Citation: WANG Jian-Tao, ZHANG Xiao-Hong, WANG Hui, OU Xue-Mei. Super-Hydrophobic Silicon/Silica Hierarchical Structure Film[J]. Acta Physico-Chimica Sinica, ;2011, 27(09): 2233-2238. doi: 10.3866/PKU.WHXB20110820 shu

Super-Hydrophobic Silicon/Silica Hierarchical Structure Film

1.
1. Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China;
2. Graduate University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Received Date: 20 April 2011
Available Online: 20 June 2011
Fund Project: 国家自然科学基金(50825304, 50972150, 20971128)资助项目 (50825304, 50972150, 20971128)

Silicon (Si)-based materials with a super-hydrophobic surface were prepared using microscale rough surfaces, which were subsequently modified by organic compounds with low surface energies. However, the super-hydrophobicity was gradually lost because of the degradation of the organic compounds when applied to an outer environment. Herein, a Si-based film with a super-hydrophobic surface fabricated by chemical vapor deposition (CVD) using a liquid metal (tin) as the growth substrate is reported. We found that the film was composed of vertical Si/SiO₂ hierarchical wires upon characterization by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD). Reasons for the generation of this super-hydrophobicity are given using the Cassie model. We conclude that the special Si/SiO₂ hierarchical structure plays an important role in the super-hydrophobic performance of the film. Compared with the previous Si-based material with a super-hydrophobic surface, this novel structure promises to widen its area of application since its super-hydrophobicity is independent of chemical modification.
- Super-hydrophobic,
- Core-shell structure,
- Silicon nanowire,
- Chemical vapor deposition,
- Film
1. [1]
  (1) Nakajima, A.; Hashimoto, K.;Watanable, T. Monatsh. Chem. 2001, 132, 31.
2. [2]
  (2) Gao, X. F.; Jiang, L. Nature 2004, 432, 36.
3. [3]
  (3) Erbil, H. Y.; Demirel, A. L.; Avci, Y.; Mert, O. Science 2003, 299, 1377.
4. [4]
  (4) Zhang, X.; Shi, F.; Niu, J.; Jiang, Y. G.;Wang, Z. Q. J. Mater. Chem. 2008, 18, 621.
5. [5]
  (5) Sun, T. L.; Feng, L.; Gao, X. F.; Jiang, L. Accounts Chem. Res. 2005, 38, 644.
6. [6]
  (6) Li, X. M.; Reinhoudt, D.; Cre -Calama, M. Chem. Soc. Rev. 2007, 36, 1350.
7. [7]
  (7) Sun, T. L.;Wang, G. J.; Feng, L.; Liu, B. Q.; Ma, Y. M.; Jiang, L.; Zhu, D. B. Angew. Chem. Int. Edit. 2004, 43, 357.
8. [8]
  (8) Zhai, L.; Berg, M. C.; Cebeci, F. Nano Lett. 2006, 6, 1213.
9. [9]
  (9) Li, X. M.; He, T.; Cre -Calama, M.; Reinhoudt, D. N. Langmuir 2008, 24, 8008.
10. [10]
  (10) Han,W.;Wu, D.; Ming,W.; Niemantsverdriet, H.; Thuene, P. C. Langmuir 2006, 22, 7956.
11. [11]
  (11) Jin, M. H.; Feng, X. J.; Feng, L.; Sun, T. L.; Zhai, J.; Li, T. J.; Jiang, L. Adv. Mater. 2005, 17, 1977.
12. [12]
  (12) Ji, J.; Fu, J.; Shen, J. Adv. Mater. 2006, 18, 1441.
13. [13]
  (13) Hang, T.; Hu, A. M.; Ling, H. Q.; Li, M.; Mao, D. L. Applied Surface Science 2010, 256, 2400.
14. [14]
  (14) Feng, L.; Li, S. H.; Li, H. J.; Zhai, J.; Song, Y. L.; Jiang, L.; Zhu, D. B. Angew. Chem. Int. Edit. 2002, 114, 1269.
15. [15]
  (15) Zhou, S. S.; Guan, Z. S.; Li, Q.; Lu, C. H.; Xu, Z. Z. Acta Phys. -Chim. Sin. 2009, 25, 1593. [周思斯, 管自生, 李强, 陆春华, 许仲梓. 物理化学学报, 2009, 25, 1593.]
16. [16]
  (16) Li, M.; Zhai, J.; Liu, H.; Song, Y.; Jiang, L.; Zhu, D. J. Phys. Chem. B 2003, 107, 9954.
17. [17]
  (17) Cao, L. L.; Price, T. P.;Weiss, M.; Gao, D. Langmuir 2008, 24, 1640.
18. [18]
  (18) Peng, K. Q.; Yan, Y. J.; Gao, S. P.; Zhu, J. Adv. Mater. 2002, 14, 1164.
19. [19]
  (19) Zhou, M.; Zheng, A. R.; Yang, J. H. Acta Phys. -Chim. Sin. 2007, 23, 1296. [周明, 郑傲然, 杨加宏. 物理化学学报, 2007, 23, 1296.]
20. [20]
  (20) Zhao, N.; Shi, F.;Wang, Z. Q.; Zhang, X. Langmuir 2005, 21, 4713.
21. [21]
  (21) Zhang, X.; Shi, F.; Yu, X.; Liu, H.; Fu, Y.;Wang, Z.; Jiang, L.; Li, X. J. Am. Chem. Soc. 2004, 126, 3064.
22. [22]
  (22) Lim, H. S.; Han, J. T.; Kwak, D.; Jin, M.; Cho, K. J. Am. Chem. Soc. 2006, 128, 14458.
23. [23]
  (23) Shirtcliffe, N. J.; McHale, G.; Newton, M. I.; Perry, C. C.; Roach, P. Chem. Commun. 2005, 3135.
24. [24]
  (24) Han, J. T.; Lee, D. H.; Ryu, C. Y.; Cho, K. J. Am. Chem. Soc. 2004, 126, 4796.
25. [25]
  (25) Li, S. M.; Zhou, S. Z.; Liu, J. H. Acta Phys. -Chim. Sin. 2009, 25, 2581. [李松梅, 周思卓, 刘建华. 物理化学学报, 2009, 25, 2581.]
26. [26]
  (26) Minko, S.; Muller, M.; Motornov, M.; Nitschke, M.; Grundke, K.; Stamm, M. J. Am. Chem. Soc. 2003, 125, 3896.
27. [27]
  (27) Zhou, Y. B.; He, B.; Yang, Y.;Wang, F.; Liu,W. M.;Wang, P. F.; Zhang,W. J.; Bello, J.; Lee, S. T. J. Nanosci. Nanotechnol. 2011, 11, 2292.
28. [28]
  (28) Xiu, Y. H.; Zhang, S.; Yelundur, V.; Rohatgi, A.; Hess, D.W.; Wong, C. P. Langmuir 2008, 24, 10421.
29. [29]
  (29) Xiu, Y. H.; Zhu, L. B.; Hess, D.W.;Wong, C. P. Nano Lett., 2007, 7, 3388.
30. [30]
  (30) Cao, M.W.; Song, X. Y.; Zhai, J.;Wang, J. B.;Wang, Y. L. J. Phys. Chem. B 2006, 110, 13072.
31. [31]
  (31) Baldacchini, T.; Carey, J. E.; Zhou, M.; Mazur, E. Langmuir 2006, 22, 4917.
32. [32]
  (32) Oner, D.; Mccarthy, T. J. Langmuir 2000, 16, 7777.
33. [33]
  (33) Nosonovsky, M.; Bhushan, B. Nano Lett. 2007, 7, 2633.
34. [34]
  (34) Xiu, Y. H.; Zhu, L. B.; Hess, D.W.;Wong, C. P. J. Phys. Chem. C 2008, 112, 11403.
35. [35]
  (35) Verplanck, N.; Galopin, E.; Camart, J. C.; Thomy, V.; Coffinier, Y.; Boukherroub, R. Nano Lett. 2007, 7, 813.
36. [36]
  (36) Dorrer, C.; Rühe, J. Adv. Mater. 2008, 20, 159.
37. [37]
  (37) Piret, G.; Coffinier, Y.; Roux, C.; Melnyk, O.; Boukherroub, R. Langmuir 2008, 24, 1670.
38. [38]
  (38) Wang, H.; Zhang, X. H.; Ma, D. D. D.; Lee, S. T. Appl. Phys. Lett. 2008, 93, 023119.
39. [39]
  (39) Wang, H.; Zhang, X. H.; Fan, X.; Lee, C. S.; Lee, S. T. Chem. Commun. 2009, 5916.
40. [40]
  (40) Cassie, A. B. D.; Baxter, S. Trans. Faraday Soc. 1944, 40, 546.
1. [1]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
2. [2]
  Xiyuan Su , Zhenlin Hu , Ye Fan , Xianyuan Liu , Xianyong Lu . Change as You Want: Multi-Responsive Superhydrophobic Intelligent Actuation Material. University Chemistry, 2024, 39(5): 228-237. doi: 10.3866/PKU.DXHX202311059
3. [3]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
4. [4]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
5. [5]
  Cunming Yu , Dongliang Tian , Jing Chen , Qinglin Yang , Kesong Liu , Lei Jiang . Chemistry “101 Program” Synthetic Chemistry Experiment Course Construction: Synthesis and Properties of Bioinspired Superhydrophobic Functional Materials. University Chemistry, 2024, 39(10): 101-106. doi: 10.12461/PKU.DXHX202408008
6. [6]
  Chunai Dai , Yongsheng Han , Luting Yan , Zhen Li , Yingze Cao . Preparation of Superhydrophobic Surfaces and Their Application in Oily Wastewater Treatment: Design of a Comprehensive Physical Chemistry Innovation Experiment. University Chemistry, 2024, 39(2): 34-40. doi: 10.3866/PKU.DXHX202307081
7. [7]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
8. [8]
  Hongyun Liu , Jiarun Li , Xinyi Li , Zhe Liu , Jiaxuan Li , Cong Xiao . Course Ideological and Political Design of a Comprehensive Chemistry Experiment: Constructing a Visual Molecular Logic System Based on Intelligent Hydrogel Film Electrodes. University Chemistry, 2024, 39(2): 227-233. doi: 10.3866/PKU.DXHX202309070
9. [9]
  Lijuan Wang , Yuping Ning , Jian Li , Sha Luo , Xiongfei Luo , Ruiwen Wang . Enhancing the Advanced Nature of Natural Product Chemistry Laboratory Courses with New Research Findings: A Case Study of the Application of Berberine Hydrochloride in Photodynamic Antimicrobial Films. University Chemistry, 2024, 39(11): 241-250. doi: 10.12461/PKU.DXHX202403017
10. [10]
  Xiaowu Zhang , Pai Liu , Qishen Huang , Shufeng Pang , Zhiming Gao , Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021
11. [11]
  Fan Wu , Wenchang Tian , Jin Liu , Qiuting Zhang , YanHui Zhong , Zian Lin . Core-Shell Structured Covalent Organic Framework-Coated Silica Microspheres as Mixed-Mode Stationary Phase for High Performance Liquid Chromatography. University Chemistry, 2024, 39(11): 319-326. doi: 10.12461/PKU.DXHX202403031
12. [12]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
13. [13]
  Jia Yao , Xiaogang Peng . Theory of Macroscopic Molecular Systems: Theoretical Framework of the Physical Chemistry Course in the Chemistry “101 Plan”. University Chemistry, 2024, 39(10): 27-37. doi: 10.12461/PKU.DXHX202408117
14. [14]
  Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, 2024, 39(10): 271-282. doi: 10.12461/PKU.DXHX202404121
15. [15]
  Yinyin Qian , Rui Xu . Utilizing VESTA Software in the Context of Material Chemistry: Analyzing Twin Crystal Nanostructures in Indium Antimonide. University Chemistry, 2024, 39(3): 103-107. doi: 10.3866/PKU.DXHX202307051
16. [16]
  Rui Li , Jiayu Zhang , Anyang Li . Two Levels of Understanding of Chemical Bonds: a Case of the Bonding Model of Hypervalent Molecules. University Chemistry, 2024, 39(2): 392-398. doi: 10.3866/PKU.DXHX202308051
17. [17]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-. doi: 10.3866/PKU.WHXB202408012
18. [18]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
19. [19]
  Jin Tong , Shuyan Yu . Crystal Engineering for Supramolecular Chirality. University Chemistry, 2024, 39(3): 86-93. doi: 10.3866/PKU.DXHX202308113
20. [20]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1254-1260. doi: 10.11862/CJIC.20240047

Get Citation

PDF

XML

Metrics

PDF Downloads(1530)
Abstract views(3337)
HTML views(10)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142