Citation: SHI Heng-Chao, WANG Wen-Chun, YANG De-Zheng, HUO Yan, JIA Li. Effect of OH Radicals on Formaldehyde Removal in Dielectric Barrier Discharge[J]. Acta Physico-Chimica Sinica, ;2011, 27(08): 1979-1984. doi: 10.3866/PKU.WHXB20110802 shu

Effect of OH Radicals on Formaldehyde Removal in Dielectric Barrier Discharge

1.
Key Laboratory of Materials Modification by Laser, Ion and Electron Beams, Dalian University of Technology, Dalian 116024, Liaoning Province, P. R. China

Received Date: 26 January 2011
Available Online: 8 June 2011
Fund Project: 国家自然科学基金(50977006, 10575019) (50977006, 10575019) 辽宁省教育厅重点实验室项目(2009S017) (2009S017)中央高校基本科研业务费专项资金 (DUT10JR03)资助项目 (DUT10JR03)

The removal of formaldehyde by dielectric barrier discharge in a coaxial cylindrical reactor has been studied at atmospheric pressure. The emission spectra of OH (A²Σ→X ²Π, 0-0) emitted from the dielectric barrier discharge have been successfully recorded. The relationship between the removal efficiency of formaldehyde and the emission intensity of OH (A²Σ→X ²Π, 0-0) has been investigated at different applied voltages, driving frequencies, concentrations of ar n and oxygen. We find that the removal efficiency of HCHO increases when the emission intensity of OH (A²Σ→X ²Π, 0-0) increases with rising applied voltage, driving frequency, and concentration of ar n. However, the removal efficiency of HCHO decreases when the emission intensity of OH (A²Σ→X ²Π, 0-0) decreases with an increase in the concentration of oxygen. The removal efficiency of HCHO is 93.8% in N₂+HCHO mixed gas at 11.5 kV applied voltage and 9 kHz driving frequency.
- Dielectric barrier discharge,
- Formaldehyde removal,
- OH radical,
- Emission spectrum,
- Atmospheric pressure
1. [1]
  
  (1) Kim, M. G.; No, B. Y.; Lee, S. M.; Nieh,W. L. J. Appl. Poly. Sci. 2003, 89, 1896.
2. [2]
  (2) Liu, X. C.; Zhang, J. Z. Studies of Trace Elements and Health 2007, 24, 55. [刘雪春, 张进忠. 微量元素与健康研究, 2007, 24, 55.]
3. [3]
  (3) Wang, G. D.; Li, K. L.; Li, D. L. Environmental Science Trends 2004, 3, 43. [王国栋, 李科林, 李德良. 环境科学动态, 2004, 3, 43.]
4. [4]
  (4) Li, J. S.; Zhao, S. H.; Xing, Y. Chinese Journal of Public Health Engineering 2002, 1, 136. [李景舜, 赵淑华, 邢义. 中国卫生工程学, 2002, 1, 136.]
5. [5]
  (5) Rong, H. Q.; Ryu, Z. Y.; Zheng, J. T.; Zhang, Y. L. J. Colloid Interface Sci. 2003, 61, 207.
6. [6]
  (6) Saleh, J. M.; Hussian, S. M. J. Chem. Soc., Faraday Trans. 1986, 82, 2221.
7. [7]
  (7) Troe, J. J. Phys. Chem. A 2007, 111, 3862.
8. [8]
  (8) Yang, J. J.; Li, D. X.; Li, Q. L.; Zhang, Z. J.;Wang, H. Q. Acta Phys. -Chim. Sin. 2001, 17, 278. 杨建军, 李东旭, 李庆霖, 张治军, 汪汉卿. 物理化学学报, 2001, 17, 278.]
9. [9]
  (9) Storch, D. G.; Kushner, M. J. J. Appl. Phys. 1993, 73, 51.
10. [10]
  (10) Chang, M. B.; Lee, C. C. Environ. Sci. Technol. 1995, 29, 181.
11. [11]
  (11) Simiand, N. B.; Pasquiers, S.; Jorand, F.; Postel, C.; Vacher, J. R. J. Phys. D-Appl. Phys. 2009, 42, 122003.
12. [12]
  (12) Ding, H. X.; Zhu, A. M.; Yang, X. F.; Li, C. H.; Xu, Y. J. Phys. D-Appl. Phys. 2005, 38, 4160.
13. [13]
  (13) Liang,W. J.; Li, J.; Li, J. X.; Zhu, T.; Jin, Y. Q. J. Hazard. Mater. 2010, 175, 1090.
14. [14]
  (14) Lowke, J. J.; Morrow, R. IEEE Trans. Plasma Sci. 1995, 23, 661.
15. [15]
  (15) Kohno, H.; Berezin, A. A.; Chang, J. S.; Tamura, M.;Yamamoto, T.; Shibuya, A.; Hondo, S. IEEE Trans. Ind. Appl. 1998, 34, 953.
16. [16]
  (16) Herzberg, G. Molecular Spectra and Molecular Strutture, Vol.1; Science Press: Beijing, 1983; pp 148?163; Trans. byWang, D. C. [Herzberg, G. 分子光谱与分子结构, 第一卷. 王鼎昌, 译. 北京: 科学出版社, 1983: 148?163.]
17. [17]
  (17) Zhang, J.; Lv, F. G.; Xu, Y.; Yang, X. F.; Zhu, A. M. Acta Phys. -Chim. Sin. 2007, 23, 1425. [张静, 吕福功, 徐勇, 杨学锋, 朱爱民. 物理化学学报, 2007, 23, 1425.]
18. [18]
  (18) Baulch, D. L.; Bowman, C. T.; Cobos, C. J.; Cox, R. A.; Just, T.; Kerr, J. A.; Pilling, M. J.; Stocker, D.; Troe, J.; Tsang,W.;Walker, R.W.;Warnatz, J. J. Phys. Chem. Ref. Data 2005, 34, 757.
19. [19]
  (19) Eichwald, O.; Yousfi, M.; Hennad, A.; Benabdessadok, M. D. J. Appl. Phys. 1997, 82, 4781.
20. [20]
  (20) Baulch, D. L.; Cobos, C. J.; Cox, R. A.; Esser, C.; Frank, P.; Just, T.; Kerr, J. A.; Pilling, M. J.; Troe, J.;Walker, R.W.; Warnatz, J. J. Phys. Chem. Ref. Data 1992, 21, 411.
21. [21]
  (21) Tsang,W.; Hampson, R. F. J. Phys. Chem. Ref. Data 1986, 15, 1087.
22. [22]
  (22) Leblond, J. B.; Collier, F.; Hoffbeck, F.; Cottin, P. J. Chem. Phys. 1981, 74, 6242.
23. [23]
  (23) Touzeau, M.; Pagnon, D. Chem. Phys. Lett. 1978, 53, 355.
24. [24]
  (24) Ono, R.; Oda, T. IEEE Trans. Ind. Appl. 2000, 36, 82.
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