Citation: WANG Jian-Tao, ZHANG Xiao-Hong, WANG Hui, OU Xue-Mei. Super-Hydrophobic Silicon/Silica Hierarchical Structure Film[J]. Acta Physico-Chimica Sinica, ;2011, 27(09): 2233-2238. doi: 10.3866/PKU.WHXB20110820 shu

Super-Hydrophobic Silicon/Silica Hierarchical Structure Film

1.
1. Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China;
2. Graduate University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Received Date: 20 April 2011
Available Online: 20 June 2011
Fund Project: 国家自然科学基金(50825304, 50972150, 20971128)资助项目 (50825304, 50972150, 20971128)

Silicon (Si)-based materials with a super-hydrophobic surface were prepared using microscale rough surfaces, which were subsequently modified by organic compounds with low surface energies. However, the super-hydrophobicity was gradually lost because of the degradation of the organic compounds when applied to an outer environment. Herein, a Si-based film with a super-hydrophobic surface fabricated by chemical vapor deposition (CVD) using a liquid metal (tin) as the growth substrate is reported. We found that the film was composed of vertical Si/SiO₂ hierarchical wires upon characterization by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD). Reasons for the generation of this super-hydrophobicity are given using the Cassie model. We conclude that the special Si/SiO₂ hierarchical structure plays an important role in the super-hydrophobic performance of the film. Compared with the previous Si-based material with a super-hydrophobic surface, this novel structure promises to widen its area of application since its super-hydrophobicity is independent of chemical modification.
- Super-hydrophobic,
- Core-shell structure,
- Silicon nanowire,
- Chemical vapor deposition,
- Film
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