Citation:
LIU Run-Hua, ZHANG Sen, XIA Xin-Yuan, YUN Da-Qin, BIAN Zu-Qiang, ZHAO Yong-Liang. DSSCs Using a Nanoparticle/Nanorod Composite TiO2 Film as a Photoanode[J]. Acta Physico-Chimica Sinica,
;2011, 27(07): 1701-1706.
doi:
10.3866/PKU.WHXB20110734
-
TiO2 anatase nanorods (ANR) were synthesized by a two-step hydrothermal method. The materials were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and transmission electron microscopy (TEM). To increase the light harvesting efficiency and electron transfer rate, N719 dye-sensitized solar cells (DSSCs) were constructed and compared by adjusting the doping ratio of the anatase nanoparticles (ANP) and ANR in the TiO2 nanocrystalline film that was used as a photoanode in the DSSCs. The best light-to-electricity conversion efficiency (7.3%) was obtained for a double-layered photoanode (ANP/(ANR+ANP)) cell, which is 20% higher than the traditional single-layered ANP cell (6.1%) when tested under the same conditions and at AM 1.5, 100 mW·cm-2.
-
-
-
[1]
- [2]
-
[3]
(3) Yamaguchi, T.; Tobe, N.; Matsumoto, D.; Arakawa, H. Chem. Commun. 2007, 4767.
-
[4]
(4) Green, M. A.; Emery, K.; King, D. L.; Hishikawa, Y.;Warta,W. Photovolt: Res. Appl. 2006, 14, 455.
-
[5]
(5) Ferber, J.; Luther, J. Solar Energy Materials and Solar Cells 1998, 54, 265.
-
[6]
(6) Barbe, C.; Arendse, F.; Comte, P.; Jirousek, M.; Lenzmann, F.; Shklover, V.; Grätzel, M. J. Am. Ceram. Soc. 1997, 80, 3157.
-
[7]
(7) Koo, B.; Park, J.; Kim, Y.; Choi, S. H.; Sung, Y. E.; Hyeon, T. J. Phys. Chem. B 2006, 110, 24318.
-
[8]
(8) Adachi, M.; Murata, Y.; Takao, J.; Jiu, J.; Sakamoto, M.;Wang, F. J. Am. Chem. Soc. 2004, 126, 14943.
-
[9]
(9) Liu, B.; Aydil, E. S. J. Am. Chem. Soc. 2009, 131, 3985.
-
[10]
(10) Kang, S. H.; Choi, S. H.; Kang, M. S.; Kim, J. Y.; Kim, H. S.; Hyeon, T.; Sung, Y. E. Adv. Mater. 2008, 20, 54.
-
[11]
(11) Law, M.; Greene, L. E.; Johnson, J. C.; Saykally, R.; Yang, P. Nat. Mater. 2005, 4, 455.
- [12]
-
[13]
(13) Yoon, J. H.; Jang, S. R.; Vittal, R.; Lee, J.; Kim, K. J. J. Photochem. Photobiol. A 2006, 180, 184.
-
[14]
(14) Marco, L. D.; Manca, M.; Giannuzzi, R.; Malara, F.; Melcarne, G.; Ciccarella, G.; Zama, I.; Cin lani, R.; Gigli, G. J. Phys. Chem. C 2010, 114, 4228.
-
[15]
(15) Wang, Z. S.; Kawauchi, H.; Kashima, T.; Arakawa, H. Coord. Chem. Rev. 2004, 248, 1381.
-
[16]
(16) Xu, H.; Tao, X.;Wang, D. T.; Zheng, Y. Z.; Chen, J. F. Electrochimica Acta 2010, 55, 2280.
-
[17]
(17) Barbe, C. J.; Arendse, F.; Comte, P.; Jirousek, M.; Lenzmann, F.; Shklover, V.; Grätzel, M. J. Am. Ceram. Soc. 1997, 80, 3157.
-
[18]
(18) Yu, Y. X.; Xu, D. S. Appl. Catal. B: Environ. 2007, 73, 166.
-
[19]
(19) Wang, Z. S.; Huang, C. H.; Huang, Y. Y.; Hou, Y. J.; Xie, P. H.; Zhang, B.W.; Cheng, H. M. Chem. Mater. 2001, 13, 678.
-
[20]
(20) Yang,W. G.;Wan, F. R.;Wang, Y. L.; Jiang, C. H. Appl. Phys. Lett. 2009, 95, 133121.
-
[21]
(21) Wang, Z. S.; Yamaguchi, T.; Sugihara, H.; Arakawa, H. Langmuir 2005, 21, 4272.
- [22]
-
[23]
(23) Hoshikawa, T.; Yamada, M.; Kikuchi, R.; Eguchi, K. J. Electrochim. Soc. 2005, 152, E68.
-
[24]
(24) ng, F. Impedance Analysis of Dye-Sensitized Solar Cells. Ph. D. Dissertation, Tianjin University, Tianjin, 2007. [巩峰. 染料敏化太阳能电池阻抗分析[D]. 天津: 天津大学, 2007.]
-
[25]
(25) Kuang, D. B.; Uchida, S.; Humphry-Baker, R.; Zakeeruddin, S. M.; Grätzel, M. Angew. Chem. Int. Edit. 2008, 47, 1923.
-
[26]
(26) Cheng, Z. L.; Yang, X. R. Chin. J. Anal. Chem. 2000, 29, 6. [程志亮, 杨秀荣. 分析化学, 2000, 29, 6.]
-
[1]
-
-
-
[1]
Yongjie ZHANG , Bintong HUANG , Yueming ZHAI . Research progress of formation mechanism and characterization techniques of protein corona on the surface of nanoparticles. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2318-2334. doi: 10.11862/CJIC.20240247
-
[2]
Zhuoya WANG , Le HE , Zhiquan LIN , Yingxi WANG , Ling LI . Multifunctional nanozyme Prussian blue modified copper peroxide: Synthesis and photothermal enhanced catalytic therapy of self-provided hydrogen peroxide. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2445-2454. doi: 10.11862/CJIC.20240194
-
[3]
Hao GUO , Tong WEI , Qingqing SHEN , Anqi HONG , Zeting DENG , Zheng FANG , Jichao SHI , Renhong LI . Electrocatalytic decoupling of urea solution for hydrogen production by nickel foam-supported Co9S8/Ni3S2 heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2141-2154. doi: 10.11862/CJIC.20240085
-
[4]
Pengyu Dong , Yue Jiang , Zhengchi Yang , Licheng Liu , Gu Li , Xinyang Wen , Zhen Wang , Xinbo Shi , Guofu Zhou , Jun-Ming Liu , Jinwei Gao . NbSe2纳米片优化钙钛矿太阳能电池的埋底界面. Acta Physico-Chimica Sinica, 2025, 41(3): 2407025-. doi: 10.3866/PKU.WHXB202407025
-
[5]
Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C3N4 nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
-
[6]
Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
-
[7]
Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
-
[8]
Zhuo WANG , Xiaotong LI , Zhipeng HU , Junqiao PAN . Three-dimensional porous carbon decorated with nano bismuth particles: Preparation and sodium storage properties. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 267-274. doi: 10.11862/CJIC.20240223
-
[9]
Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd0.5Zn0.5S Nanorods on Ti3C2 MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 100031-. doi: 10.3866/PKU.WHXB202402016
-
[10]
Yipeng Zhou , Chenxin Ran , Zhongbin Wu . Metacognitive Enhancement in Diversifying Ideological and Political Education within Graduate Course: A Case Study on “Solar Cell Performance Enhancement Technology”. University Chemistry, 2024, 39(6): 151-159. doi: 10.3866/PKU.DXHX202312096
-
[11]
Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO2分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
-
[12]
Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
-
[13]
Xiaxue Chen , Yuxuan Yang , Ruolin Yang , Yizhu Wang , Hongyun Liu . Adjustable Polychromatic Fluorescence: Investigating the Photoluminescent Properties of Copper Nanoclusters. University Chemistry, 2024, 39(9): 328-337. doi: 10.3866/PKU.DXHX202308019
-
[14]
Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
-
[15]
Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I2 interface modification engineering on the performance of all-inorganic CsPbBr3 perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
-
[16]
Xiaoyao YIN , Wenhao ZHU , Puyao SHI , Zongsheng LI , Yichao WANG , Nengmin ZHU , Yang WANG , Weihai SUN . Fabrication of all-inorganic CsPbBr3 perovskite solar cells with SnCl2 interface modification. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 469-479. doi: 10.11862/CJIC.20240309
-
[17]
Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS2 Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
-
[18]
Jiahui CHEN , Tingting ZHENG , Xiuyun ZHANG , Wei LÜ . Research progress of near-infrared absorption inorganic nanomaterials in photothermal and photodynamic therapy of tumors. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2396-2414. doi: 10.11862/CJIC.20240106
-
[19]
Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
-
[20]
Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . 氰基修饰的苝二酰亚胺衍生物作为膜厚不敏感型阴极界面材料用于高效有机太阳能电池. Acta Physico-Chimica Sinica, 2025, 41(3): 2406007-. doi: 10.3866/PKU.WHXB202406007
-
[1]
Metrics
- PDF Downloads(1616)
- Abstract views(2769)
- HTML views(15)