Citation: LI Qing-Hai, GU Tong-Xin, YU Sheng-Song, YAO Yan, LI Bing, LI Wu. Study on the Precipitation Pathway of Nanyishan Oilfield Brine at Subzero Temperatures[J]. Acta Physico-Chimica Sinica, ;2011, 27(08): 1803-1808. doi: 10.3866/PKU.WHXB20110823 shu

Study on the Precipitation Pathway of Nanyishan Oilfield Brine at Subzero Temperatures

LI Qing-Hai ^2,3 ,
GU Tong-Xin ¹ ,
YU Sheng-Song ² ,
YAO Yan ² ,
LI Bing ^2, ,
LI Wu ²

1.
1. State Key Laboratory of Frozen Soil Engineering Cold and Arid Regions Environmental & Engineering Research Institute, Chinese Academy of Sciences, Lanzhou 730000;
2. Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008;
3. Graduate University of Chinese Academy of Sciences, Beijing 100049

Received Date: 28 March 2011
Available Online: 21 June 2011
Fund Project: 国家自然科学基金(41073023) (41073023)国家十一五科技支撑计划项目(2006BAB09B07)资助 (2006BAB09B07)

The crystallization processes of oilfield brine components from the Nanyishan area at temperature between -18.90 and -30.90 °C were studied by a self-designed refrigeration instrument and the precipitation temperatures of the first and second salts were measured accurately. The concentrations of the major ions (Ca²⁺, Mg²⁺, K⁺, Cl^-, B₂O₃, Na⁺) in the liquid phase of the brine at different temperatures (from -18.90 to -30.90 °C) were determined by chemical analyses. The solids obtained at low temperature were identified and the phase changes of the oilfield brine at temperatures between -10.0 and -30.0 °C were monitored in situ by subzero temperature X-ray powder diffraction. The results show that the first salt (hydrohalite) precipitates at -19.10 °C and the ice and NaCl·2H₂O co-precipitate at -23.55 °C.
- Oilfield brine,
- Freezing,
- Hydrohalite,
- Ice,
- X-ray diffraction at subzero temperature
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