Citation: XU Xiao-Ling, LI Chun-Yi, SHAN Hong-Hong. Novel Modified Magnesium-Aluminate Spinels as Potential FCC Matrix Components[J]. Acta Physico-Chimica Sinica, ;2011, 27(08): 1947-1955. doi: 10.3866/PKU.WHXB20110837 shu

Novel Modified Magnesium-Aluminate Spinels as Potential FCC Matrix Components

1.
State Key Laboratory of Heavy Oil Processing, College of Chemistry and Chemical Engineering, China University of Petroleum (East China), Qingdao 266555, Shandong Province, P. R. China

Received Date: 30 March 2011
Available Online: 28 June 2011
Fund Project:

Modified magnesium-aluminate spinels (MgAl₂O₄) were prepared by recrystallizing a mixture of MgAl₂O₄ and zeolite Y nanoclusters in acidic medium to improve the acidity of MgAl₂O₄, which was commonly used as a sulfur transfer agent in fluid catalytic cracking (FCC) units. The acidity and basicity of these samples can be tuned by varying the pH value of the synthesis system. From the characterization and catalytic cracking tests the introduction of zeolitic building units into the spinels contributed to the increased microporosity, acidity, and hydrothermal stability. The catalytic results indicate that the activities and the product selectivities of the modified spinels for vacuum gas oil (V ) cracking improved remarkably compared to the parent spinel. These samples exhibited even better performance than Kaolin clay for V cracking while retaining a part of the basic sites for oxidative SO₂ uptake. Moreover, the FCC catalyst prepared using the modified spinel as a partial matrix, after equilibration, also gave superior catalytic behavior compared to a reference FCC catalyst with Kaolin clay as the main matrix.
- Magnesium-aluminate spinel,
- Zeolite Y nanocluster,
- Sulfur transfer,
- Catalytic cracking,
- Hydrothermal stability
1. [1]
  
  (1) Pǎcurariu, C.; Lazǎu, I.; Ecsedi, Z.; Lazǎu, R.; Barvinschi, P.; Mǎrginean, G. J. Eur. Ceram. Soc. 2007, 27, 707.
2. [2]
  (2) Prabhakaran, K.; Patil, D. S.; Dayal, R.; khale, N. M.; Sharma, S. C. Mater. Res. Bull. 2009, 44, 613.
3. [3]
  (3) Guo, J.; Lou, H.; Zhao, H.;Wang, X.; Zheng, X. Mater. Lett. 2004, 58, 1920.
4. [4]
  (4) Iqbal, M. J.; Farooq, S. Mater. Sci. Eng. B 2007, 136, 140.
5. [5]
  (5) Bhattacharyya, A. A.;Woltermann, G. M.; Yoo, J. S.; Karch, J. A.; Cormier,W. E. Ind. Eng. Chem. Res. 1988, 27, 1356.
6. [6]
  (6) Yoo, J. S.; Bhattacharyya, A. A.; Radlowski, C. A. Ind. Eng. Chem. Res. 1991, 30, 1444.
7. [7]
  (7) Yoo, J. S.; Bhattacharyya, A. A.; Radlowski, C. A. Ind. Eng. Chem. Res. 1992, 31, 1252.
8. [8]
  (8) Wang, J.; Li, C. Mater. Lett. 1997, 32, 223.
9. [9]
  (9) Wang, J. A.; Chen, L. F.; Limas-Ballesteros, R.; Montoya, A.; Dominguez, J. M. J. Mol. Catal. A- Chem. 2003, 194, 181.
10. [10]
  (10) Wang, J.; Li, C. Appl. Surf. Sci. 2000, 161, 406.
11. [11]
  (11) Wang, J.; Chen, L.; Li, C. J. Mol. Catal. A- Chem. 1999, 139, 315.
12. [12]
  (12) Corma, A.; Palomares, A. E.; Rey, F. Appl. Catal. B 1994, 4, 29.
13. [13]
  (13) Corma, A.; Palomares, A. E.; Rey, F.; Márques, F. J. Catal. 1997, 170, 140.
14. [14]
  (14) Cantú, M.; López-Salinas, E.; Valente, J. S.; Montiel, R. Environ. Sci. Technol. 2005, 39, 9715.
15. [15]
  (15) Palomares, A. E.; Lópes-Nieto, J. M.; Lázaro, F. J.; Lópes, A.; Corma, A. Appl. Catal. B 1999, 20, 257.
16. [16]
  (16) Pereira, H. B.; Polato, C. M. S.; Monteiro, J. L. F.; Henriques, C. A. Catal. Today 2010, 149, 309.
17. [17]
  (17) Busca, G. Catal. Today 1998, 41, 191.
18. [18]
  (18) Shen, J.; Kobe, J. M.; Chen, Y.; Dumesic, J. A. Langmuir 1994, 10, 3902.
19. [19]
  (19) Iglesla, E.; Barton, D. G.; Biscardi, J. A.; Gines, M. J. L.; Soled, S. L. Catal. Today 1997, 38, 339.
20. [20]
  (20) Wang, L.; Guo, H.; Qi,W.; Su, S.; Deng, X.; Liu, J.; Liu, S. Sulfur transfer additive for catalytic cracking of hydrocarbons and a catalytic cracking process of hydrocarbons using the same. US Patent 20030121824A1, 2003-01-21.
21. [21]
  (21) de Morais, B. A. H.; Ramos, F. S. O.; Pinheiro, T. B.; Lima, C. L.; de Sousa, F. F.; Barros, E. B. D.; Filho, J. M.; de Oliveira, A. S.; de Souza, J. R.; Valentini, A.; Oliveira, A. C. Appl. Catal. AGen. 2010, 382, 148.
22. [22]
  (22) Valente, J. S.; Hernandez-Cortez, J.; Cantu, M. S.; Ferrat, G.; López-Salinas, E. Catal. Today 2010, 150, 340.
23. [23]
  (23) Do, T. O.; Nossov, A.; Springuel-Huet, M. A.; Schneider, C.; Bretherton, J. L.; Fyfe, C. A.; Kaliaguine, S. J. Am. Chem. Soc. 2004, 126, 14324.
24. [24]
  (24) Do, T. O.; Kaliaguine, S. J. Am. Chem. Soc. 2003, 125, 618.
25. [25]
  (25) Do, T. O.; Kaliaguine, S. Angew. Chem. 2002, 114, 1078.
26. [26]
  (26) Liu, Y.; Zhang,W. Z.; Pinnavaia, T. J. J. Am. Chem. Soc. 2000, 122, 8791.
27. [27]
  (27) Tan, Q.; Liu, H.; Song, T.; Shi, G.; Shen, B.; Bao, X. AIChE J. 2008, 54, 1850.
28. [28]
  (28) Tan, Q.; Bao, X.; Song, T.; Fan, Y.; Shi, G.; Shen, B.; Liu, C.; Gao, X. J. Catal. 2007, 251, 69.
29. [29]
  (29) Xu, X.; Ran, X.; Cui, Q.; Li, C.; Shan, H. Energy Fuels 2010, 24, 3754.
30. [30]
  (30) Olhero, S. M.; Ganesh, I.; Torres, P. M. C.; Ferreira. J. M. F. Langmuir 2008, 24, 9525.
31. [31]
  (31) Ju, Y.; Shen, Z.; Zhao, J.; Zhao, J.;Wang, X. Acta Phys. -Chim. Sin. 2006, 22, 28. [鞠雅娜, 沈志虹, 赵佳, 赵俊桥, 王秀林. 物理化学学报, 2006, 22, 28.]
32. [32]
  (32) Tonetto, G. M.; Ferreira, M. L.; Atias, J. A.; de Lasa, H. I. AIChE J. 2006, 52, 754.
33. [33]
  (33) Jiang, G.; Zhang, L.; Zhao, Z.; Zhou, X.; Duan, A.; Xu, C.; Gao, J. Appl. Catal. A- Gen. 2008, 340, 176.
34. [34]
  (34) Lercher, J. A.; Jndling, C. G.; Eder-Mirth, G. Catal. Today 1996, 27, 353.
35. [35]
  (35) Song, H.; Jiang,W.; Da, Z. Acta Petrolei Sin. (Pet. Process. Sect.) 2003, 19, 14. [宋海涛, 蒋文斌, 达志坚. 石油学报(石油加工), 2003, 19, 14.]
36. [36]
  (36) Rossi, P. F.; Busca, G.; Lorenzelli, V.; Saur, O.; Lavalley, J. C. Langmuir 1987, 3, 52.
37. [37]
  (37) Rossi, P. F.; Busca, G.; Lorenzelli, V.;Waqif, M.; Saw, O.; Lavalley, J. C. Langmuir 1991, 7, 2677.
38. [38]
  (38) Lavalley, J. C. Catal. Today 1996, 27, 377.
39. [39]
  (39) Wallenstein, D.; Harding, R.H. Appl. Catal. A- Gen. 2001, 214, 11.
40. [40]
  (40) Wang, G.; Xu, C.; Gao, J. Fuel Process. Technol. 2008, 89, 864.
41. [41]
  (41) Ren, Y.; Shi, L. China Inorg. Chem. Ind. 2008, 40, 17. [任彦瑾, 施力. 无机盐工业, 2008, 40, 17.]
1. [1]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
2. [2]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
3. [3]
  Shitao Fu , Jianming Zhang , Cancan Cao , Zhihui Wang , Chaoran Qin , Jian Zhang , Hui Xiong . Study on the Stability of Purple Cabbage Pigment. University Chemistry, 2024, 39(4): 367-372. doi: 10.3866/PKU.DXHX202401059
4. [4]
  Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
5. [5]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043
6. [6]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
7. [7]
  Jiaxi Xu , Yuan Ma . Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide. University Chemistry, 2024, 39(11): 374-377. doi: 10.3866/PKU.DXHX202402049
8. [8]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
9. [9]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
10. [10]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
11. [11]
  Hongyao Li , Youyan Liu , Luwei Dai , Min Yang , Qihui Wang . The Blessing of Indium Sulfide：Confronting the Narrow Path with Uric Acid. University Chemistry, 2024, 39(5): 325-335. doi: 10.3866/PKU.DXHX202311104
12. [12]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
13. [13]
  Jingke LIU , Jia CHEN , Yingchao HAN . Nano hydroxyapatite stable suspension system: Preparation and cobalt adsorption performance. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1763-1774. doi: 10.11862/CJIC.20240060
14. [14]
  Shule Liu . Application of SPC/E Water Model in Molecular Dynamics Teaching Experiments. University Chemistry, 2024, 39(4): 338-342. doi: 10.3866/PKU.DXHX202310029
15. [15]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
16. [16]
  Jinyao Du , Xingchao Zang , Ningning Xu , Yongjun Liu , Weisi Guo . Electrochemical Thiocyanation of 4-Bromoethylbenzene. University Chemistry, 2024, 39(6): 312-317. doi: 10.3866/PKU.DXHX202310039
17. [17]
  Xiaxue Chen , Yuxuan Yang , Ruolin Yang , Yizhu Wang , Hongyun Liu . Adjustable Polychromatic Fluorescence: Investigating the Photoluminescent Properties of Copper Nanoclusters. University Chemistry, 2024, 39(9): 328-337. doi: 10.3866/PKU.DXHX202308019
18. [18]
  Jinfu Ma , Hui Lu , Jiandong Wu , Zhongli Zou . Teaching Design of Electrochemical Principles Course Based on “Cognitive Laws”: Kinetics of Electron Transfer Steps. University Chemistry, 2024, 39(3): 174-177. doi: 10.3866/PKU.DXHX202309052
19. [19]
  Jiajia Li , Xiangyu Zhang , Zhihan Yuan , Zhengyang Qian , Jian Zhu . 3D Printing Based on Photo-Induced Reversible Addition-Fragmentation Chain Transfer Polymerization. University Chemistry, 2024, 39(5): 11-19. doi: 10.3866/PKU.DXHX202309073
20. [20]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028

Get Citation

PDF

XML

Metrics

PDF Downloads(982)
Abstract views(2433)
HTML views(4)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142