Citation: ZHENG Tao, LI Pan, XIAO Sheng-Chun, WANG Dan, Lü Jing-Wen, MEN Zhi-Wei. Luminance Properties and Judd-Ofelt Theory Study of Yb³⁺ Sensitization Wideband Er³⁺ Doped Fluorphosphate Glass[J]. Acta Physico-Chimica Sinica, ;2011, 27(09): 2095-2100. doi: 10.3866/PKU.WHXB20110906 shu

Luminance Properties and Judd-Ofelt Theory Study of Yb³⁺ Sensitization Wideband Er³⁺ Doped Fluorphosphate Glass

1.
1. Department of Material Science and Engineering, Changchun University of Science and Technology, Changchun 130022, P. R. China;
2. Department of Physics, Jilin University, Changchun 130012, P. R. China

Received Date: 3 March 2011
Available Online: 5 July 2011
Fund Project: 国家自然科学基金(11075026)资助项目 (11075026)

A new Er³⁺/Yb³⁺-codoped fluorphosphate glass was prepared by high temperature melting. Its density, absorption spectra, and fluorescence spectra were measured and investigated. The effect of Er³⁺ and Yb³⁺ concentrations on the spectroscopic properties of the glass sample are discussed. A Judd-Ofelt theory analysis on the absorption spectra was performed. The oscillator strengths were Ω_t (t=2, 4, 6 ), Ω₂= 4.36×10^-20 cm², Ω₄=1.35×10^-20 cm², and Ω₆=0.79×10^-20 cm². The lifetime (τ_m) of the ⁴I_13/2 level for the Er³⁺ ions was 8.26 ms and the full width at half maximum (FWHM) of the main emission peak was 68 nm at 1.53 μm. The large stimulated emission cross-section (σ_e=8.5×10^-21 cm²) of the Er³⁺ was calculated using McCumber theory. The spectroscopic properties of the Er³⁺ ion were compared among different glasses. The FWHM and σ_e of Er³⁺/Yb³⁺-codoped fluorphosphate glass were found to be larger than those of other glass hosts, which indicates that this glass may be a potentially useful candidate material host for a high-gain erbium-doped fiber amplifier.
- Fluorphosphate glass,
- McCumber theory,
- Judd-Ofelt theory,
- Fluorescence spectrum,
- Fluorescence lifetime
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沈阳化工大学材料科学与工程学院沈阳 110142

Luminance Properties and Judd-Ofelt Theory Study of Yb3+ Sensitization Wideband Er3+ Doped Fluorphosphate Glass

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通讯作者: 陈斌, bchen63@163.com

Luminance Properties and Judd-Ofelt Theory Study of Yb³⁺ Sensitization Wideband Er³⁺ Doped Fluorphosphate Glass