Citation: YAN Hui, ZHANG Huan, ZHANG Ding, ZHU Zhi, QI Lu. Hydrothermal Synthesis of Spherical Li₄Ti₅O₁₂ as Anode Material for High Power Lithium-Ion Secondary Battery[J]. Acta Physico-Chimica Sinica, ;2011, 27(09): 2118-2122. doi: 10.3866/PKU.WHXB20110841 shu

Hydrothermal Synthesis of Spherical Li₄Ti₅O₁₂ as Anode Material for High Power Lithium-Ion Secondary Battery

1.
Beijing National Laboratory for Molecular Sciences, New Energy Materials and Technology Laboratory, Department of Applied Chemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Received Date: 28 March 2011
Available Online: 4 July 2011
Fund Project: 国家高技术研究发展计划项目(863) (2008AA11A102)资助 (863) (2008AA11A102)

Pure spinel-type lithium titanate, Li₄Ti₅O₁₂, was successfully fabricated by a facile hydrothermal route using anatase TiO₂ and LiOH solution as raw materials. The obtained samples were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), and laser particle size distribution (PSD) analysis. The results showed that a spherical well-crystallized Li₄Ti₅O₁₂ oxide was obtained at a calcination temperature of 800 °C. The optimal Li₄Ti₅O₁₂ also has excellent electrochemical performance, which reached 162 mAh·g^-1 at a current density of 35 mA· g^-1 and a od rate capability with a capacity reached 124 mAh·g^-1 even at a current density of 720 mA·g^-1.
- Hydrothermal synthesis,
- Spherical,
- Li₄Ti₅O₁₂,
- Electrochemical performance,
- Lithium-ion secondary battery
1. [1]
  (1) Ohzuku, T.; Ueda, A.; Yamamoto, N. J. Electrochem. Soc. 1995, 142, 1431.
2. [2]
  (2) Abraham, K. M.; Pasquariello, D. M.;Willstaedt, E. B. J. Electrochem. Soc. 1990, 137, 743.
3. [3]
  (3) Courtney, I. A.; Dahn, J. R. J. Electrochem. Soc. 1997, 144, 2045.
4. [4]
  (4) Poizot, P.; Laruelle, S.; Grugeon, S.; Dupont, L.; Tarascon, J. M. J. Power Sources 2001, 97-98, 235.
5. [5]
  (5) Poizot, P.; Laruelle, S.; Grugeon, S.; Dupont, L.; Tarascon, J. M. Nature 2000, 407, 496.
6. [6]
  (6) Wang, G. J.; Gao, J.; Fu, L. J.; Zhao, N. H.;Wu, Y. P.; Takamura, T. J. Power Sources 2007, 174, 1109.
7. [7]
  (7) Yao, J.W.;Wu, F. J. Funct. Mater. 2007, 38 (8), 1294. [姚经文, 吴锋. 功能材料, 2007, 38 (8), 1294.]
8. [8]
  (8) Pasquier, A. D.; Huang, C. C.; Spitler, T. J. Power Sources 2009, 186, 508.
9. [9]
  (9) Venkateswarlu, M.; Chen, C. H.; Do, J. S.; Lin, C.W.; Chou, T. C.; Hwang, B. J. J. Power Sources 2005, 146, 204.
10. [10]
  (10) Wang, D.; Ding, N.; Song, X. H.; Chen, C. H. J. Mater. Sci. 2009, 44, 198.
11. [11]
  (11) Yang, J.W.; Zhong, H.; Zhong, H. Y.; Li, J.; Dai, Y. Y. J. Cent. South Univ. 2005, 36 (1), 55. [杨建文, 钟晖, 钟海云, 李荐, 戴艳阳. 中南大学学报, 2005, 36 (1), 55.]
12. [12]
  (12) Zaghib, K.; Simoneau, M.; Armand, M.; Gauthier, M. J. Power Sources 1999, 81-82, 300.
13. [13]
  (13) Guerfia, A.; Sevignya, S.; Lagacea, M.; Hovington, P.; Kinoshita, K.; Zaghib, K. J. Power Sources 2003, 119-121, 88.
14. [14]
  (14) Bach, S.; Pereira-Ramos, J. P.; Baffier, N. J. Power Sources 1999, 81-82, 273.
15. [15]
  (15) Jiang, C. H.; Ichihara, M.; Honma, I.; Zhou, H. S. Electrochim. Acta 2007, 52, 6470.
16. [16]
  (16) Li, J. R.; Tang, Z. L.; Zhang, Z. T. Electrochem. Commun. 2005, 7, 894.
17. [17]
  (17) Li, Y.; Zhao, H. L.; Tian, Z. H.; Qiu,W. H.; Li, X. J. Alloy. Compd. 2008, 455, 471.
18. [18]
  (18) Yu, Y.; Shui, J. L.; Chen, C. H. Solid State Commun. 2005, 135, 485.
19. [19]
  (19) Nakahara, K.; Nakajima, R.; Matsushima, T.; Majima, H. J. Power Sources 2003, 117, 131.
20. [20]
  (20) Hong, K. P.; Young, T. M.; Do, K. K.; Chong, H. K. J. Am. Ceram. Soc. 1996, 79, 2727.
21. [21]
  (21) Allen, G. C.; Paul, M. Appl. Spectrosc. 1995, 49, 451.
22. [22]
  (22) Gao, L.; Chen, J. Y.; Huang, J. H.; Yan, D. S. J. Inorg. Mater. 1995, 10 (4), 421. [高濂, 陈锦元, 黄军华, 严东生. 无机材料学报, 1995, 10 (4), 421.]
23. [23]
  (23) Lai, C.; Dou, Y. Y. ; Li, X.; Gao, X. P. J. Power Sources 2010, 195, 3676.
24. [24]
  (24) Rahman, M. M.;Wang, J. Z.; Hassan, M. F.; Chou, S. L.; Wexler, D.; Liu, H. K. J. Power Sources 2010, 195, 4297.
25. [25]
  (25) Yao, X. L.; Xie, S.; Chen, C. H.;Wang, Q. S.; Sun, J. H.; Li, Y. L.; Lu, S. X. Electrochim. Acta 2005, 50, 4076.
1. [1]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
2. [2]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
3. [3]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050
4. [4]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
5. [5]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
6. [6]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
7. [7]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
8. [8]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
9. [9]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
10. [10]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
11. [11]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
12. [12]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
13. [13]
  Yong Zhou , Jia Guo , Yun Xiong , Luying He , Hui Li . Comprehensive Teaching Experiment on Electrochemical Corrosion in Galvanic Cell for Chemical Safety and Environmental Protection Course. University Chemistry, 2024, 39(7): 330-336. doi: 10.3866/PKU.DXHX202310109
14. [14]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
15. [15]
  Li Jiang , Changzheng Chen , Yang Su , Hao Song , Yanmao Dong , Yan Yuan , Li Li . Electrochemical Synthesis of Polyaniline and Its Anticorrosive Application: Improvement and Innovative Design of the “Chemical Synthesis of Polyaniline” Experiment. University Chemistry, 2024, 39(3): 336-344. doi: 10.3866/PKU.DXHX202309002
16. [16]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
17. [17]
  Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096
18. [18]
  Bingliang Li , Yuying Han , Dianyang Li , Dandan Liu , Wenbin Shang . One-Step Synthesis of Benorilate Guided by Green Chemistry Principles and in vivo Dynamic Evaluation. University Chemistry, 2024, 39(6): 342-349. doi: 10.3866/PKU.DXHX202311070
19. [19]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
20. [20]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009

Get Citation

PDF

XML

Metrics

PDF Downloads(1985)
Abstract views(2815)
HTML views(19)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Hydrothermal Synthesis of Spherical Li4Ti5O12 as Anode Material for High Power Lithium-Ion Secondary Battery

Metrics

通讯作者: 陈斌, bchen63@163.com

Hydrothermal Synthesis of Spherical Li₄Ti₅O₁₂ as Anode Material for High Power Lithium-Ion Secondary Battery