Citation: FU Rong, ZHENG Jun-Sheng, WANG Xi-Zhao, MA Jian-Xin. Effect of the Reduction Heat-Treatment Condition on the Performance of Pt-Fe/C Alloy Catalyst[J]. Acta Physico-Chimica Sinica, ;2011, 27(09): 2141-2147. doi: 10.3866/PKU.WHXB20110809 shu

Effect of the Reduction Heat-Treatment Condition on the Performance of Pt-Fe/C Alloy Catalyst

FU Rong ^1,2 ,
ZHENG Jun-Sheng ^1,3, ,
WANG Xi-Zhao ^1,3 ,
MA Jian-Xin ^1,3,

1.
1. Clean Energy Automotive Engineering Center, Tongji University (Jiading Campus), Shanghai 201804, P. R. China;
2. School of Resource and Environment Engineering, East China University of Science and Technology, Shanghai 200237, P. R. China;
3. School of Automotive Studies, Tongji University (Jiading Campus), Shanghai 201804, P. R. China

Received Date: 1 April 2011
Available Online: 13 June 2011
Fund Project: 国家自然科学基金(21006073) (21006073)上海市青年科技启明星计划(11QA1407200) (11QA1407200)上海市重点学科(B303)资助项目 (B303)

Pt-Fe/C catalyst for proton exchange membrane fuel cell (PEMFC) was prepared by a pulse-microwave assisted chemical reduction heat-treatment synthesis method. The elemental content was tested by inductively coupled plasma (ICP). The microstructure and morphology of the as-prepared catalyst were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The electrocatalytic performance was measured by cyclic voltammetry (CV). The results indicate that pulse-microwave assisted chemical reduction heat-treatment synthesis is an efficient method for preparing PEMFC catalysts while the temperature and time of heat treatment greatly affect the size and activity of the Pt-Fe nanoparticles. For a heating temperature of 500 °C and a time of 3 h the Pt-Fe nanoparticles were uniform in size. Moreover, the Pt-Fe/C-500-3h alloy catalyst was highly dispersed on the surface of the carbon support and the TEM and XRD showed that the average Pt-Fe nanoparticle size was 1.8 nm. The electrochemical measurements show that the electrochemical surface area (ESA) of the catalyst was 55.14 m²·g^-1.
- Pulse-microwave assisted chemical reduction,
- Fuel cell,
- Pt-Fe/C catalyst
1. [1]
  (1) Prater, K. B. J. Power Sources 1996, 61, 105.
2. [2]
  (2) Ran, H. B.; Li, L. L.; Li, L.;Wei, Z. D. J. Chongqing University (Science Edition) 2005, 28 (4), 120. [冉洪波, 李兰兰, 李莉, 魏子栋. 重庆大学学报(自然科学版), 2005, 28 (4), 120.]
3. [3]
  (3) Wei, Z. D.; Zhang, S. T.; Tang, Z. Y.; Guo, H. T. J. Electrochem. 2000, 30, 723-725.
4. [4]
  (4) Toda, T.; Igarashi, H.; Uchida, H.;Watanabe, M. J. Electrochem. Soc. 1999, 146, 3750.
5. [5]
  (5) Beard, C.; Ross, P. N. J. Electrochem. Soc. 1990, 137, 3368.
6. [6]
  (6) Mukerjee, S.; Srinivasan, S. J. Electroanal. Chem. 1993, 357, 201.
7. [7]
  (7) Zhang, P.; Pan, M.; Yuan, R. Z.; ng, Y. P. Chin. J. Nonferrous Metals 2004, 14 (7), 1157. [张萍, 潘牧, 袁润章, 巩英鹏. 中国有色金属学报, 2004, 14 (7), 1157.]
8. [8]
  (8) Li,W. Z.; Xin, Q.; Yan, Y. S. Int. J. Hydrog. Energy 2010, 35 (6), 2530.
9. [9]
  (9) Li,W.; Zhou,W. J.; Li, H. Q.; Zhou, Z. H.; Zhou, B.; Sun, G. Q.; Xin, Q. Electrochimica Acta 2004, 49 (7), 1045.
10. [10]
  (10) Malheiro, A. R.; Perez, J.; Villullas, H. M. J. Power Sources 2010, 195, 3111.
11. [11]
  (11) Deivaraj, T. C.; Lee, J. Y. J. Power Sources 2005, 142, 43.
12. [12]
  (12) Park, G. G.; Yang, T. H.; Yoon, Y. G.; Lee,W. Y.; Kim, C. S. Int. J. Hydrog. Energy 2003, 28 (6), 645.
13. [13]
  (13) Chu, Y. Y.;Wang, Z. B.; Gu, D. M.; Yin, G. P. J. Power Sources 2010, 195, 1799
14. [14]
  (14) Song, S. Q.;Wang, Y.; Shen, P. K. J. Power Sources 2007, 170, 46
15. [15]
  (15) Wang, X. Z.; Zheng, J. S.; Fu, R.; Ma, J. X. Acta Phys. -Chim. Sin. 2011, 27 (1), 85. [王喜照, 郑俊生, 符蓉, 马建新. 物理化学学报, 2011, 27 (1), 85.]
16. [16]
  (16) Wang, X. Z.; Zheng, J. S.; Fu, R.; Ma, J. X. Chin. J. Catal. 2011, 32 (4), 599. [王喜照, 郑俊生, 符蓉, 马建新. 催化学报, 2011, 32 (4), 599.]
17. [17]
  (17) Salgado, J. R. C.; Antolini, E.; nzalez, E. R. J. Power Sources 2005, 141, 13.
18. [18]
  (18) Baglio, V.; Ari?o, A.S.; Stassi, A.; D'Urso, C. D.; Blasi, A. D.; Luna, A. M. C.; Antonucci, V. J. Power Sources 2006, 159, 900.
19. [19]
  (19) Raadmilovic, V.; Gasteiger, H. A.; Ross, P. N. J. Catal. 1995, 154, 98.
20. [20]
  (20) Soryna, S. C. Handbook of Stable Strontium; Plenum Press: New York, 1981, pp 11-13.
1. [1]
  Shiqi Zhang , Heng Zhang , Aiwen Lei . 从物理化学的角度看化学能的利用. University Chemistry, 2025, 40(6): 310-315. doi: 10.12461/PKU.DXHX202408124
2. [2]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069
3. [3]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
4. [4]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
5. [5]
  Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . 碳修饰的铜催化剂实现安培级电流电化学还原CO₂制C₂₊产物. Acta Physico-Chimica Sinica, 2025, 41(3): 2404012-. doi: 10.3866/PKU.WHXB202404012
6. [6]
  Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081
7. [7]
  Yulian Hu , Xin Zhou , Xiaojun Han . A Virtual Simulation Experiment on the Design and Property Analysis of CO₂ Reduction Photocatalyst. University Chemistry, 2025, 40(3): 30-35. doi: 10.12461/PKU.DXHX202403088
8. [8]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
9. [9]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
10. [10]
  Zelong LIANG , Shijia QIN , Pengfei GUO , Hang XU , Bin ZHAO . Synthesis and electrocatalytic CO₂ reduction performance of metal-organic framework catalysts loaded with silver particles. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 165-173. doi: 10.11862/CJIC.20240409
11. [11]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
12. [12]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
13. [13]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
14. [14]
  Xue Liu , Lipeng Wang , Luling Li , Kai Wang , Wenju Liu , Biao Hu , Daofan Cao , Fenghao Jiang , Junguo Li , Ke Liu . Cu基和Pt基甲醇水蒸气重整制氢催化剂研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100049-. doi: 10.1016/j.actphy.2025.100049
15. [15]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
16. [16]
  Yu Wang , Haiyang Shi , Zihan Chen , Feng Chen , Ping Wang , Xuefei Wang . 具有富电子Pt^δ^-壳层的空心AgPt@Pt核壳催化剂：提升光催化H₂O₂生成选择性与活性. Acta Physico-Chimica Sinica, 2025, 41(7): 100081-. doi: 10.1016/j.actphy.2025.100081
17. [17]
  Fangxuan Liu , Ziyan Liu , Guowei Zhou , Tingting Gao , Wenyu Liu , Bin Sun . Hollow structured photocatalysts. Acta Physico-Chimica Sinica, 2025, 41(7): 100071-. doi: 10.1016/j.actphy.2025.100071
18. [18]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
19. [19]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
20. [20]
  Xuejie Wang , Guoqing Cui , Congkai Wang , Yang Yang , Guiyuan Jiang , Chunming Xu . 碳基催化剂催化有机液体氢载体脱氢研究进展. Acta Physico-Chimica Sinica, 2025, 41(5): 100044-. doi: 10.1016/j.actphy.2024.100044

Get Citation

PDF

XML

Metrics

PDF Downloads(1058)
Abstract views(2410)
HTML views(3)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142