Citation: FANG Yu-Zhu, JIANG Fang-Ting, LU Yong. Electrocatalytic Performance of Self-Supporting CNTs/SMF-Ni Hybrid Electrodes for the Aerobic Oxidation of p-MT to p-MBA[J]. Acta Physico-Chimica Sinica, ;2011, 27(08): 1854-1858. doi: 10.3866/PKU.WHXB20110828 shu

Electrocatalytic Performance of Self-Supporting CNTs/SMF-Ni Hybrid Electrodes for the Aerobic Oxidation of p-MT to p-MBA

1.
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, P. R. China

Received Date: 22 March 2011
Available Online: 23 June 2011
Fund Project: 国家自然科学基金(20973063, 21076083) (20973063, 21076083) 国家重点基础研究发展规划项目(973) (2011CB201403) (973) (2011CB201403) (20090076110006) (20090076110006)科技启明星(跟踪)计划&rdquo (跟踪)(10HQ1400800) (10HQ1400800)上海市重点学科建设项目(B409)资助 (B409)

A promising macroscopic carbon nanotube (CNT) system was developed by catalytic chemical vapor deposition through CNT growth on a three-dimensional network of sinter-locked conductive metal microfibers (i.e., SMF-Ni using 8 μm nickel fibers and SMF-SS using 8 μm SS316L fibers). The electrocatalytic performance of CNTs/SMF-Ni [CNTs: 50% (w)] and CNTs/SMF-SS [CNTs: 40% (w)] hybrids were examined as electrodes in the aerobic oxidation of p-anisaldehyde (p-MT) to p-cresol methyl ether (p-MBA). An excellent conversion of 95.4% and a target product selectivity of 96.5% can be obtained with a very high electric current efficiency of >80% in the presence of air at a current density of 16 mA·cm^-2 in a methanol/p-MT/KF electrolyte using SMF-SS and CNTs/SMF-Ni as an anode and a cathode, respectively.
- CNTs,
- Electrochemical oxidation,
- p-Anisaldehyde,
- p-Cresol methyl ether
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