Citation: WANG Xiao-Rong, HAO Guang-Ping, LU An-Hui, LI Wen-Cui. Adsorption and Release Behavior of Vitamin B12 in Tubular Structured Ordered Mesoporous Carbon[J]. Acta Physico-Chimica Sinica, ;2011, 27(09): 2239-2243. doi: 10.3866/PKU.WHXB20110834 shu

Adsorption and Release Behavior of Vitamin B12 in Tubular Structured Ordered Mesoporous Carbon

1.
State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116023, Liaoning Province, P. R. China

Received Date: 18 April 2011
Available Online: 27 June 2011
Fund Project: 高等学校博士学科点专项科研基金(20100041110017) 资助项目 (20100041110017)

Ordered mesoporous carbon with hexa nal arrays consisting of tubular-type pores (CMK-5) was synthesized via a nanocasting process by the direct use of SBA-15 as a template, furfuryl alcohol as a carbon source and oxalic acid as the catalyst. The structure of CMK-5 was analyzed by different techniques including scanning electron microscopy, powder X-ray diffraction and N₂ adsorption analysis. The specific surface area and pore volume were found to be 1856 m²·g^-1 and 2.10 cm³·g^-1, respectively, with mesopore sizes concentrated at 3.1 and 5.5 nm. Because of the unique structure the adsorption capacities of CMK-5 towards vitamin B12 was found to be as high as 943 mg·g^-1 in a short period of 120 min, which is significantly higher than that of commercial activated carbon. The composites of CMK-5 and vitamin B12 without any treatment gave slow-release performance in a simulated body fluid. The concentration of the release solutions remained 9 mg·L^-1 under dynamic conditions. A high loading capacity and slow release rate of vitamin B12 on the CMK-5 support suggested that CMK-5 might have a potential application in drug delivery.
- Ordered mesoporous carbon,
- Dual-model pore channel,
- Vitamin B12,
- Adsorption,
- Drug release
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沈阳化工大学材料科学与工程学院沈阳 110142