
11. [11]
  (11) Ma, Y. J.; Fu, Z. Z.; Ren, X. N.; Song, Q. Y.; Zhou, X. Y. Chin. J. Anal. Chem. 2008, 36 (2), 241. [马永均, 付周周, 任小娜, 宋青云, 周秀英. 分析化学, 2008, 36 (2), 241.]
12. [12]
  (12) Charoenkwan, K.; Dennis, H. E. J. Electroanal. Chem. 2004, 565, 29.
13. [13]
  (13) Nú?ez-Vergara, L. J.; Bonta, M.; Navarrete-Encina, P. A.; Squella, J. A. Electrochimica Acta 2001, 46, 4289.
14. [14]
  (14) Bontá, M.; Chauviere, G.; Périé, J.; Nú?ez-Vergara, L. J.; Squella, J. A. Electrochimica Acta 2002, 47, 4045.
15. [15]
  (15) Núñez-Vergara, L. J.; Ortiz, M. E.; Bollo, S.; Squella, J. A. Chem. Biol. Interact. 1997, 106, 1
16. [16]
  (16) ncalves, A.; Mathieu, C.; Herlem, M.; Etcheberry, A. J. Electroanal. Chem. 1999, 477, 140.
17. [17]
  (17) Oldham, K. B.; Cardwell, T. J.; Santos, J. H.; Bond, A. M. J. Electroanal. Chem. 1997, 430, 25.
18. [18]
  (18) Oldham, K. B.; Cardwell, T. J.; Santos, J. H.; Bond, A. M. J. Electroanal. Chem. 1997, 430, 39.
19. [19]
  (19) Bento, M. F.; Thouin, L.; Amatore, C. J. Electroanal. Chem. 1998, 446, 91.
20. [20]
  (20) Privat, C.; Trevin, S.; Bedioui, F.; Devynck, J. J. Electroanal. Chem. 1997, 436, 261.
21. [21]
  (21) Evans, D. H.; Geraldo, M. D.; Montenegro, M. I.; Pletcher, D.; Slevin, L. J. Electroanal. Chem. 1997, 439, 115.
1. [1]
  Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081
2. [2]
  Hao Wu , Zhen Liu , Dachang Bai . ¹H NMR Spectrum of Amide Compounds. University Chemistry, 2024, 39(3): 231-238. doi: 10.3866/PKU.DXHX202309020
3. [3]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
4. [4]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
5. [5]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
6. [6]
  Chi Li , Jichao Wan , Qiyu Long , Hui Lv , Ying Xiong . N-Heterocyclic Carbene (NHC)-Catalyzed Amidation of Aldehydes with Nitroso Compounds. University Chemistry, 2024, 39(5): 388-395. doi: 10.3866/PKU.DXHX202312016
7. [7]
  Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096
8. [8]
  Zhuoming Liang , Ming Chen , Zhiwen Zheng , Kai Chen . Multidimensional Studies on Ketone-Enol Tautomerism of 1,3-Diketones By ¹H NMR. University Chemistry, 2024, 39(7): 361-367. doi: 10.3866/PKU.DXHX202311029
9. [9]
  Aidang Lu , Yunting Liu , Yanjun Jiang . Comprehensive Organic Chemistry Experiment: Synthesis and Characterization of Triazolopyrimidine Compounds. University Chemistry, 2024, 39(8): 241-246. doi: 10.3866/PKU.DXHX202401029
10. [10]
  Hongbo Zhang , Yihong Tang , Suxia Zhang , Yuanting Li . Electrochemical Monitoring of Photocatalytic Degradation of Phenol Pollutants: A Recommended Comprehensive Analytical Chemistry Experiment. University Chemistry, 2024, 39(6): 326-333. doi: 10.3866/PKU.DXHX202310013
11. [11]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
12. [12]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
13. [13]
  Yihao Zhao , Jitian Rao , Jie Han . Synthesis and Photochromic Properties of 3,3-Diphenyl-3H-Naphthopyran: Design and Teaching Practice of a Comprehensive Organic Experiment. University Chemistry, 2024, 39(10): 149-155. doi: 10.3866/PKU.DXHX202402050
14. [14]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
15. [15]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
16. [16]
  Yongming Zhu , Huili Hu , Yuanchun Yu , Xudong Li , Peng Gao . Construction and Practice on New Form Stereoscopic Textbook of Electrochemistry for Energy Storage Science and Engineering: Taking Basic Course of Electrochemistry as an Example. University Chemistry, 2024, 39(8): 44-47. doi: 10.3866/PKU.DXHX202312086
17. [17]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
18. [18]
  Jinyao Du , Xingchao Zang , Ningning Xu , Yongjun Liu , Weisi Guo . Electrochemical Thiocyanation of 4-Bromoethylbenzene. University Chemistry, 2024, 39(6): 312-317. doi: 10.3866/PKU.DXHX202310039
19. [19]
  Yong Zhou , Jia Guo , Yun Xiong , Luying He , Hui Li . Comprehensive Teaching Experiment on Electrochemical Corrosion in Galvanic Cell for Chemical Safety and Environmental Protection Course. University Chemistry, 2024, 39(7): 330-336. doi: 10.3866/PKU.DXHX202310109
20. [20]
  Zhengli Hu , Jia Wang , Yi-Lun Ying , Shaochuang Liu , Hui Ma , Wenwei Zhang , Jianrong Zhang , Yi-Tao Long . Exploration of Ideological and Political Elements in the Development History of Nanopore Electrochemistry. University Chemistry, 2024, 39(8): 344-350. doi: 10.3866/PKU.DXHX202401072

Get Citation

PDF

XML

Metrics

PDF Downloads(1044)
Abstract views(2402)
HTML views(7)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142