Citation: BASLAK Canan, BIN L Haluk, COSKUN Ahmet, ATALAY Tevfik. Synthesis of a Novel Thiadiazine Derivative and Electrochemical Properties for Pb²⁺ Transfer across Water/1,2-Dichloroethane Interface[J]. Acta Physico-Chimica Sinica, ;2011, 27(08): 1859-1862. doi: 10.3866/PKU.WHXB20110801 shu

Synthesis of a Novel Thiadiazine Derivative and Electrochemical Properties for Pb²⁺ Transfer across Water/1,2-Dichloroethane Interface

1.
Department of Chemistry, Selcuk University, 42099 Meram/Konya, Turkey

Received Date: 14 March 2011
Available Online: 7 June 2011
Fund Project: The project was supported by the Scientific Research Fund of Selcuk University, Turkey (BAP-07201027). (BAP-07201027)

The transfer of Pb²⁺ facilitated by interfacial complexation with 5-(4-phenoxyphenyl)-6H-1,3,4-thiadiazin-2-amine (PPTA) at the polarized water/1,2-dicholoroethane (1,2-DCE) interface was investigated by cyclic voltammetry. We synthesized the thiadiazine derivative, PPTA, firstly. The transfer was performed at different metal concentrations and scan rates, and the obtained voltammetric transfer peaks toward Pb²⁺ ion over other divalent cations (Zn²⁺, Co²⁺, Ni²⁺, Cd²⁺, Hg²⁺, and Cu²⁺) were reversible. The dependence of the half-wave potentials of the Pb²⁺ ion on the concentration of PPTA in the organic phase indicates that the ion transfer is facilitated by the formation of 1:2 (metal:ligand) complex in the organic phase with the association constant (lgβ₂) of (17.1±0.2).
- Pb²⁺,
- Thiadiazine,
- Cyclic voltammetry,
- Ion transfer,
- ITIES
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of a Novel Thiadiazine Derivative and Electrochemical Properties for Pb2+ Transfer across Water/1,2-Dichloroethane Interface

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通讯作者: 陈斌, bchen63@163.com

Synthesis of a Novel Thiadiazine Derivative and Electrochemical Properties for Pb²⁺ Transfer across Water/1,2-Dichloroethane Interface