Citation: FANG Yu-Zhu, JIANG Fang-Ting, LU Yong. Electrocatalytic Performance of Self-Supporting CNTs/SMF-Ni Hybrid Electrodes for the Aerobic Oxidation of p-MT to p-MBA[J]. Acta Physico-Chimica Sinica, ;2011, 27(08): 1854-1858. doi: 10.3866/PKU.WHXB20110828 shu

Electrocatalytic Performance of Self-Supporting CNTs/SMF-Ni Hybrid Electrodes for the Aerobic Oxidation of p-MT to p-MBA

1.
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, P. R. China

Received Date: 22 March 2011
Available Online: 23 June 2011
Fund Project: 国家自然科学基金(20973063, 21076083) (20973063, 21076083) 国家重点基础研究发展规划项目(973) (2011CB201403) (973) (2011CB201403) (20090076110006) (20090076110006)科技启明星(跟踪)计划&rdquo (跟踪)(10HQ1400800) (10HQ1400800)上海市重点学科建设项目(B409)资助 (B409)

A promising macroscopic carbon nanotube (CNT) system was developed by catalytic chemical vapor deposition through CNT growth on a three-dimensional network of sinter-locked conductive metal microfibers (i.e., SMF-Ni using 8 μm nickel fibers and SMF-SS using 8 μm SS316L fibers). The electrocatalytic performance of CNTs/SMF-Ni [CNTs: 50% (w)] and CNTs/SMF-SS [CNTs: 40% (w)] hybrids were examined as electrodes in the aerobic oxidation of p-anisaldehyde (p-MT) to p-cresol methyl ether (p-MBA). An excellent conversion of 95.4% and a target product selectivity of 96.5% can be obtained with a very high electric current efficiency of >80% in the presence of air at a current density of 16 mA·cm^-2 in a methanol/p-MT/KF electrolyte using SMF-SS and CNTs/SMF-Ni as an anode and a cathode, respectively.
- CNTs,
- Electrochemical oxidation,
- p-Anisaldehyde,
- p-Cresol methyl ether
1. [1]
  
  (1) Hu, A. Z.; Zhang, S. J.; Zhu, R. F. J. Shenyang Inst. Chem. Tech. 2000, 14 (2), 124. [胡爱珠, 张胜建, 朱瑞芬. 沈阳化工学院学报, 2000, 14 (2), 124.]
2. [2]
  (2) Shi, Y. X.;Wang, C. L.; Lin, F. L. Appl. Chem. Ind. 2001, 30 (2), 22. [石玉香, 王春林, 林枫玲. 应用化工, 2001, 30 (2), 22.]
3. [3]
  (3) Gu, D. P.; Jia, Z. B. Progress of Organic Electrosynthesis Technology; China Petrochemical Press: Beijing; 2001. [顾登平, 贾振斌. 有机电合成进展. 北京: 中国石化出版社, 2001.]
4. [4]
  (4) Zhong,W. H. Flavour Frag. Cosmet. 1990, 4, 4. [钟文海. 香料香精化妆品, 1990, 4, 4.]
5. [5]
  (5) Bentrup, U.; Martin, A.;Wolf, G. U. Catal. Today 2003, 78 (1-4), 229.
6. [6]
  (6) Reddy, B. M.; Vijaya, K. M.; Jeeva, R. K. Appl. Catal. A- Gen. 1999, 181 (1), 77.
7. [7]
  (7) Yi, F. P.; Zhou, Y. H.; Li,W. G.; Liu, X. M. J. Guangxi Univ. (Nat. Sci. Ed.) 1998, 23 (1), 54. [易封萍, 周永红, 李伟光, 刘雄民. 广西大学学报(自然科学), 1998, 23 (1), 54.]
8. [8]
  (8) Li,W. G.; Su, G. J.; Liu, X. M.; Liang, H. J. Chem. World 2003, 9, 464. [李伟光, 粟桂娇, 刘雄民, 梁红军. 化学世界, 2003, 9, 464.]
9. [9]
  (9) Liu, L. H.; Ning, X. L. Guangxi Chem. Ind. 1997, 26 (1), 11. [刘利华, 宁秀玲. 广西化工, 1997, 26 (1), 11.]
10. [10]
  (10) Wang, Q. J.; Liu, F. S.; Yu, S. T. J. Qingdao Sci. Tech. (Nat. Sci. Ed.) 2007, 28 (2), 118. [王庆军, 刘富胜, 于世涛. 青岛科技大学学报(自然科学版), 2007, 28 (2), 118.]
11. [11]
  (11) Gu, D. P.; Hu, R. S.; Liu, X; Zhang, Y. J. Fine Chem. 2004, 21 (1), 53. [顾登平, 胡瑞省, 刘欣, 张元静. 精细化工, 2004, 21 (1), 53.]
12. [12]
  (12) Tang, X. J.; Liang, J. J.; Yan, X.; Li, P. H. Chem. Engineer 2008, 148 (1), 60. [唐新军, 梁建军, 颜鑫, 李平辉. 化学工程师, 2008, 148 (1), 60.]
13. [13]
  (13) Tang, X. J.; Ou, L. H.; Yi, J. L.; Zeng, Y. Chem. Res. Appl. 2005, 18 (5), 554. [唐新军, 欧利辉, 易建龙, 曾跃. 化学研究与应用, 2005, 18 (5), 554.]
14. [14]
  (14) Bejan, D.; Savall, A. J. Electroanal. Chem. 2001, 507 (1-2), 234.
15. [15]
  (15) Hu, R. S.; Liu, X.; Gu, D. P.; Zhang, Y. J. J. Chem. Eng. Chin. Univ. 2005, 19 (1), 134. [胡瑞省, 刘欣, 顾登平, 张元静. 高校化学工程学报, 2005, 19 (1), 134.]
16. [16]
  (16) Said, A. H.; Mhalla, F. M.; Amatore, C. Verpeaux, J. N. J. Electroanal. Chem. 1999, 464 (1), 85.
17. [17]
  (17) Ogibin, Y. N.; Ilovaisky, A. I.; Merkulova, V. M. Russ. Chem. Bull. 1995, 44, 507.
18. [18]
  (18) Fichter, F.; Christen, A. Helv. Chim. Acta 1925, 8, 332.
19. [19]
  (19) Yang, A. Y.; Liu, S. R.; Hu, Y. C. Chin. J. Synthetic Chem. 1995, 3 (3), 239. [杨爱云, 刘士荣, 胡云楚. 合成化学, 1995, 3 (3), 239.]
20. [20]
  (20) Li, Z. L.; Zhang, Y. K.; Cheng, J. P. Fine Chem. 1995, 12 (11), 16. [李则林, 张永康, 成介平. 精细化工, 1995, 12 (11), 16.]
21. [21]
  (21) Jiang, H.;Wu, B. L.; Cha, C. S. Electrochim. Acta 1998, 43 (16-17), 2549.
22. [22]
  (22) Yang, J. L.; Li, J. F.; Lu, Y. Acta Phys. -Chim. Sin. 2009, 25, 2045 [杨九龙, 李剑锋, 路勇. 物理化学学报, 2009, 25, 2045.]
23. [23]
  (23) Jiang, F. T.; Fang, Y. Z.; Liu, Y.; Chen, L.; Xue, Q. S.; Lu, Y.; Lu, J. X.; He, M. Y. J. Mater. Chem. 2009, 19 (22), 3632.
24. [24]
  (24) Liu? Y.;Wang? H.; Li? J. F.; Lu? Y.;Wu? H. H.; Xue? Q. S.; Chen, L. Appl. Catal. A- Gen. 2007, 328, 77.
25. [25]
  (25) Jiang, F. T. Preparation, Characterization and Application of Carbon Nano-tubes (CNTs) Grown on Thin-sheet Sinter-locked Ni-/SS-316L-microfibers. Ph. D. Dissertation. East China Normal University, Shanghai, 2009. [姜芳婷. 薄层烧结Ni 或SS-316L纤维上碳纳米管(CNTs)的生长、表征及应用探索研究[D.] 上海: 华东师范大学, 2009.]
26. [26]
  (26) Carra, S.; Santacesaria, E. Catal. Rev.-Sci. Eng. 1980, 22, 75.
27. [27]
  (27) Yano, T.; Popa, E.; Tryk, D. A.; Hashimoto, K.; Fujishima, A. J. Electrochem. Soc. 1999, 146 (3), 1081.
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