Citation: ZHANG Kong, LIU Qian, SU Xiao-Bin, ZHONG Hong-Mei, SHI Yun, PAN Yu-Bai. Effect of Defects on the Luminescence and Scintillation Property of YLuAG:Ce Phosphors Obtained by Different Synthetic Routes[J]. Acta Physico-Chimica Sinica, ;2011, 27(08): 2001-2008. doi: 10.3866/PKU.WHXB20110732 shu

Effect of Defects on the Luminescence and Scintillation Property of YLuAG:Ce Phosphors Obtained by Different Synthetic Routes

ZHANG Kong ^1,2 ,
LIU Qian ^1, ,
SU Xiao-Bin ^1,2 ,
ZHONG Hong-Mei ¹ ,
SHI Yun ³ ,
PAN Yu-Bai ³

1.
1. State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, P. R. China;
2. Graduate University of Chinese Academy of Sciences, Beijing 100049, P. R. China;
3. Key Laboratory of Transparent Opto-functional Inorganic Material, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, P. R. China

Received Date: 21 March 2011
Available Online: 3 June 2011
Fund Project: 国家高技术研究发展计划(863) (2009AA03Z437)资助项目 (863) (2009AA03Z437)

Optimized YLuAG:Ce (Y_0.600Lu_2.364Al₅O₁₂:Ce_0.036) phosphors were synthesized by three methods: nitrate-pyrolysis (NP), co-precipitation (CP) with ammonium hydrogen carbonate, and citrate-combustion (CC). Differences in the reaction process, crystallization, morphologies, photoluminescence (PL), and scintillant performance of the three kinds of phosphors were revealed and are explained using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), transmission electron microscopy (TEM), PL and thermoluminescence (TL) measurements and observations. Obvious differences in the emission bands and decay times of the different phosphors prepared were found and the differences were mostly caused by the defects either on the surface or in the bulk phase of the YLuAG:Ce phosphors powders. The recorded thermoluminescence spectra of the three kinds of phosphors show a different intensity and main glow peak positions. Additionally, the thermoluminescence spectra show that the synthesis methods induce defects in the phosphors. The defects result in strong trapping process effects and a high probability of radiative recombination between the trapped holes and electrons in the final phosphor powders that were obtained using the different synthesis routes.
- YLuAG:Ce phosphor,
- Synthesis,
- Luminescence,
- Decay time,
- Defect
1. [1]
  
  (1) Heath, R. L.; Hofstadter, R.; Hughes, E. B. Nucl. Instrum. Methods 1979, 162, 431.
2. [2]
  (2) Ishii, M.; Kobayashi, M. Cryst. Growth Charact. 1991, 23, 245.
3. [3]
  (3) Nikl, M.; Mihokova, E.; Mares, J. A.; Vedda, A.; Martini, M.; Nejezchleb, K.; Blazek, K. Phys. Stat. Sol. 2000, 181, 10.
4. [4]
  (4) Anti?, ?.; Krsmanovi?, R.;Wojtowicz, M.; Zych, E.; Bártová, B.; Drami?anin, M. D. Opt. Mater. 2010, 32, 1612.
5. [5]
  (5) Mihóková, E.; Nikl, M.; Mareš, J. A.; Beitlerová, A.; Vedda, A.; Nejezchleb, K.; Bla?ek, K.; D'Ambrosio, C. J. Lumin. 2007, 126, 77.
6. [6]
  (6) Pankaratov, V.; Gri rjeva, L.; Millers, D.; Chudoba, T. Radiat. Measur. 2007, 42, 679.
7. [7]
  (7) Zych, E.; Brecdher, C.;Wojtowicz, A. J.; Lingertat, H. J. Lumin. 1997, 75, 193.
8. [8]
  (8) Ikesue, A.; Kamata, K.; Yoshida, K. J. Am. Ceram. Soc. 1995, 78, 225.
9. [9]
  (9) Zych, E.; Brecher, C.; Lingertat, H. J. Lumin. 1998, 78, 121.
10. [10]
  (10) Zhang, K.; Liu, Q. F.; Liu, Q.; Shi, Y.; Pan, Y. B. J. Comb. Chem. 2010, 12, 453.
11. [11]
  (11) Pan, Y. X.;Wu, M. M.; Su, Q. Mater. Sci. Eng. B 2004, 106, 251.
12. [12]
  (12) Qiu, F. G.; Pu, X. P.; Li, J.; Liu, X. J.; Pan,Y. B.; Guo, J. K. Ceram. Int. 2005, 31, 663.
13. [13]
  (13) Bhattacharyya, S.; Ghatak, S. Ceram. Int. 2009, 35, 29.
14. [14]
  (14) Wu, Z. G.; Zhang, X. D.; He,W.; Du, Y.W.; Jia, N. T.; Xu, G. G. J. Alloys Compd. 2009, 468, 571.
15. [15]
  (15) Hassanzadeh-Tabrizi, S. A.; Taheri-Nassaj, E.; Sarpoolaky, H. J. Alloy. Compd. 2008, 456, 282.
16. [16]
  (16) Blasse, G.; Bril, A. Appl. Phys. Lett. 1967, 11, 53.
17. [17]
  (17) Yuan, F. L.; Ryu, H. Mater. Sci. Eng. B 2004, 107, 14.
18. [18]
  (18) Kasuya, R.; Isobe, T.; Kuma, H.; Katano, J. J. Phys. Chem. B 2005, 109, 22126.
19. [19]
  (19) Wei, Z. G.; Sun, L. D.; Jiang, X. C.; Liao, C. S.; Yan, C. H. Chem. Mater. 2003, 15, 3011.
20. [20]
  (20) Robbins, D. J.; Cockayne, B.; Lent, B. Phys. Rev. B 1979, 19, 1254.
21. [21]
  (21) Zhang, K.; Liu, H. Z.;Wu, Y. T. J. Inorg. Mater. 2008, 23, 1045.
22. [22]
  (22) Chen, R.; McKeever, S.W. S. Theory of Thermoluminescence and Related Phenomena. 1st ed.World Scientific: Singapore, 1997; pp 99-113.
23. [23]
  (23) Rodríguez-Rojas, R. A.; De la Rosa-Cruz, E.; Díaz-Torres, L. A.; Salas, P.; Meléndrez, R.; Barboza-Flores, M.; Meneses-Nava, M. A.; Barbosa-Garíc, O. Opt. Mater. 2004, 25, 285.
24. [24]
  (24) Zhong, J. P.; Liang, H. B.; Su, Q.; Zhou, J. Y.;Wang, J. Y. Tans. Nonferrous Met. Soc. China 2009, 19, 1628.
25. [25]
  (25) Yang, X. B.; Xu, J.; Li, H. J.; Bi, Q. Y.; Su, L. B.; Cheng, Y.; Tang, Q. J. Appl. Phys. 2009, 106, 033105.
1. [1]
  Yi DING , Peiyu LIAO , Jianhua JIA , Mingliang TONG . Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393
2. [2]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
3. [3]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
4. [4]
  Bin SUN , Heyan JIANG . Glucose-modified bis-Schiff bases: Synthesis and bio-activities in Alzheimer′s disease therapy. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1338-1350. doi: 10.11862/CJIC.20240428
5. [5]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
6. [6]
  Han ZHANG , Jianfeng SUN , Jinsheng LIANG . Hydrothermal synthesis and luminescent properties of broadband near-infrared Na₃CrF₆ phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098
7. [7]
  Xuewei BA , Cheng CHENG , Huaikang ZHANG , Deqing ZHANG , Shuhua LI . Preparation and luminescent performance of Sr_1-xZrSi₂O₇∶xDy³⁺ phosphor with high thermal stability. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 357-364. doi: 10.11862/CJIC.20240096
8. [8]
  Yan ZHAO , Jiaxu WANG , Zhonghu LI , Changli LIU , Xingsheng ZHAO , Hengwei ZHOU , Xiaokang JIANG . Gd³⁺-doped Sc₂W3O₁₂: Eu³⁺ red phosphor: Preparation and luminescence performance. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 461-468. doi: 10.11862/CJIC.20240316
9. [9]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
10. [10]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
11. [11]
  Jianyu Qin , Yuejiao An , Yanfeng Zhang . In Situ Assembled ZnWO₄/g-C₃N₄ S-Scheme Heterojunction with Nitrogen Defect for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408002-. doi: 10.3866/PKU.WHXB202408002
12. [12]
  Liping GUO . Synthesis and crystal structure characterization of yttrium imido complex: The reactivity of 2-substituted-1-amino-o-carborane with yttrium dialkyl complex. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1409-1415. doi: 10.11862/CJIC.20250065
13. [13]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
14. [14]
  Jia-He Li , Yu-Ze Liu , Jia-Hui Ma , Qing-Xiao Tong , Jian-Ji Zhong , Jing-Xin Jian . 洛芬碱衍生物的合成、化学发光与重金属离子检测. University Chemistry, 2025, 40(6): 230-237. doi: 10.12461/PKU.DXHX202407080
15. [15]
  Cun WANG , Shaohan XU , Yuqian ZHANG , Yaoyao ZHANG , Tao GONG , Rong WEN , Yuhang LIAO , Yanrong REN . Terbium complex electrochemiluminescent emitters: Synthesis and application in the detection of epinephrine. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1351-1360. doi: 10.11862/CJIC.20240427
16. [16]
  Yan ZHAO , Xiaokang JIANG , Zhonghui LI , Jiaxu WANG , Hengwei ZHOU , Hai GUO . Preparation and fluorescence properties of Eu³⁺-doped CaLaGaO₄ red-emitting phosphors. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1861-1868. doi: 10.11862/CJIC.20240242
17. [17]
  Cheng Zheng , Shiying Zheng , Yanping Zhang , Shoutian Zheng , Qiaohua Wei . Synthesis, Copper Content Analysis, and Luminescent Performance Study of Binuclear Copper (I) Complexes with Isomeric Luminescence Shift: A Comprehensive Chemical Experiment Recommendation. University Chemistry, 2024, 39(7): 322-329. doi: 10.3866/PKU.DXHX202310131
18. [18]
  Zishuo Yi , Peng Liu , Yan Xu . Fluorescent “Chameleon”: A Popular Science Experiment Based on Dynamic Luminescence. University Chemistry, 2024, 39(9): 304-310. doi: 10.12461/PKU.DXHX202311079
19. [19]
  Yanyang Li , Zongpei Zhang , Kai Li , Shuangquan Zang . Ideological and Political Design for the Comprehensive Experiment of the Synthesis and Aggregation-Induced Emission (AIE) Performance Study of Salicylaldehyde Schiff-Base. University Chemistry, 2024, 39(2): 105-109. doi: 10.3866/PKU.DXHX202307020
20. [20]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107

Get Citation

PDF

XML

Metrics

PDF Downloads(909)
Abstract views(2898)
HTML views(8)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142