Citation: JIANG Jin-Qiang, NG Yun-Hua, CHENG Hao, LIU Xiao-Ya, ZHANG Sheng-Wen, XU Jing. Photodimerization Behavior of 7-Hydroxy-4-methyl-8-(4'-methylpiperazin-1'-yl) Methylcoumarin[J]. Acta Physico-Chimica Sinica, ;2011, 27(08): 1968-1974. doi: 10.3866/PKU.WHXB20110821 shu

Photodimerization Behavior of 7-Hydroxy-4-methyl-8-(4'-methylpiperazin-1'-yl) Methylcoumarin

1.
School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, Jiangsu Province, P. R. China

Received Date: 4 May 2011
Available Online: 20 June 2011
Fund Project: 国家自然科学基金(20704017, 50973044) (20704017, 50973044)项目及中央高校基本科研业务费专项资金(JUSRP31003)资助 (JUSRP31003)

The water-soluble coumarin derivative 7-hydroxy-4-methyl-8-(4'-methylpiperazin-1'-yl) methylcoumarin (HMPC) was synthesized by the Mannich reaction between 7-hydroxy-4-methylcoumarin and N-methylpiperazine, which possesses an electrondonating piperazine group with pH responsivity. Since the piperazine group is a pH-sensitive electron donor, the resultant HMPC has interesting photophysical and photochemical properties in different pH solutions. We investigated the characteristic UV absorption and photodimerization behavior of the coumarin derivative. The characteristic UV absorption and also the photodimerization of HMPC, which was irradiated by UV light (λ>310 nm), was effectively changed in different pH solutions. The photodimerization experiments showed that in the neutral solution the dimerization reaction rate was most rapid followed by that in the alkaline solution and it was the slowest in the acidic solution at the same concentration.
- Coumarin,
- Piperazine,
- pH-sensitivity,
- Tertiary amine group,
- Electron donor,
- Photodimerization
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