Citation: CAO Xiao-Wei, LIU Wen-Hua, LI Xin-Ran, WANG Rong, WU Xia-Qin. SERS Spectroscopic Characterization and Analysis of the Molecular Structure of Linkage Monolayers in Assembled ld Nanoparticle Films[J]. Acta Physico-Chimica Sinica, ;2011, 27(07): 1600-1608. doi: 10.3866/PKU.WHXB20110723 shu

SERS Spectroscopic Characterization and Analysis of the Molecular Structure of Linkage Monolayers in Assembled ld Nanoparticle Films

1.
Department of Chemistry, Shanghai Normal University, Shanghai 200234, P. R. China

Received Date: 24 November 2010
Available Online: 27 May 2011
Fund Project: 国家自然科学基金(20775049, 20973114)资助项目 (20775049, 20973114)

Molecular assembly was used to prepare a 4,4′-dithiodipyridine (PySSPy) self-assembled monolayers (SAMs) modified ld electrode. The prepared PySSPy SAMs modified on ld electrode were then used as linkage monolayers to fabricate ld nanoparticle assembled films. In our research, surface- enhanced Raman scattering (SERS) technique was used to investigate the structural characteristics of the linkage monolayers. Moreover, electrochemical in situ SERS spectroscopy was used to characterize the effect of electrode potential on the molecular structure of this linkage monolayer. An analysis of the regular variations in intensities and shifts of the characteristic Raman peak pairs related to the adsorbed molecules in this linkage monolayer, such as at 1011 and 1093 cm^-1, 1575 and 1610 cm^-1, 1206 and 1215 cm^-1, revealed that the aromaticity of the pyridyl ring groups in the linkage monolayer changed with the applied electrode potential. The results show that the adsorbed molecule exists mainly in the form of a thiol tautomer in the negative potential range while it exists mainly in the form of a thione tautomer in the positive potential range.
- ld nanoparticle,
- Nanoparticle film,
- 4,4′-Dithiodipyridine,
- Self-assembled monolayer,
- Surface-enhanced Raman scattering,
- Electrode potential
1. [1]
  
  (1) Ulman, A. Chem. Rev. 1996, 96, 1533.
2. [2]
  (2) Smallery, J. F.; Feldberg, S.W.; Chidesy, C. E. D.; Linford, M. R.; Newton, M. D.; Liu, Y. P. J.Phys.Chem. 1995, 99, 13141.
3. [3]
  (3) Sun, L.; Crooks, R. M.; Ricoo, A. J. Langmuir 1993, 9, 1775.
4. [4]
  (4) Freeman, R. G.; Grabar, K. C.; Allison, K. J.; Bright, R. M.; Davis, J. A.; Guthrie, A. P.; Hommer, M. B.; Jackson, M. A.; Smith, P. C.;Walter, D. G.; Natan, M. J. Science 1995, 267, 1629.
5. [5]
  (5) Zhu, T.; Zhang, X.;Wang, J.; Fu, X. Y.; Liu, Z. F. Thin Solid Films 1998, 327-329, 595.
6. [6]
  (6) Daniel, M. C.; Astruc, D. Chem. Rev. 2004, 104, 293.
7. [7]
  (7) Mulvaney, S. P.; Keating, C. D. Anal. Chem. 2000, 72, 145R.
8. [8]
  (8) Chumanov, G.; Sokolov, K.; Gre ry, B.W.; Cotton, T. M. J. Phys. Chem. 1995, 99, 9466.
9. [9]
  (9) Cao, X.W.; Qian, Q. Q.; Deng,W. Q.; Zhang, T. T. Acta Chim. Sin. 2010, 68, 107. [曹晓卫, 钱庆庆, 邓卫芹, 张婷婷. 化学学报, 2010, 68, 107.]
10. [10]
  (10) Fu, X. Y.; Mou, T.;Wang, J.; Zhu, T.; Liu, Z. F. Acta Phys.-Chim. Sin. 1998, 14, 968. [符小艺, 牟涛, 王健, 朱涛, 刘忠范. 物理化学学报, 1998, 14, 968.]
11. [11]
  (11) Zhou,W.; Baunach, T.; Ivanova, V.; Kolb, D. M. Langmuir 2004, 20, 4590.
12. [12]
  (12) Hu, J.; Zhao, B.; Xu,W.; Li, B.; Fan, Y. Spectrochimica Acta A 2002, 58, 2827.
13. [13]
  (13) Sawaguchi, T.; Mizutani, F.; Yoshimoto, S.; Taniguchi, I. Electrochim. Acta 2000, 45, 2861.
14. [14]
  (14) Taniguchi, I.; Yoshimoto, S.; Yoshida, M.; Kobayashi, S. I.; Miyawaki, T.; Aono, Y.; Sunatsuki, Y.; Taira, H. Electrochim. Acta 2000, 45, 2843.
15. [15]
  (15) Yu, H. Z.; Xia, N.; Liu, Z. F. Anal. Chem. 1999, 71, 1354.
16. [16]
  (16) Taniguchi, I.; Iseki, M.; Yamaguchi, H.; Yasukouchi, K. J. Electroanal.Chem. 1985, 186, 299.
17. [17]
  (17) Zhang, B.;Wang, R.; Zhu, G. Y.; Cao, X.W.;Wu, X. Q.; Zhang, Z. R.; Ohsaka, T. Electrochemistry 2007, 13, 1. [张蓓, 王荣, 朱国阳, 曹晓卫, 吴霞琴, 章宗穰, 大阪武男. 电化学, 2007, 13, 1.]
18. [18]
  (18) Nogueira, H. I. S.; Cruz, S. M. G.; Soares-Santos, P. C. R.; Ribeiro-Claro, P. J. A.; Trindade, T. J. Raman Spectrosc. 2003, 34, 350.
19. [19]
  (20) Cao, X.W. J. Raman Spectrosc. 2005, 36, 250.
20. [20]
  (19) Chen, T. K.; Luo, G.; Ewing, A. G. Anal. Chem. 1994, 66, 3031.
21. [21]
  (21) Gao, P.;Weaver, M. J. J. Phys. Chem. 1985, 89, 5040.
22. [22]
  (22) Patterson, M. L.;Weaver, M. J. J. Phys. Chem. 1985, 89, 5046.
23. [23]
  (23) Baldwin, J. A.; Schühler, N.; Butler, I. S.; Andrews, M. P. Langmuir 1996, 12, 6389.
24. [24]
  (24) Baldwin, J. A.; Vlckova, B.; Andrews, M. P.; Butler, I. S. Langmuir 1997, 13, 3744.
25. [25]
  (25) Jung, H. S.; Kim, K.; Kim, M. S. J. Mol. Struct. 1997, 407, 139.
26. [26]
  (26) Lin-Vien, D.; Colthup, N. B.; Fateley,W. G.; Grasselli, J. G. The Handbook of Infrared and Raman Characteristic Frequencies of Organic Molecules; Academic Press: San Die , 1991; pp 295-301.
27. [27]
  (27) Green, J. H. S. Spectrochim. Acta A 1968, 24, 1627.
28. [28]
  (28) Huang, Y. F.; Yin, N. N.;Wang X.;Wu, D. Y.; Ren, B.; Tian, Z. Q. Chem. Eur. J. 2010, 16, 1449.
29. [29]
  (29) Moskoovits, M. Rev. Mod. Phys. 1985, 57, 783.
30. [30]
  (30) Bunding, K. A.; Bell, M. I. Surface Science 1983, 118, 329.
31. [31]
  (31) Baunach, T.; Ivanova, V.; Scherson, D. A.; Kolb, D. M. Langmuir 2004, 20, 2797.
32. [32]
  (32) Diógenes, I. C. N.; Carvalho, I. M. M.; Longhnotti, E.; Lopes, L. G. F.; Temperini, M. L. A.; Andrade, G. F. S.; Moreira, í. S. J. Electroanal. Chem. 2007, 605, 1.
33. [33]
  (33) Diógenes, I. C. N.; Sousa, J. R.; Carvalho, I. M. M.; Temperini, M. L. A.; Tanaka, A. A.; Moreira, Í. S. Dalton Trans. 2003, 11, 2231.
34. [34]
  (34) Diógenes, I. C. N.; Nart, F. C.; Temperini, M. L. A.; Moreira, í. S. Inorg. Chem. 2001, 40, 4884.
35. [35]
  (35) Chao, Y.W.; Zhou, Q.; Li, Y.; Yan, Y. Y.;Wu, Y.; Zheng, J.W. J. Phys. Chem.C 2007, 111, 16990.
36. [36]
  (36) Liu,W. H.; Cao, X.W.;Wang, H. H.; Dai, Y. T.;Wang, R.;Wu, X. Q.; Zhang, Z. R. The Journal of Light Scattering 2008, 20, 27. [刘文华, 曹晓卫, 王洪华, 戴钰婷, 王荣, 吴霞琴, 章宗穰. 光散射学报, 2008, 20, 27.]
1. [1]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
2. [2]
  Lina Liu , Xiaolan Wei , Jianqiang Hu . Exploration of Subject-Oriented Undergraduate Comprehensive Chemistry Experimental Teaching Based on the “STS Concept”: Taking the Experiment of Gold Nanoparticles as an Example. University Chemistry, 2024, 39(10): 337-343. doi: 10.12461/PKU.DXHX202405112
3. [3]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
4. [4]
  Wei Peng , Baoying Wen , Huamin Li , Yiru Wang , Jianfeng Li . Exploration and Practice on Raman Scattering Spectroscopy Experimental Teaching. University Chemistry, 2024, 39(8): 230-240. doi: 10.3866/PKU.DXHX202312062
5. [5]
  Zhuomin Zhang , Hanbing Huang , Liangqiu Lin , Jingsong Liu , Gongke Li . Course Construction of Instrumental Analysis Experiment: Surface-Enhanced Raman Spectroscopy for Rapid Detection of Edible Pigments. University Chemistry, 2024, 39(2): 133-139. doi: 10.3866/PKU.DXHX202308034
6. [6]
  Huihui LIU , Baichuan ZHAO , Chuanhui WANG , Zhi WANG , Congyun ZHANG . Green synthesis of MIL-101/Au composite particles and their sensitivity to Raman detection of thiram. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2021-2030. doi: 10.11862/CJIC.20240059
7. [7]
  Weihan Zhang , Menglu Wang , Ankang Jia , Wei Deng , Shuxing Bai . 表面硫物种对钯-硫纳米片加氢性能的影响. Acta Physico-Chimica Sinica, 2024, 40(11): 2309043-. doi: 10.3866/PKU.WHXB202309043
8. [8]
  Tong Zhou , Jun Li , Zitian Wen , Yitian Chen , Hailing Li , Zhonghong Gao , Wenyun Wang , Fang Liu , Qing Feng , Zhen Li , Jinyi Yang , Min Liu , Wei Qi . Experiment Improvement of “Redox Reaction and Electrode Potential” Based on the New Medical Concept. University Chemistry, 2024, 39(8): 276-281. doi: 10.3866/PKU.DXHX202401005
9. [9]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
10. [10]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
11. [11]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
12. [12]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
13. [13]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
14. [14]
  Lan Ma , Cailu He , Ziqi Liu , Yaohan Yang , Qingxia Ming , Xue Luo , Tianfeng He , Liyun Zhang . Magical Surface Chemistry: Fabrication and Application of Oil-Water Separation Membranes. University Chemistry, 2024, 39(5): 218-227. doi: 10.3866/PKU.DXHX202311046
15. [15]
  Jingyi Chen , Fu Liu , Tiejun Zhu , Kui Cheng . Practice of Integrating Ideological and Political Education into Raman Spectroscopy Analysis Experiment Course. University Chemistry, 2024, 39(2): 140-146. doi: 10.3866/PKU.DXHX202310111
16. [16]
  Zhaoyue Lü , Zhehao Chen , Yi Ni , Duanbin Luo , Xianfeng Hong . Multi-Level Teaching Design and Practice Exploration of Raman Spectroscopy Experiment. University Chemistry, 2024, 39(11): 304-312. doi: 10.12461/PKU.DXHX202402047
17. [17]
  Shengbiao Zheng , Liang Li , Nini Zhang , Ruimin Bao , Ruizhang Hu , Jing Tang . Metal-Organic Framework-Derived Materials Modified Electrode for Electrochemical Sensing of Tert-Butylhydroquinone: A Recommended Comprehensive Chemistry Experiment for Translating Research Results. University Chemistry, 2024, 39(7): 345-353. doi: 10.3866/PKU.DXHX202310096
18. [18]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
19. [19]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
20. [20]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169

Get Citation

PDF

XML

Metrics

PDF Downloads(1633)
Abstract views(2870)
HTML views(6)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142