Citation: ZHAO Hao-Chuan, SONG Yang, GUO Xiao-Dong, ZHONG Ben-He, DONG Jing, LIU Heng. Effect of Precursor Ingredient Temperature on the Performance of LiFePO₄ by Hydrothermal Method[J]. Acta Physico-Chimica Sinica, ;2011, 27(10): 2347-2352. doi: 10.3866/PKU.WHXB20110905 shu

Effect of Precursor Ingredient Temperature on the Performance of LiFePO₄ by Hydrothermal Method

1.
1. College of Chemical Engineering, Sichuan University, Chengdu 610065, P. R. China;
2. College of Materials Science and Engineering, Sichuan University, Chengdu 610064, P. R. China

Received Date: 25 April 2011
Available Online: 4 July 2011
Fund Project: 国家科技支撑计划(2007BAQ01055)资助项目 (2007BAQ01055)

We investigated LiFePO₄ particles that were prepared by a hydrothermal reaction at different ingredient temperatures. The precursors and final LiFePO₄ products were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), cyclic voltammetry (CV), and elemental analysis. The results show that ingredient temperature had a significant effect on the color and characteristics of the LiFePO₄ precursors. High purity Li₃PO₄ was obtained and the formation of Fe(OH)₃ in the precursors was inhibited by controlling the ingredient temperature carefully. In addition well-crystalline and free Fe³⁺ LiFePO₄ samples were synthesized, which greatly increased the discharge capacity of the LiFePO₄ cathode materials. At an ingredient temperature of 30 °C the discharge specific capacity of the as-prepared sample was found to be 156 mAh·g^-1 at 0.1C rate, 151 mAh·g^-1 at 0.5C rate and it remained 127 mAh·g^-1 even at a rate of 10C while the cycling retention rate was 99% after 20 cycles.
- Lithium ion battery,
- Cathode,
- Hydrothermal method,
- LiFePO₄,
- Temperature
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沈阳化工大学材料科学与工程学院沈阳 110142

Effect of Precursor Ingredient Temperature on the Performance of LiFePO4 by Hydrothermal Method

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Effect of Precursor Ingredient Temperature on the Performance of LiFePO₄ by Hydrothermal Method