Citation: ZHAO Peng-Fei, JI Sheng-Fu, WEI Ni, MA Qian, LIU Hui, LI Cheng-Yue. Effect of Boron Promoter on the Structure and Hydrodesulfurization Activity of Ni₂P/SBA-15 Catalysts[J]. Acta Physico-Chimica Sinica, ;2011, 27(07): 1737-1742. doi: 10.3866/PKU.WHXB20110728 shu

Effect of Boron Promoter on the Structure and Hydrodesulfurization Activity of Ni₂P/SBA-15 Catalysts

1.
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China

Received Date: 29 December 2010
Available Online: 1 June 2011
Fund Project: 国家基础研究重大项目计划(973) (2006CB202503)基金资助 (973) (2006CB202503)

The catalyst precursors of B-Ni₂P/SBA-15 were synthesized by co-impregnation using (NH₄)₂HPO₄ as the source of phosphorus, Ni(NO)₃ as the source of nickel and H₃BO₃ as the source of boron. The B-Ni₂P/SBA-15 catalysts with an initial P/Ni molar ratio of 0.8 and a boron content from 0.35% to 2.10%(w) were prepared by temperature-programmed reduction in a H₂ flow. The structure of the catalysts was characterized by X-ray diffraction (XRD), N₂ adsorption-desorption, transmission electron microscopy (TEM) and NH₃ temperature-programmed desorption (NH₃-TPD). The catalytic performances of hydrodesulfurization (HDS) were evaluated in a fixed-bed microreactor using dibenzothiophene (DBT) as a model compound. The results showed that the B-Ni₂P/SBA-15 catalysts still retained mesoporous structure. The Ni₂P phase was mainly active phases in all the catalysts. The proper addition of boron reduced the Ni₂P active phases but increased the specific surface area of the catalysts. The amount of acid in B-Ni₂P/SBA-15 also increased with addition of boron. When the reaction temperature was increased from 300 to 360 ℃, the HDS conversion of DBT over the catalyst clearly improved with an increase in the content of boron. The B-Ni₂P/SBA-15 catalyst with a boron content of 1.40%(w) had the best catalytic activity. The mechanism of the HDS of DBT consisted of main direct desulfurization (DDS) over the B-Ni₂P/SBA-15 catalysts.
- Hydrodesulfurization,
- SBA-15,
- Ni₂P,
- Dibenzothiophene,
- Boron
1. [1]
  
  (1) Cheng,W.; Zhang, J. Y.;Wang, R. J.;Wang, Y. Q.; He, F. Acta Phys. -Chim. Sin. 1999, 15, 647. [程伟, 张继炎, 王日杰, 王亚权, 何菲. 物理化学学报, 1999, 15, 647.]
2. [2]
  (2) Li, X. S.; Hou, Z. S.; Xin, Q.; Guo, X. X. Acta Phys. -Chim. Sin. 1993, 9, 63. [李新生, 侯震山, 辛勤, 郭燮贤. 物理化学学报, 1993, 9, 63.]
3. [3]
  (3) Li, X.; Zhang, Y. L.;Wang, A. J.;Wang, Y.; Hu, Y. K. Catal. Commun. 2010, 11, 1129.
4. [4]
  (4) Lee, Y. K.; Shu, Y. Y.; Oyama, S. T. Appl. Catal. A 2007, 322, 191.
5. [5]
  (5) Montesinos, C.; Zepeda, T.; Pawelec, B.; Lima, E.; Fierro, J. G.; Olivas, A.; Reyes, J. Appl. Catal. A 2008, 334, 330.
6. [6]
  (6) Trawczyáski, J. Appl. Catal. A 2000, 197, 289.
7. [7]
  (7) Lu, M. H.;Wang, A. J.; Li, X.; Duan, X. P.; Hu, Y. K. Acta Petro. Sin. (Petrol Proces Sec) 2006, 22, 33. [鲁墨弘, 王安杰, 李翔, 段新平, 胡永康. 石油学报(石油加工), 2006, 22, 33.]
8. [8]
  (8) Abu, I.; Smith, K. Appl. Catal. A 2007, 328, 58.
9. [9]
  (9) Song, L.; Li,W.;Wang, G.; Zhang, M.; Tao, K. Cata1. Today 2007, 125, 137.
10. [10]
  (10) Lee, Y.; Oyama, S. J. Catal. 2006, 239, 376.
11. [11]
  (11) Sawhill, S.; Layman, K.; vanWyk, D.; Engelhard, M.;Wang, C.; Bussell, M. J. Catal. 2005, 231, 300.
12. [12]
  (12) Huang, X. F.; Ji, S. F.;Wu, P. Y.; Liu, Q. Q.; Liu, H.; Zhu, J. Q.; Li, C. Y. Acta Phys. -Chim. Sin. 2008, 24, 1773. [黄晓凡, 季生福, 吴平易, 刘倩倩, 刘辉, 朱吉钦, 李成岳. 物理化学学报, 2008, 24, 1773.]
13. [13]
  (13) Usman, U.; Takaki, M.; Kubota, T.; Okamoto, Y. Appl. Catal. A. 2005, 286, 148.
14. [14]
  (14) Parks, G. L.; Pease, M. L.; Burns, A.W.; Layman, K. A.; Bussell, M. E.;Wang, X.; Hanson, J.; Rodriguez, J. J. Catal. 2007, 246, 277.
15. [15]
  (15) Rayo, P.; Rana, M.; Ramírez, J.; Ancheyta, J.; Elguezabal, A. Catal. Today 2008, 130, 283.
16. [16]
  (16) Ferdous, D.; Dalai, A. K.; Adjaye, J. Appl. Catal. A 2004, 260, 137.
17. [17]
  (17) Korányi, T.; Vít, Z.; Poduval, D.; Ryoo, R.; Kim, H. S.; Hensen, E. M. J. Catal. 2008, 253, 119.
18. [18]
  (18) Duan, X.; Teng, Y.;Wang, A.; Koganb, V. M.; Li, X.;Wang, Y. J. Catal. 2009, 261, 232.
19. [19]
  (19) Shang, H. Y.; Liu, C. G.; Chai, Y. M.; Xing, J. X. Acta Chim. Sin. 2004, 62, 888. [商红岩, 刘晨光, 柴永明, 邢金仙. 化学学报, 2004, 62, 888.]
20. [20]
  (20) Liu, B. J.; Zheng, Y. Y.; Meng, Q. M.; Jiang, Y. T.; Sheng, S. S.; Yang,W. S.; Xiong, G. X. J. Mol. Catal. 2004, 18, 447. [刘百军, 郑宇印, 孟庆民, 蒋应田, 盛世善, 杨维慎, 熊国兴. 分子催化, 2004, 18, 447.]
21. [21]
  (21) Moses, P.; Hinnemann, B.; Tops?e, H.; N?rskov, J. K. J. Catal. 2007, 248, 188.
22. [22]
  (22) Chen, T.;Wang, C. M.;Wang, I.; Tsai, T. C. J. Catal. 2010, 272, 28.
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Effect of Boron Promoter on the Structure and Hydrodesulfurization Activity of Ni2P/SBA-15 Catalysts

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通讯作者: 陈斌, bchen63@163.com

Effect of Boron Promoter on the Structure and Hydrodesulfurization Activity of Ni₂P/SBA-15 Catalysts