Citation: XU Xiao-Ling, LI Chun-Yi, SHAN Hong-Hong. Novel Modified Magnesium-Aluminate Spinels as Potential FCC Matrix Components[J]. Acta Physico-Chimica Sinica, ;2011, 27(08): 1947-1955. doi: 10.3866/PKU.WHXB20110837 shu

Novel Modified Magnesium-Aluminate Spinels as Potential FCC Matrix Components

1.
State Key Laboratory of Heavy Oil Processing, College of Chemistry and Chemical Engineering, China University of Petroleum (East China), Qingdao 266555, Shandong Province, P. R. China

Received Date: 30 March 2011
Available Online: 28 June 2011
Fund Project:

Modified magnesium-aluminate spinels (MgAl₂O₄) were prepared by recrystallizing a mixture of MgAl₂O₄ and zeolite Y nanoclusters in acidic medium to improve the acidity of MgAl₂O₄, which was commonly used as a sulfur transfer agent in fluid catalytic cracking (FCC) units. The acidity and basicity of these samples can be tuned by varying the pH value of the synthesis system. From the characterization and catalytic cracking tests the introduction of zeolitic building units into the spinels contributed to the increased microporosity, acidity, and hydrothermal stability. The catalytic results indicate that the activities and the product selectivities of the modified spinels for vacuum gas oil (V ) cracking improved remarkably compared to the parent spinel. These samples exhibited even better performance than Kaolin clay for V cracking while retaining a part of the basic sites for oxidative SO₂ uptake. Moreover, the FCC catalyst prepared using the modified spinel as a partial matrix, after equilibration, also gave superior catalytic behavior compared to a reference FCC catalyst with Kaolin clay as the main matrix.
- Magnesium-aluminate spinel,
- Zeolite Y nanocluster,
- Sulfur transfer,
- Catalytic cracking,
- Hydrothermal stability
1. [1]
  
  (1) Pǎcurariu, C.; Lazǎu, I.; Ecsedi, Z.; Lazǎu, R.; Barvinschi, P.; Mǎrginean, G. J. Eur. Ceram. Soc. 2007, 27, 707.
2. [2]
  (2) Prabhakaran, K.; Patil, D. S.; Dayal, R.; khale, N. M.; Sharma, S. C. Mater. Res. Bull. 2009, 44, 613.
3. [3]
  (3) Guo, J.; Lou, H.; Zhao, H.;Wang, X.; Zheng, X. Mater. Lett. 2004, 58, 1920.
4. [4]
  (4) Iqbal, M. J.; Farooq, S. Mater. Sci. Eng. B 2007, 136, 140.
5. [5]
  (5) Bhattacharyya, A. A.;Woltermann, G. M.; Yoo, J. S.; Karch, J. A.; Cormier,W. E. Ind. Eng. Chem. Res. 1988, 27, 1356.
6. [6]
  (6) Yoo, J. S.; Bhattacharyya, A. A.; Radlowski, C. A. Ind. Eng. Chem. Res. 1991, 30, 1444.
7. [7]
  (7) Yoo, J. S.; Bhattacharyya, A. A.; Radlowski, C. A. Ind. Eng. Chem. Res. 1992, 31, 1252.
8. [8]
  (8) Wang, J.; Li, C. Mater. Lett. 1997, 32, 223.
9. [9]
  (9) Wang, J. A.; Chen, L. F.; Limas-Ballesteros, R.; Montoya, A.; Dominguez, J. M. J. Mol. Catal. A- Chem. 2003, 194, 181.
10. [10]
  (10) Wang, J.; Li, C. Appl. Surf. Sci. 2000, 161, 406.
11. [11]
  (11) Wang, J.; Chen, L.; Li, C. J. Mol. Catal. A- Chem. 1999, 139, 315.
12. [12]
  (12) Corma, A.; Palomares, A. E.; Rey, F. Appl. Catal. B 1994, 4, 29.
13. [13]
  (13) Corma, A.; Palomares, A. E.; Rey, F.; Márques, F. J. Catal. 1997, 170, 140.
14. [14]
  (14) Cantú, M.; López-Salinas, E.; Valente, J. S.; Montiel, R. Environ. Sci. Technol. 2005, 39, 9715.
15. [15]
  (15) Palomares, A. E.; Lópes-Nieto, J. M.; Lázaro, F. J.; Lópes, A.; Corma, A. Appl. Catal. B 1999, 20, 257.
16. [16]
  (16) Pereira, H. B.; Polato, C. M. S.; Monteiro, J. L. F.; Henriques, C. A. Catal. Today 2010, 149, 309.
17. [17]
  (17) Busca, G. Catal. Today 1998, 41, 191.
18. [18]
  (18) Shen, J.; Kobe, J. M.; Chen, Y.; Dumesic, J. A. Langmuir 1994, 10, 3902.
19. [19]
  (19) Iglesla, E.; Barton, D. G.; Biscardi, J. A.; Gines, M. J. L.; Soled, S. L. Catal. Today 1997, 38, 339.
20. [20]
  (20) Wang, L.; Guo, H.; Qi,W.; Su, S.; Deng, X.; Liu, J.; Liu, S. Sulfur transfer additive for catalytic cracking of hydrocarbons and a catalytic cracking process of hydrocarbons using the same. US Patent 20030121824A1, 2003-01-21.
21. [21]
  (21) de Morais, B. A. H.; Ramos, F. S. O.; Pinheiro, T. B.; Lima, C. L.; de Sousa, F. F.; Barros, E. B. D.; Filho, J. M.; de Oliveira, A. S.; de Souza, J. R.; Valentini, A.; Oliveira, A. C. Appl. Catal. AGen. 2010, 382, 148.
22. [22]
  (22) Valente, J. S.; Hernandez-Cortez, J.; Cantu, M. S.; Ferrat, G.; López-Salinas, E. Catal. Today 2010, 150, 340.
23. [23]
  (23) Do, T. O.; Nossov, A.; Springuel-Huet, M. A.; Schneider, C.; Bretherton, J. L.; Fyfe, C. A.; Kaliaguine, S. J. Am. Chem. Soc. 2004, 126, 14324.
24. [24]
  (24) Do, T. O.; Kaliaguine, S. J. Am. Chem. Soc. 2003, 125, 618.
25. [25]
  (25) Do, T. O.; Kaliaguine, S. Angew. Chem. 2002, 114, 1078.
26. [26]
  (26) Liu, Y.; Zhang,W. Z.; Pinnavaia, T. J. J. Am. Chem. Soc. 2000, 122, 8791.
27. [27]
  (27) Tan, Q.; Liu, H.; Song, T.; Shi, G.; Shen, B.; Bao, X. AIChE J. 2008, 54, 1850.
28. [28]
  (28) Tan, Q.; Bao, X.; Song, T.; Fan, Y.; Shi, G.; Shen, B.; Liu, C.; Gao, X. J. Catal. 2007, 251, 69.
29. [29]
  (29) Xu, X.; Ran, X.; Cui, Q.; Li, C.; Shan, H. Energy Fuels 2010, 24, 3754.
30. [30]
  (30) Olhero, S. M.; Ganesh, I.; Torres, P. M. C.; Ferreira. J. M. F. Langmuir 2008, 24, 9525.
31. [31]
  (31) Ju, Y.; Shen, Z.; Zhao, J.; Zhao, J.;Wang, X. Acta Phys. -Chim. Sin. 2006, 22, 28. [鞠雅娜, 沈志虹, 赵佳, 赵俊桥, 王秀林. 物理化学学报, 2006, 22, 28.]
32. [32]
  (32) Tonetto, G. M.; Ferreira, M. L.; Atias, J. A.; de Lasa, H. I. AIChE J. 2006, 52, 754.
33. [33]
  (33) Jiang, G.; Zhang, L.; Zhao, Z.; Zhou, X.; Duan, A.; Xu, C.; Gao, J. Appl. Catal. A- Gen. 2008, 340, 176.
34. [34]
  (34) Lercher, J. A.; Jndling, C. G.; Eder-Mirth, G. Catal. Today 1996, 27, 353.
35. [35]
  (35) Song, H.; Jiang,W.; Da, Z. Acta Petrolei Sin. (Pet. Process. Sect.) 2003, 19, 14. [宋海涛, 蒋文斌, 达志坚. 石油学报(石油加工), 2003, 19, 14.]
36. [36]
  (36) Rossi, P. F.; Busca, G.; Lorenzelli, V.; Saur, O.; Lavalley, J. C. Langmuir 1987, 3, 52.
37. [37]
  (37) Rossi, P. F.; Busca, G.; Lorenzelli, V.;Waqif, M.; Saw, O.; Lavalley, J. C. Langmuir 1991, 7, 2677.
38. [38]
  (38) Lavalley, J. C. Catal. Today 1996, 27, 377.
39. [39]
  (39) Wallenstein, D.; Harding, R.H. Appl. Catal. A- Gen. 2001, 214, 11.
40. [40]
  (40) Wang, G.; Xu, C.; Gao, J. Fuel Process. Technol. 2008, 89, 864.
41. [41]
  (41) Ren, Y.; Shi, L. China Inorg. Chem. Ind. 2008, 40, 17. [任彦瑾, 施力. 无机盐工业, 2008, 40, 17.]
1. [1]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
2. [2]
  Xuewei BA , Cheng CHENG , Huaikang ZHANG , Deqing ZHANG , Shuhua LI . Preparation and luminescent performance of Sr_1-xZrSi₂O₇∶xDy³⁺ phosphor with high thermal stability. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 357-364. doi: 10.11862/CJIC.20240096
3. [3]
  Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . 基于高离子迁移动力学的取向ZnQ分子筛保护层实现高稳定水系锌金属负极的构筑. Acta Physico-Chimica Sinica, 2025, 41(1): 2309003-. doi: 10.3866/PKU.WHXB202309003
4. [4]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
5. [5]
  Shitao Fu , Jianming Zhang , Cancan Cao , Zhihui Wang , Chaoran Qin , Jian Zhang , Hui Xiong . Study on the Stability of Purple Cabbage Pigment. University Chemistry, 2024, 39(4): 367-372. doi: 10.3866/PKU.DXHX202401059
6. [6]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043
7. [7]
  Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
8. [8]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
9. [9]
  Jiaxi Xu , Yuan Ma . Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide. University Chemistry, 2024, 39(11): 374-377. doi: 10.3866/PKU.DXHX202402049
10. [10]
  Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 100034-. doi: 10.3866/PKU.WHXB202406012
11. [11]
  Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408
12. [12]
  Yiping HUANG , Liqin TANG , Yufan JI , Cheng CHEN , Shuangtao LI , Jingjing HUANG , Xuechao GAO , Xuehong GU . Hollow fiber NaA zeolite membrane for deep dehydration of ethanol solvent by vapor permeation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 225-234. doi: 10.11862/CJIC.20240224
13. [13]
  Jing SU , Bingrong LI , Yiyan BAI , Wenjuan JI , Haiying YANG , Zhefeng Fan . Highly sensitive electrochemical dopamine sensor based on a highly stable In-based metal-organic framework with amino-enriched pores. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1337-1346. doi: 10.11862/CJIC.20230414
14. [14]
  Renqing Lü , Shutao Wang , Fang Wang , Guoping Shen . Computational Chemistry Aided Organic Chemistry Teaching: A Case of Comparison of Basicity and Stability of Diazine Isomers. University Chemistry, 2025, 40(3): 76-82. doi: 10.12461/PKU.DXHX202404119
15. [15]
  Baitong Wei , Jinxin Guo , Xigong Liu , Rongxiu Zhu , Lei Liu . Theoretical Study on the Structure, Stability of Hydrocarbon Free Radicals and Selectivity of Alkane Chlorination Reaction. University Chemistry, 2025, 40(3): 402-407. doi: 10.12461/PKU.DXHX202406003
16. [16]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
17. [17]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
18. [18]
  Yaping Li , Sai An , Aiqing Cao , Shilong Li , Ming Lei . The Application of Molecular Simulation Software in Structural Chemistry Education: First-Principles Calculation of NiFe Layered Double Hydroxide. University Chemistry, 2025, 40(3): 160-170. doi: 10.12461/PKU.DXHX202405185
19. [19]
  Yanglin Jiang , Mingqing Chen , Min Liang , Yige Yao , Yan Zhang , Peng Wang , Jianping Zhang . Experimental and Theoretical Investigations of Solvent Polarity Effect on ESIPT Mechanism in 4′-N,N-diethylamino-3-hydroxybenzoflavone. Acta Physico-Chimica Sinica, 2025, 41(2): 100012-. doi: 10.3866/PKU.WHXB202309027
20. [20]
  Hongyao Li , Youyan Liu , Luwei Dai , Min Yang , Qihui Wang . The Blessing of Indium Sulfide：Confronting the Narrow Path with Uric Acid. University Chemistry, 2024, 39(5): 325-335. doi: 10.3866/PKU.DXHX202311104

Get Citation

PDF

XML

Metrics

PDF Downloads(982)
Abstract views(2520)
HTML views(4)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142