Citation: YAN Hui, ZHANG Huan, ZHANG Ding, ZHU Zhi, QI Lu. Hydrothermal Synthesis of Spherical Li₄Ti₅O₁₂ as Anode Material for High Power Lithium-Ion Secondary Battery[J]. Acta Physico-Chimica Sinica, ;2011, 27(09): 2118-2122. doi: 10.3866/PKU.WHXB20110841 shu

Hydrothermal Synthesis of Spherical Li₄Ti₅O₁₂ as Anode Material for High Power Lithium-Ion Secondary Battery

1.
Beijing National Laboratory for Molecular Sciences, New Energy Materials and Technology Laboratory, Department of Applied Chemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Received Date: 28 March 2011
Available Online: 4 July 2011
Fund Project: 国家高技术研究发展计划项目(863) (2008AA11A102)资助 (863) (2008AA11A102)

Pure spinel-type lithium titanate, Li₄Ti₅O₁₂, was successfully fabricated by a facile hydrothermal route using anatase TiO₂ and LiOH solution as raw materials. The obtained samples were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), and laser particle size distribution (PSD) analysis. The results showed that a spherical well-crystallized Li₄Ti₅O₁₂ oxide was obtained at a calcination temperature of 800 °C. The optimal Li₄Ti₅O₁₂ also has excellent electrochemical performance, which reached 162 mAh·g^-1 at a current density of 35 mA· g^-1 and a od rate capability with a capacity reached 124 mAh·g^-1 even at a current density of 720 mA·g^-1.
- Hydrothermal synthesis,
- Spherical,
- Li₄Ti₅O₁₂,
- Electrochemical performance,
- Lithium-ion secondary battery
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Hydrothermal Synthesis of Spherical Li₄Ti₅O₁₂ as Anode Material for High Power Lithium-Ion Secondary Battery