Citation: LI Qing-Hai, GU Tong-Xin, YU Sheng-Song, YAO Yan, LI Bing, LI Wu. Study on the Precipitation Pathway of Nanyishan Oilfield Brine at Subzero Temperatures[J]. Acta Physico-Chimica Sinica, ;2011, 27(08): 1803-1808. doi: 10.3866/PKU.WHXB20110823 shu

Study on the Precipitation Pathway of Nanyishan Oilfield Brine at Subzero Temperatures

LI Qing-Hai ^2,3 ,
GU Tong-Xin ¹ ,
YU Sheng-Song ² ,
YAO Yan ² ,
LI Bing ^2, ,
LI Wu ²

1.
1. State Key Laboratory of Frozen Soil Engineering Cold and Arid Regions Environmental & Engineering Research Institute, Chinese Academy of Sciences, Lanzhou 730000;
2. Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008;
3. Graduate University of Chinese Academy of Sciences, Beijing 100049

Received Date: 28 March 2011
Available Online: 21 June 2011
Fund Project: 国家自然科学基金(41073023) (41073023)国家十一五科技支撑计划项目(2006BAB09B07)资助 (2006BAB09B07)

The crystallization processes of oilfield brine components from the Nanyishan area at temperature between -18.90 and -30.90 °C were studied by a self-designed refrigeration instrument and the precipitation temperatures of the first and second salts were measured accurately. The concentrations of the major ions (Ca²⁺, Mg²⁺, K⁺, Cl^-, B₂O₃, Na⁺) in the liquid phase of the brine at different temperatures (from -18.90 to -30.90 °C) were determined by chemical analyses. The solids obtained at low temperature were identified and the phase changes of the oilfield brine at temperatures between -10.0 and -30.0 °C were monitored in situ by subzero temperature X-ray powder diffraction. The results show that the first salt (hydrohalite) precipitates at -19.10 °C and the ice and NaCl·2H₂O co-precipitate at -23.55 °C.
- Oilfield brine,
- Freezing,
- Hydrohalite,
- Ice,
- X-ray diffraction at subzero temperature
1. [1]
  
  (1) Fu, J. L.; Yu, S. S.; Li, S. J.; Ren, H. Y. J. Salt Lake Research 2005, 13, 17. [付建龙, 于升松, 李世金, 任海燕. 盐湖研究, 2005, 13, 17.]
2. [2]
  (2) Cui, X. M. Study on Simulated Evaporation of Nanyishan Oilfield Brine and Identification of Crystallization. Ph. D. Dissertation, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining,2009. [崔香梅.南翼山油田卤水模拟蒸发研究及析出物的鉴定[D]. 西宁: 中国科学院青海盐湖研究所, 2009.]
3. [3]
  (3) Ringer,W. E. J. Chem. Weekblad 1906, 3, 223.
4. [4]
  (4) Nelson, K. H.; Thompson T. G. J. Mar. Res. 1954, 13, 166.
5. [5]
  (5) Thompson, T. G.; Nelson, K. H. Amer. J. Sci. 1956, 254, 227.
6. [6]
  (6) Gitterman, K. E. Thermal Analysis of Seawater, Cold Regions Research and Engineering Laboratory, USA, 1937.
7. [7]
  (7) Li, Q. H.; Li, B.; Yao, Y.;Wu, Z. J.; Li,W. Journal of Salt Lake Research 2009, 17, 64. [李青海,李冰,姚燕,吴志坚, 李武. 盐湖研究, 2009, 17, 64.]
8. [8]
  (8) Richardson, C. Journal of Glaciology 1976, 17, 507.
9. [9]
  (9) Spencer, R. J.; Nancy, M.; John, H.W. Geochimica et Cosmochimica Acta 1990, 54, 575.
10. [10]
  (10) Herut, B.; Starinsky, A.; Katz, A.; Bein, A. Geochim. Cosmochim. Acta 1990, 54, 13.
11. [11]
  (11) Abraham, S. A. Geochimica et Cosmochimica Acta 2003, 67, 1475.
12. [12]
  (12) Han, Y. S.; Meng, G. L.;Wang, S. Q. Quaternary Underground Brine in the Coastal Areas of the Northern China; Science Press: Beijing, 1996; pp 153-155. [韩有松, 孟广兰,王少青著. 中国北方沿海第四纪地下卤水. 北京: 科学出版社, 1996: 153-155.]
13. [13]
  (13) Meng, G. L.;Wang, Z. Y.;Wang, S. Q.;Wang, Y. Q.; Chen, X. B. Oceanologia et Limnologia Sinica 1999, 30, 416. [孟广兰, 王珍岩, 王少青, 王雅卿, 陈肖柏. 海洋与湖沼, 1999, 30, 416.]
14. [14]
  (14) Gao, S. Y.; Liu, H. G.; Mu, Z. J. Chinese Journal of Inorganic Chemistry 1987, 3, 113. [高世扬, 刘化国, 牟振基. 无机化学学报, 1987, 3, 113.]
15. [15]
  (15) Gao, S. Y.; Zhao, J. F.; Xue, F. S. J. Salt Lake Research 1998, 6, 1. [高世扬, 赵金福, 薛方山. 盐湖研究, 1998, 6, 1.]
16. [16]
  (16) Guo, G. L.; Zhang, S. B. Journal of Sea-Lake Salt and Chemical Industry 1996, 25, 11 [郭桂兰, 张士宾. 海湖盐与化工, 1996, 25,11.]
17. [17]
  (17) Zhang, Y. S.; Mie, Z.; Bo, L. Z.; Zheng, M. P. Journal of Sea-Lake Salt and Chemical Industry 2001, 30, 3. [张永生, 乜贞, 卜令忠, 郑绵平. 海湖盐与化工, 2001, 30, 3.]
18. [18]
  (18) Yi, L. X.;Wang, X. K.; Sun, Z. N.; Chen, L. F.; Dong, J. G.; Tang, N.; Xu, B. L.; Ma, R. X. Journal of Sea-Lake Salt and Chemical Industry 2002, 31, 4. [衣丽霞, 王学魁, 孙之南, 陈丽芳, 董景岗, 唐娜, 徐宝玲, 马若欣. 海湖盐与化工, 2002, 31, 4.]
19. [19]
  (19) Wu, Z. M.; Deng, X. C. Journal of Inorganic Chemicals Industry 2001, 33, 6. [乌志明,邓小川. 无机盐工业, 2001, 33, 6.]
20. [20]
  (20) Qinghai Institute of Salt Lakes, Chinese Academy of Sciences. Analysis Methods for Brines and Salts, 2nd ed; Science Press: Beijing, 1988. [中国科学院青海盐湖研究所. 卤水和盐的分析方法. 第二版. 北京: 科学出版社, 1988.]
21. [21]
  (21) Liu,W. H.; He, J. J.;Wang, L. Analytical Instrumentation 1999, No. 2, 5. [刘文华, 何建久, 王立. 分析仪器, 1999, No. 2, 5.]
22. [22]
  (22) Fang, Y.; Song, P. S.; Lei, Y. C.; Yang, B.; Guo, Y. M.; Fang, C. H. Journal of Analytical Science 2000, 16, 153. [房艳, 宋彭生, 雷亚川, 杨波, 郭亚梅, 房春晖. 分析科学学报, 2000, 16, 153.]
23. [23]
  (23) Fang, Y.; Song, P. S.; Lei, Y. C.; Yang, B.; Fang, C. H. Journal of Analytical Science 2000, 16, 211. [房艳, 宋彭生, 雷亚川, 杨波, 房春晖. 分析科学学报, 2000, 16, 210.]
24. [24]
  (24) Fang, Y.; Yang, B.; Lei, Y. C.; Fang, C. H. Journal of Analytical Science 2000, 16, 383. [房艳, 杨波, 雷亚川, 房春晖. 分析科学学报, 2000, 16, 383.]
25. [25]
  (25) Zhou, Y. Q.; Fang, Y.; Fang, C. H. Acta Phys. -Chim. Sin. 2010, 26, 2323. [周勇全, 房艳, 房春晖. 物理化学学报, 2010, 26, 2323.]
26. [26]
  (26) Li, Q. H.; He, L.;Yao, Y.; Zhu, D. H.; Li, B.; Li,W. Chinese Journal of Inorganic Chemistry 2010, 26, 1804. [李青海, 何荔, 姚燕, 朱东海, 李冰, 李武. 无机化学学报, 2010, 26, 1804.]
1. [1]
  Wei Li , Guoqiang Feng , Ze Chang . Teaching Reform of X-ray Diffraction Using Synchrotron Radiation in Materials Chemistry. University Chemistry, 2024, 39(3): 29-35. doi: 10.3866/PKU.DXHX202308060
2. [2]
  Hongwei Ma , Hui Li . Three Methods for Structure Determination from Powder Diffraction Data. University Chemistry, 2024, 39(3): 94-102. doi: 10.3866/PKU.DXHX202310035
3. [3]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
4. [4]
  Yubang Li , Xixi Hu , Daiqian Xie . The microscopic formation mechanism of O + H2 products from photodissociation of H2O. Chinese Journal of Structural Chemistry, 2024, 43(5): 100274-100274. doi: 10.1016/j.cjsc.2024.100274
5. [5]
  Xin Li , Wanting Fu , Ruiqing Guan , Yue Yuan , Qinmei Zhong , Gang Yao , Sheng-Tao Yang , Liandong Jing , Song Bai . Nucleophiles promotes the decomposition of electrophilic functional groups of tetracycline in ZVI/H₂O₂ system: Efficiency and mechanism. Chinese Chemical Letters, 2024, 35(10): 109625-. doi: 10.1016/j.cclet.2024.109625
6. [6]
  Dong-Xue Jiao , Hui-Li Zhang , Chao He , Si-Yu Chen , Ke Wang , Xiao-Han Zhang , Li Wei , Qi Wei . Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units. Chinese Journal of Structural Chemistry, 2024, 43(6): 100304-100304. doi: 10.1016/j.cjsc.2024.100304
7. [7]
  Jing Wang , Zhongliao Wang , Jinfeng Zhang , Kai Dai . Single-layer crystalline triazine-based organic framework photocatalysts with different linking groups for H2O2 production. Chinese Journal of Structural Chemistry, 2023, 42(12): 100202-100202. doi: 10.1016/j.cjsc.2023.100202
8. [8]
  Zhenyu Hu , Zhenchun Yang , Shiqi Zeng , Kun Wang , Lina Li , Chun Hu , Yubao Zhao . Cationic surface polarization centers on ionic carbon nitride for efficient solar-driven H₂O₂ production and pollutant abatement. Chinese Chemical Letters, 2024, 35(10): 109526-. doi: 10.1016/j.cclet.2024.109526
9. [9]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007
10. [10]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
11. [11]
  Hongwei Ma , Fang Zhang , Hui Ai , Niu Zhang , Shaochun Peng , Hui Li . Integrated Crystallographic Teaching with X-ray,TEM and STM. University Chemistry, 2024, 39(3): 5-17. doi: 10.3866/PKU.DXHX202308107
12. [12]
  Yang Xia , Kangyan Zhang , Heng Yang , Lijuan Shi , Qun Yi . 构建双通道路径增强iCOF/Bi₂O₃ S型异质结在纯水体系中光催化合成H₂O₂性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407012-. doi: 10.3866/PKU.WHXB202407012
13. [13]
  Zhenchun Yang , Bixiao Guo , Zhenyu Hu , Kun Wang , Jiahao Cui , Lina Li , Chun Hu , Yubao Zhao . Molecular engineering towards dual surface local polarization sites on poly(heptazine imide) framework for boosting H₂O₂ photo-production. Chinese Chemical Letters, 2024, 35(8): 109251-. doi: 10.1016/j.cclet.2023.109251
14. [14]
  Xiaodan Wang , Yingnan Liu , Zhibin Liu , Zhongjian Li , Tao Zhang , Yi Cheng , Lecheng Lei , Bin Yang , Yang Hou . Highly efficient electrosynthesis of H₂O₂ in acidic electrolyte on metal-free heteroatoms co-doped carbon nanosheets and simultaneously promoting Fenton process. Chinese Chemical Letters, 2024, 35(7): 108926-. doi: 10.1016/j.cclet.2023.108926
15. [15]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
16. [16]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
17. [17]
  Liang TANG , Jingfei NI , Kang XIAO , Xiangmei LIU . Synthesis and X-ray imaging application of lanthanide-organic complex-based scintillators. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1892-1902. doi: 10.11862/CJIC.20240139
18. [18]
  Yuqiao Zhou , Weidi Cao , Shunxi Dong , Lili Lin , Xiaohua Liu . Study on the Teaching Reformation of Practical X-ray Crystallography. University Chemistry, 2024, 39(3): 23-28. doi: 10.3866/PKU.DXHX202303003
19. [19]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
20. [20]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019

Get Citation

PDF

XML

Metrics

PDF Downloads(1071)
Abstract views(2548)
HTML views(62)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142