Citation: BASLAK Canan, BIN L Haluk, COSKUN Ahmet, ATALAY Tevfik. Synthesis of a Novel Thiadiazine Derivative and Electrochemical Properties for Pb²⁺ Transfer across Water/1,2-Dichloroethane Interface[J]. Acta Physico-Chimica Sinica, ;2011, 27(08): 1859-1862. doi: 10.3866/PKU.WHXB20110801 shu

Synthesis of a Novel Thiadiazine Derivative and Electrochemical Properties for Pb²⁺ Transfer across Water/1,2-Dichloroethane Interface

1.
Department of Chemistry, Selcuk University, 42099 Meram/Konya, Turkey

Received Date: 14 March 2011
Available Online: 7 June 2011
Fund Project: The project was supported by the Scientific Research Fund of Selcuk University, Turkey (BAP-07201027). (BAP-07201027)

The transfer of Pb²⁺ facilitated by interfacial complexation with 5-(4-phenoxyphenyl)-6H-1,3,4-thiadiazin-2-amine (PPTA) at the polarized water/1,2-dicholoroethane (1,2-DCE) interface was investigated by cyclic voltammetry. We synthesized the thiadiazine derivative, PPTA, firstly. The transfer was performed at different metal concentrations and scan rates, and the obtained voltammetric transfer peaks toward Pb²⁺ ion over other divalent cations (Zn²⁺, Co²⁺, Ni²⁺, Cd²⁺, Hg²⁺, and Cu²⁺) were reversible. The dependence of the half-wave potentials of the Pb²⁺ ion on the concentration of PPTA in the organic phase indicates that the ion transfer is facilitated by the formation of 1:2 (metal:ligand) complex in the organic phase with the association constant (lgβ₂) of (17.1±0.2).
- Pb²⁺,
- Thiadiazine,
- Cyclic voltammetry,
- Ion transfer,
- ITIES
1. [1]
  
  (1) Ferreira, E. S.; Garau, A.; Lippolis, V.; Pereira, C. M.; Silva, F. J. Electroanal. Chem. 2006, 587, 155.
2. [2]
  (2) Katano, H.; Kuboyama, H.; Senda, M. J. Electroanal. Chem. 2000, 483, 117.
3. [3]
  (3) Bin l, H.; Akgemci, E. G.; Ersoz, M.; Atalay, T. Electroanalysis 2007, 19, 1327.
4. [4]
  (4) Shaaban, M. R.; Fuchigami, T. Tetrahedron Lett. 2002, 43, 273.
5. [5]
  (5) Zhang, M.; Sun, P.; Chen, Y.; Li, F.; Gao, Z.; Shao, Y. Chin. Sci. Bull. 2003, 48, 1234.
6. [6]
  (6) Tomaszewski, L.; Reymond, F.; Brevet, P. F.; Girault, H. H. J. Electroanal. Chem. 2000, 483, 135.
7. [7]
  (7) Kasumov, V. T.; K?ksal, F. Spectrochim. Acta Part A 2005, 61, 225.
8. [8]
  (8) Hatay, I.; Su, B.; Li, F.; Partovi-Nia, R.; Vrubel, H.; Hu, X.; Ersoz, M.; Girault, H. H. Angew. Chem. Int. Edit. 2009, 48, 5139.
9. [9]
  (9) Alemu, H. Pure Appl. Chem. 2004, 76, 697.
10. [10]
  (10) Herzog, G.; McMahon, B.; Lefoix, M.; Mullins, N. D.; Collins, C. J.; Moynihan, H. A.; Arrigan, D.W. M. J. Electroanal. Chem. 2008, 622, 109.
11. [11]
  (11) bry, V.; Ulmeanu, S.; Reymond, F.; Bouchard, G.; Carrupt, P. A.; Testa, B.; Girault, H. H. J. Am. Chem. Soc. 1998, 123, 10684.
12. [12]
  (12) Koryta, J. Electrochim. Acta 1979, 24, 293.
13. [13]
  (13) Shao, Y.; Stewart, A. A.; Girault, H. H. J. Chem. Soc. Faraday Trans. 1991, 87, 2593.
14. [14]
  (14) Lagger, G.; Tomaszewski, L.; Osborne, M. D.; Seddon, B. J.; Girault, H. H. J. Electroanal. Chem. 1998, 451, 29.
15. [15]
  (15) Prasad, A. R.; Ramalingam, T.; Rao, A.B.; Diwan, P. V.; Sattur, P. B. Eur. J. Med. Chem. 1989, 24, 199.
16. [16]
  (16) Fotouhi, L.; Mosavi, M.; Heravia, M. M.; Nematollahi, D. Tetrahedron Lett. 2006, 47, 8553.
17. [17]
  (17) Rodr?guez-Fernandez, E.; Manzano, J. L.; Benito, J. J.; Hermosa, R.; Monte, E.; Criado, J. J. J. Inorg. Biochem. 2005, 99, 1558.
18. [18]
  (18) El-Daway, M. A.; Omar, A. M. M. E.; Ismail, A. M.; Hazzaa, A. A. B. J. Pharm. Sci. 1983, 72, 45.
19. [19]
  (19) Witvrouw, M.; Arranz, M. E.; Pannecouque, C.; Declercq, R.; Jonckheere, H.; Schmit, J. C.; Vandamme, A. M.; Diaz, J. A.; Ingate, S. T.; Desmyter, J.; Esnouf, R.; Van Meervelt, L.; Vega, S.; Balzarini, J.; Clercq, D. Antimicrob. Agents Chemother. 1998, 42, 618.
20. [20]
  (20) Mahajan, R. K.; Sood, P.; Mahajan, M. P.; Singh, P. Anal. Sci. 2004, 20, 1423.
21. [21]
  (21) Adamo, M. A.; Adlington, R. M.; Baldwin J. E.; Day, A. L. Tetrahedron 2004, 60, 841.
22. [22]
  (22) Akgemci, E. G.; Bin l, H.; Ersoz, M.; Stibor, I. Electroanalysis 2008, 20, 1354.
23. [23]
  (23) Marecek, V.; Samec, Z. J. Electroanal. Chem. 1985, 185, 263.
24. [24]
  (24) Koryta, J. Electrochim. Acta 1984, 29, 445.
25. [25]
  (25) Yuan, Y.; Gao, Z.; Guo, J.; Shao, Y. J. Electroanal. Chem. 2002, 526, 85.
26. [26]
  (26) Katano, H.; Senda, M. Anal. Sci. 1996, 12, 683.
27. [27]
  (27) Tetko, V.; Gasteiger, J.; Todeschini, R.; Mauri, A.; Livingstone, D.; Ertl, P.; Palyulin, V. A.; Radchenko, E. V.; Zefirov, N. S.; Makarenko, A. S.; Tanchuk, V. Y.; Prokopenko, V. V. J. Comput. Aid. Mol. Des. 2005, 19, 453.
28. [28]
  (28) Steyaert, G.; Lisa, G.; Gaillard, P.; Boss, G.; Reymond, F.; Girault, H. H.; Carrupt, P. A.; Testa, B. J. Chem. Soc. Faraday Trans. 1997, 93, 401.
29. [29]
  (29) Shao, Y.; Osborne, M. D.; Girault, H. H. J. Electroanal. Chem. 1991, 318, 101.
30. [30]
  (30) Cheng, Y.; Schiffrin, D. J. J. Electroanal. Chem. 1997, 429, 37.
1. [1]
  Cen Zhou , Biqiong Hong , Yiting Chen . Application of Electrochemical Techniques in Supramolecular Chemistry. University Chemistry, 2025, 40(3): 308-317. doi: 10.12461/PKU.DXHX202406086
2. [2]
  Jun LUO , Baoshu LIU , Yunchang ZHANG , Bingkai WANG , Beibei GUO , Lan SHE , Tianheng CHEN . Europium(Ⅲ) metal-organic framework as a fluorescent probe for selectively and sensitively sensing Pb²⁺ in aqueous solution. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2438-2444. doi: 10.11862/CJIC.20240240
3. [3]
  Weiping Guo , Ying Zhu , Hong-Hua Cui , Lingyun Li , Yan Yu , Zhong-Zhen Luo , Zhigang Zou . β-Pb₃P₂S₈: A new optical crystal with exceptional birefringence effect. Chinese Chemical Letters, 2025, 36(2): 110256-. doi: 10.1016/j.cclet.2024.110256
4. [4]
  Yiqian Jiang , Zihan Yang , Xiuru Bi , Nan Yao , Peiqing Zhao , Xu Meng . Mediated electron transfer process in α-MnO₂ catalyzed Fenton-like reaction for oxytetracycline degradation. Chinese Chemical Letters, 2024, 35(8): 109331-. doi: 10.1016/j.cclet.2023.109331
5. [5]
  Yu-Yu Tan , Lin-Heng He , Wei-Min He . Copper-mediated assembly of SO₂F group via radical fluorine-atom transfer strategy. Chinese Chemical Letters, 2024, 35(9): 109986-. doi: 10.1016/j.cclet.2024.109986
6. [6]
  Huiju Cao , Lei Shi . sp¹-Hybridized linear and cyclic carbon chain. Chinese Chemical Letters, 2025, 36(4): 110466-. doi: 10.1016/j.cclet.2024.110466
7. [7]
  Yu-Hang Li , Shuai Gao , Lu Zhang , Hanchun Chen , Chong-Chen Wang , Haodong Ji . Insights on selective Pb adsorption via O 2p orbit in UiO-66 containing rich-zirconium vacancies. Chinese Chemical Letters, 2024, 35(8): 109894-. doi: 10.1016/j.cclet.2024.109894
8. [8]
  Yi Liu , Zhe-Hao Wang , Guan-Hua Xue , Lin Chen , Li-Hua Yuan , Yi-Wen Li , Da-Gang Yu , Jian-Heng Ye . Photocatalytic dicarboxylation of strained C–C bonds with CO₂ via consecutive visible-light-induced electron transfer. Chinese Chemical Letters, 2024, 35(6): 109138-. doi: 10.1016/j.cclet.2023.109138
9. [9]
  Weixu Li , Yuexin Wang , Lin Li , Xinyi Huang , Mengdi Liu , Bo Gui , Xianjun Lang , Cheng Wang . Promoting energy transfer pathway in porphyrin-based sp2 carbon-conjugated covalent organic frameworks for selective photocatalytic oxidation of sulfide. Chinese Journal of Structural Chemistry, 2024, 43(7): 100299-100299. doi: 10.1016/j.cjsc.2024.100299
10. [10]
  Yuan Teng , Zichun Zhou , Jinghua Chen , Siying Huang , Hongyan Chen , Daibin Kuang . Dual atom-bridge effect promoting interfacial charge transfer in 2D/2D Cs₃Bi₂Br₉/BiOBr epitaxial heterojunction for efficient photocatalysis. Chinese Chemical Letters, 2025, 36(2): 110430-. doi: 10.1016/j.cclet.2024.110430
11. [11]
  Huizhong Wu , Ruiheng Liang , Ge Song , Zhongzheng Hu , Xuyang Zhang , Minghua Zhou . Enhanced interfacial charge transfer on Bi metal@defective Bi₂Sn₂O₇ quantum dots towards improved full-spectrum photocatalysis: A combined experimental and theoretical investigation. Chinese Chemical Letters, 2024, 35(6): 109131-. doi: 10.1016/j.cclet.2023.109131
12. [12]
  Xing Xiao , Yunling Jia , Wanyu Hong , Yuqing He , Yanjun Wang , Lizhi Zhao , Huiqin An , Zhen Yin . Sulfur-defective ZnIn2S4 nanosheets decorated by TiO2 nanosheets with exposed {001} facets to accelerate charge transfer for efficient photocatalytic hydrogen evolution. Chinese Journal of Structural Chemistry, 2024, 43(12): 100474-100474. doi: 10.1016/j.cjsc.2024.100474
13. [13]
  Yi Liu , Peng Lei , Yang Feng , Shiwei Fu , Xiaoqing Liu , Siqi Zhang , Bin Tu , Chen Chen , Yifan Li , Lei Wang , Qing-Dao Zeng . Topologically engineering of π-conjugated macrocycles: Tunable emission and photochemical reaction toward multi-cyclic polymers. Chinese Chemical Letters, 2024, 35(10): 109571-. doi: 10.1016/j.cclet.2024.109571
14. [14]
  Junxin Li , Chao Chen , Yuzhen Dong , Jian Lv , Jun-Mei Peng , Yuan-Ye Jiang , Daoshan Yang . Ligand-promoted reductive coupling between aryl iodides and cyclic sulfonium salts by nickel catalysis. Chinese Chemical Letters, 2024, 35(11): 109732-. doi: 10.1016/j.cclet.2024.109732
15. [15]
  Xingang Kong , Yabei Su , Cuijuan Xing , Weijie Cheng , Jianfeng Huang , Lifeng Zhang , Haibo Ouyang , Qi Feng . Facile synthesis of porous TiO₂/SnO₂ nanocomposite as lithium ion battery anode with enhanced cycling stability via nanoconfinement effect. Chinese Chemical Letters, 2024, 35(11): 109428-. doi: 10.1016/j.cclet.2023.109428
16. [16]
  Xiuzheng Deng , Yi Ke , Jiawen Ding , Yingtang Zhou , Hui Huang , Qian Liang , Zhenhui Kang . Construction of ZnO@CDs@Co₃O₄ sandwich heterostructure with multi-interfacial electron-transfer toward enhanced photocatalytic CO₂ reduction. Chinese Chemical Letters, 2024, 35(4): 109064-. doi: 10.1016/j.cclet.2023.109064
17. [17]
  Ying Hou , Zhen Liu , Xiaoyan Liu , Zhiwei Sun , Zenan Wang , Hong Liu , Weijia Zhou . Laser constructed vacancy-rich TiO_2-x/Ti microfiber via enhanced interfacial charge transfer for operando extraction-SERS sensing. Chinese Chemical Letters, 2024, 35(9): 109634-. doi: 10.1016/j.cclet.2024.109634
18. [18]
  Xin Jiang , Han Jiang , Yimin Tang , Huizhu Zhang , Libin Yang , Xiuwen Wang , Bing Zhao . g-C₃N₄/TiO_2-X heterojunction with high-efficiency carrier separation and multiple charge transfer paths for ultrasensitive SERS sensing. Chinese Chemical Letters, 2024, 35(10): 109415-. doi: 10.1016/j.cclet.2023.109415
19. [19]
  Binyang Qin , Mengqi Wang , Shimei Wu , Yining Li , Chilin Liu , Yufei Zhang , Haosen Fan . Carbon dots confined nanosheets assembled NiCo₂S₄@CDs cross-stacked architecture for enhanced sodium ion storage. Chinese Chemical Letters, 2024, 35(7): 108921-. doi: 10.1016/j.cclet.2023.108921
20. [20]
  Huixin Chen , Chen Zhao , Hongjun Yue , Guiming Zhong , Xiang Han , Liang Yin , Ding Chen . Unraveling the reaction mechanism of high reversible capacity CuP₂/C anode with native oxidation PO_x component for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(1): 109650-. doi: 10.1016/j.cclet.2024.109650

Get Citation

PDF

XML

Metrics

PDF Downloads(1062)
Abstract views(2102)
HTML views(17)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of a Novel Thiadiazine Derivative and Electrochemical Properties for Pb2+ Transfer across Water/1,2-Dichloroethane Interface

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis of a Novel Thiadiazine Derivative and Electrochemical Properties for Pb²⁺ Transfer across Water/1,2-Dichloroethane Interface